Hydrogen-Bond Restructuring of Water-in-Salt Electrolyte Confined in Ti 3 C 2 T x MXene Monitored by Operando Infrared Spectroscopy

Lounasvuori, Mailis; Mathis, Tyler S.; Gogotsi, Yury; Petit, Tristan

doi:10.1021/acs.jpclett.2c03769

Hydrogen-Bond Restructuring of Water-in-Salt Electrolyte Confined in Ti ₃ C ₂ T _x MXene Monitored by Operando Infrared Spectroscopy

Journal Article · 06 February 2023 · Journal of Physical Chemistry Letters

DOI:https://doi.org/10.1021/acs.jpclett.2c03769· OSTI ID:2422599

Lounasvuori, Mailis ^[1]; ^[2]; ^[2]; ^[1]

Nanoscale Solid−Liquid Interfaces, Helmholtz-Zentrum Berlin für Materialien und Energie GmbH, 14109 Berlin, Germany
Department of Materials Science and Engineering and A. J. Drexel Nanomaterials Institute, Drexel University, Philadelphia, Pennsylvania 19104, United States

Not provided.

Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Fluid Interface Reactions, Structures and Transport Center (FIRST)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC02-05CH11231

OSTI ID:: 2422599

Journal Information:: Journal of Physical Chemistry Letters, Journal Name: Journal of Physical Chemistry Letters Journal Issue: 6 Vol. 14; ISSN 1948-7185

Publisher:: American Chemical Society

Country of Publication:: United States

Language:: English

References (32)

Localized Water‐In‐Salt Electrolyte for Aqueous Lithium‐Ion Batteries Jaumaux, Pauline; Yang, Xu; Zhang, Bao Angewandte Chemie International Edition, Vol. 60, Issue 36 https://doi.org/10.1002/anie.202107389	journal	July 2021
Direct Assessment of Nanoconfined Water in 2D Ti ₃ C ₂ Electrode Interspaces by a Surface Acoustic Technique Shpigel, Netanel; Levi, Mikhael D.; Sigalov, Sergey Journal of the American Chemical Society, Vol. 140, Issue 28 https://doi.org/10.1021/jacs.8b04862	journal	June 2018
Hydrated Alkali-Metal Cations: Infrared Spectroscopy and ab Initio Calculations of M ⁺ (H ₂ O) _{x =2−5} Ar cluster ions for M = Li, Na, K, and Cs Miller, Dorothy J.; Lisy, James M. Journal of the American Chemical Society, Vol. 130, Issue 46 https://doi.org/10.1021/ja803665q	journal	November 2008
Analysis of Surface OH Groups on TiO ₂ Single Crystal with Polarization Modulation Infrared External Reflection Spectroscopy Takahashi, Keita; Yui, Hiroharu The Journal of Physical Chemistry C, Vol. 113, Issue 47 https://doi.org/10.1021/jp903426s	journal	October 2009
Negative dielectric constant of water confined in nanosheets Sugahara, Akira; Ando, Yasunobu; Kajiyama, Satoshi Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-08789-8	journal	February 2019
Fermi resonance in OH-stretch vibrational spectroscopy of liquid water and the water hexamer Kananenka, Alexei A.; Skinner, J. L. The Journal of Chemical Physics, Vol. 148, Issue 24 https://doi.org/10.1063/1.5037113	journal	June 2018
Proton Redox and Transport in MXene-Confined Water Sun, Yangyunli; Zhan, Cheng; Kent, Paul R. C. ACS Applied Materials & Interfaces, Vol. 12, Issue 1 https://doi.org/10.1021/acsami.9b18139	journal	December 2019
“Water-in-Salt” electrolytes enable green and safe Li-ion batteries for large scale electric energy storage applications Suo, Liumin; Han, Fudong; Fan, Xiulin Journal of Materials Chemistry A, Vol. 4, Issue 17 https://doi.org/10.1039/C6TA00451B	journal	January 2016
Designing Electrolyte Structure to Suppress Hydrogen Evolution Reaction in Aqueous Batteries Nian, Qingshun; Zhang, Xiaoren; Feng, Yazhi ACS Energy Letters, Vol. 6, Issue 6 https://doi.org/10.1021/acsenergylett.1c00833	journal	May 2021
Modified MAX Phase Synthesis for Environmentally Stable and Highly Conductive Ti ₃ C ₂ MXene Mathis, Tyler S.; Maleski, Kathleen; Goad, Adam ACS Nano, Vol. 15, Issue 4 https://doi.org/10.1021/acsnano.0c08357	journal	April 2021
Dense Charge Accumulation in MXene with a Hydrate-Melt Electrolyte Kim, Kijae; Ando, Yasunobu; Sugahara, Akira Chemistry of Materials, Vol. 31, Issue 14 https://doi.org/10.1021/acs.chemmater.9b01334	journal	June 2019
Tracking ion intercalation into layered Ti ₃ C ₂ MXene films across length scales Gao, Qiang; Sun, Weiwei; Ilani-Kashkouli, Poorandokht Energy & Environmental Science, Vol. 13, Issue 8 https://doi.org/10.1039/D0EE01580F	journal	January 2020
Can Anions Be Inserted into MXene? Shpigel, Netanel; Chakraborty, Arup; Malchik, Fyodor Journal of the American Chemical Society, Vol. 143, Issue 32 https://doi.org/10.1021/jacs.1c03840	journal	August 2021
Cation Intercalation and High Volumetric Capacitance of Two-Dimensional Titanium Carbide Lukatskaya, M. R.; Mashtalir, O.; Ren, C. E. Science, Vol. 341, Issue 6153 https://doi.org/10.1126/science.1241488	journal	September 2013
Water-in-salt electrolyte for safe and high-energy aqueous battery Shen, Yuanhao; Liu, Bin; Liu, Xiaorui Energy Storage Materials, Vol. 34 https://doi.org/10.1016/j.ensm.2020.10.011	journal	January 2021
The Applications of Water‐in‐Salt Electrolytes in Electrochemical Energy Storage Devices Liang, Tingting; Hou, Ruilin; Dou, Qingyun Advanced Functional Materials, Vol. 31, Issue 3 https://doi.org/10.1002/adfm.202006749	journal	October 2020
“Water-in-Salt” Electrolyte Makes Aqueous Sodium-Ion Battery Safe, Green, and Long-Lasting Suo, Liumin; Borodin, Oleg; Wang, Yuesheng Advanced Energy Materials, Vol. 7, Issue 21 https://doi.org/10.1002/aenm.201701189	journal	July 2017
Evidence of the existence of the low-density liquid phase in supercooled, confined water Mallamace, F.; Broccio, M.; Corsaro, C. Proceedings of the National Academy of Sciences, Vol. 104, Issue 2 https://doi.org/10.1073/pnas.0607138104	journal	December 2006
Toward the Experimental Understanding of the Energy Storage Mechanism and Ion Dynamics in Ionic Liquid Based Supercapacitors Yan, Runyu; Antonietti, Markus; Oschatz, Martin Advanced Energy Materials, Vol. 8, Issue 18 https://doi.org/10.1002/aenm.201800026	journal	March 2018
Surface Redox Pseudocapacitance of Partially Oxidized Titanium Carbide MXene in Water-in-Salt Electrolyte Wang, Xuehang; Bak, Seong-Min; Han, Meikang ACS Energy Letters, Vol. 7, Issue 1 https://doi.org/10.1021/acsenergylett.1c02262	journal	November 2021
Suppressing Hydrogen Evolution in Aqueous Lithium-Ion Batteries with Double-Site Hydrogen Bonding Zhou, Lixue; Tian, Songwei; Du, Xiaofan ACS Energy Letters, Vol. 8, Issue 1 https://doi.org/10.1021/acsenergylett.2c01993	journal	November 2022
Origin of the Electrochemical Stability of Aqueous Concentrated Electrolyte Solutions Yokoyama, Yuko; Fukutsuka, Tomokazu; Miyazaki, Kohei Journal of The Electrochemical Society, Vol. 165, Issue 14 https://doi.org/10.1149/2.0491814jes	journal	January 2018
How Ions Affect the Structure of Water Hribar, Barbara; Southall, Noel T.; Vlachy, Vojko Journal of the American Chemical Society, Vol. 124, Issue 41 https://doi.org/10.1021/ja026014h	journal	October 2002
Stable high-voltage aqueous pseudocapacitive energy storage device with slow self-discharge Avireddy, Hemesh; Byles, Bryan W.; Pinto, David Nano Energy, Vol. 64 https://doi.org/10.1016/j.nanoen.2019.103961	journal	October 2019
Titanium Carbide MXene Shows an Electrochemical Anomaly in Water-in-Salt Electrolytes Wang, Xuehang; Mathis, Tyler S.; Sun, Yangyunli ACS Nano, Vol. 15, Issue 9 https://doi.org/10.1021/acsnano.1c06027	journal	August 2021
"Water-in-salt" electrolyte enables high-voltage aqueous lithium-ion chemistries Suo, L.; Borodin, O.; Gao, T. Science, Vol. 350, Issue 6263 https://doi.org/10.1126/science.aab1595	journal	November 2015
A review of rechargeable batteries for portable electronic devices Liang, Yeru; Zhao, Chen‐Zi; Yuan, Hong InfoMat, Vol. 1, Issue 1 https://doi.org/10.1002/inf2.12000	journal	March 2019
Water in Carbon Nanotubes: The Peculiar Hydrogen Bond Network Revealed by Infrared Spectroscopy Dalla Bernardina, Simona; Paineau, Erwan; Brubach, Jean-Blaise Journal of the American Chemical Society, Vol. 138, Issue 33 https://doi.org/10.1021/jacs.6b02635	journal	August 2016
Vibrational Sum-Frequency Spectrum of the Water Bend at the Air/Water Interface Vinaykin, Mikhail; Benderskii, Alexander V. The Journal of Physical Chemistry Letters, Vol. 3, Issue 22 https://doi.org/10.1021/jz3014776	journal	October 2012
The IRIS THz/Infrared beamline at BESSY II Puskar, Ljiljana; Schade, Ulrich Journal of large-scale research facilities JLSRF, Vol. 2 https://doi.org/10.17815/jlsrf-2-95	journal	November 2016
Infrared Spectral and Dynamical Properties of Water Confined in Nanobubbles at Hybrid Interfaces of Diamond and Graphene: A Molecular Dynamics Study Kayal, Abhijit; Chandra, Amalendu The Journal of Physical Chemistry C, Vol. 121, Issue 42 https://doi.org/10.1021/acs.jpcc.7b06911	journal	October 2017
Interfacial Dissociation of Contact-Ion-Pair on MXene Electrodes in Concentrated Aqueous Electrolytes Kim, Kijae; Okubo, Masashi; Yamada, Atsuo Journal of The Electrochemical Society, Vol. 166, Issue 15 https://doi.org/10.1149/2.0931915jes	journal	January 2019

Similar Records

Ambipolar Electrochemistry of Pre‐Intercalated Ti ₃ C ₂ T _x MXene in Ionic Liquid Electrolyte

Journal Article · 2023 · Batteries & Supercaps · OSTI ID:2422595

Tuning the Microenvironment of Water Confined in Ti ₃ C ₂ T _x MXene by Cation Intercalation

Journal Article · 2024 · Journal of Physical Chemistry. C · OSTI ID:2305436

Electrochemical Actuators Based on Two-Dimensional Ti ₃ C ₂ T _x (MXene)

Journal Article · 2019 · Nano Letters · OSTI ID:1767627

Related Subjects

Chemistry
Materials Science
Physics
Science & Technology - Other Topics

Hydrogen-Bond Restructuring of Water-in-Salt Electrolyte Confined in Ti 3 C 2 T x MXene Monitored by Operando Infrared Spectroscopy

Citation Formats

References (32)

Similar Records

Related Subjects

Hydrogen-Bond Restructuring of Water-in-Salt Electrolyte Confined in Ti ₃ C ₂ T _x MXene Monitored by Operando Infrared Spectroscopy