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Tuning Phosphine Oxide-Substituted ortho -Carboranes for Improved Biphasic Electrochemical UO 2 2+ Capture and Release

Journal Article · · Inorganic Chemistry
 [1];  [2];  [2];  [2];  [2];  [2];  [3]
  1. Department of Chemistry and Biochemistry, University of California, Santa Barbara, California 93106, United States; OSTI
  2. Department of Chemistry and Biochemistry, University of California, Santa Barbara, California 93106, United States
  3. Department of Chemistry and Biochemistry, University of California, Santa Barbara, California 93106, United States; Department of Chemistry, University of Calgary, 2500 University Drive NW, Calgary, Alberta, T2N 1N4, Canada
Not provided.
Research Organization:
Univ. of California, Santa Barbara, CA (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
SC0021649
OSTI ID:
2421950
Journal Information:
Inorganic Chemistry, Journal Name: Inorganic Chemistry Journal Issue: 37 Vol. 62; ISSN 0020-1669
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English

References (29)

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Involvement of 5f Orbitals in the Covalent Bonding between the Uranyl Ion and Trialkyl Phosphine Oxide: Unraveled by Oxygen K-Edge X-ray Absorption Spectroscopy and Density Functional Theory journal November 2021
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Selective electrochemical capture and release of uranyl from aqueous alkali, lanthanide, and actinide mixtures using redox-switchable carboranes journal January 2022
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Molecular Forces in Liquid–Liquid Extraction journal July 2021
A Camouflagednido-Carborane Anion: Facile Synthesis of Octa-B-methyl-1,2-dicarba-closo-dodecaborane(12) and Its Deboration Reaction journal April 1999
Structure Activity Relationship Approach toward the Improved Separation of Rare-Earth Elements Using Diglycolamides journal November 2020
From Mono‐ to Poly‐Substituted Frameworks: A Way of Tuning the Acidic Character of CcH in o‐Carborane Derivatives journal September 2009
9-Iodo-o-carborane journal October 1985
Actinide structural studies. Part 1. Crystal and molecular structures of dinitratodioxobis(triphenylphosphine oxide)neptunium(VI), dinitratodioxobis(triphenylphosphine oxide)uranium(VI), and dichlorodioxo-(triphenylphosphine oxide)neptunium(VI) journal January 1982
Are Methyl Groups Electron-Donating or Electron-Withdrawing in Boron Clusters? Permethylation of o-Carborane journal June 2005
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The role of surfactant force field on the properties of liquid/liquid interfaces journal May 2020
How substituents at boron atoms affect the CH-acidity and the electron-withdrawing effect of the ortho-carborane cage: A close look on the 1H NMR spectra journal March 2023
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Agents and processes design for transuranium elements back extraction in TRPO process journal January 2012
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Does It Bind? A Method to Determine the Affinity of Calcium and Magnesium Ions for Polymers Using 1H NMR Spectroscopy journal July 2022

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