A Coupled Volatility and Molecular Composition Based Source Apportionment of Atmospheric Organic Aerosol

Rund, Phil; Lee, Ben H.; Mohr, Claudia; Thornton, Joel A.

doi:10.1021/acsearthspacechem.3c00034

A Coupled Volatility and Molecular Composition Based Source Apportionment of Atmospheric Organic Aerosol

Journal Article · 09 June 2023 · ACS Earth and Space Chemistry

DOI:https://doi.org/10.1021/acsearthspacechem.3c00034· OSTI ID:2421719

^[1]; Lee, Ben H. ^[2]; Mohr, Claudia ^[3]; ^[2]

Department of Atmospheric Sciences, University of Washington, Seattle, Washington 98195, United States; OSTI
Department of Atmospheric Sciences, University of Washington, Seattle, Washington 98195, United States
Department of Environmental Science, Stockholm University, Stockholm SE-10691, Sweden

Not provided.

Research Organization:: Univ. of Washington, Seattle, WA (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

DOE Contract Number:: SC0021097

OSTI ID:: 2421719

Journal Information:: ACS Earth and Space Chemistry, Journal Name: ACS Earth and Space Chemistry Journal Issue: 7 Vol. 7; ISSN 2472-3452

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: English

References (62)

Characterization of a real-time tracer for isoprene epoxydiols-derived secondary organic aerosol (IEPOX-SOA) from aerosol mass spectrometer measurements Hu, W. W.; Campuzano-Jost, P.; Palm, B. B. Atmospheric Chemistry and Physics, Vol. 15, Issue 20 https://doi.org/10.5194/acp-15-11807-2015	journal	January 2015
Advantages of diffuse radiation for terrestrial ecosystem productivity: ADVANTAGES OF DIFFUSE RADIATION Gu, Lianhong; Baldocchi, Dennis; Verma, Shashi B. Journal of Geophysical Research: Atmospheres, Vol. 107, Issue D6 https://doi.org/10.1029/2001JD001242	journal	March 2002
Vapor-Pressure Pathways Initiate but Hydrolysis Products Dominate the Aerosol Estimated from Organic Nitrates Zare, Azimeh; Fahey, Kathleen M.; Sarwar, Golam ACS Earth and Space Chemistry, Vol. 3, Issue 8 https://doi.org/10.1021/acsearthspacechem.9b00067	journal	May 2019
Secondary organic aerosol formation from biomass burning intermediates: phenol and methoxyphenols Yee, L. D.; Kautzman, K. E.; Loza, C. L. Atmospheric Chemistry and Physics, Vol. 13, Issue 16 https://doi.org/10.5194/acp-13-8019-2013	journal	January 2013
A new method to retrieve the diurnal variability of planetary boundary layer height from lidar under different thermodynamic stability conditions Su, Tianning; Li, Zhanqing; Kahn, Ralph Remote Sensing of Environment, Vol. 237 https://doi.org/10.1016/j.rse.2019.111519	journal	February 2020
Formation of Low-Volatility Organic Compounds in the Atmosphere: Recent Advancements and Insights Barsanti, Kelley C.; Kroll, Jesse H.; Thornton, Joel A. The Journal of Physical Chemistry Letters, Vol. 8, Issue 7 https://doi.org/10.1021/acs.jpclett.6b02969	journal	March 2017
Molecular Composition and Volatility of Organic Aerosol in the Southeastern U.S.: Implications for IEPOX Derived SOA Lopez-Hilfiker, F. D.; Mohr, C.; D’Ambro, E. L. Environmental Science & Technology, Vol. 50, Issue 5 https://doi.org/10.1021/acs.est.5b04769	journal	February 2016
Effect of NO_x level on secondary organic aerosol (SOA) formation from the photooxidation of terpenes Ng, N. L.; Chhabra, P. S.; Chan, A. W. H. Atmospheric Chemistry and Physics, Vol. 7, Issue 19 https://doi.org/10.5194/acp-7-5159-2007	journal	January 2007
Source apportionment of submicron organic aerosols at an urban site by factor analytical modelling of aerosol mass spectra Lanz, V. A.; Alfarra, M. R.; Baltensperger, U. Atmospheric Chemistry and Physics, Vol. 7, Issue 6 https://doi.org/10.5194/acp-7-1503-2007	journal	January 2007
The AeroCom evaluation and intercomparison of organic aerosol in global models Tsigaridis, K.; Daskalakis, N.; Kanakidou, M. Atmospheric Chemistry and Physics, Vol. 14, Issue 19 https://doi.org/10.5194/acp-14-10845-2014	journal	January 2014
Aqueous chemistry and its role in secondary organic aerosol (SOA) formation Lim, Y. B.; Tan, Y.; Perri, M. J. Atmospheric Chemistry and Physics, Vol. 10, Issue 21 https://doi.org/10.5194/acp-10-10521-2010	journal	January 2010
Ubiquity and dominance of oxygenated species in organic aerosols in anthropogenically-influenced Northern Hemisphere midlatitudes: UBIQUITY AND DOMINANCE OF OXYGENATED OA Zhang, Q.; Jimenez, J. L.; Canagaratna, M. R. Geophysical Research Letters, Vol. 34, Issue 13 https://doi.org/10.1029/2007GL029979	journal	July 2007
Theoretical constraints on pure vapor-pressure driven condensation of organics to ultrafine particles: ORGANIC CONDENSATION Donahue, N. M.; Trump, E. R.; Pierce, J. R. Geophysical Research Letters, Vol. 38, Issue 16 https://doi.org/10.1029/2011GL048115	journal	August 2011
Interpretation of organic components from Positive Matrix Factorization of aerosol mass spectrometric data Ulbrich, I. M.; Canagaratna, M. R.; Zhang, Q. Atmospheric Chemistry and Physics, Vol. 9, Issue 9 https://doi.org/10.5194/acp-9-2891-2009	journal	January 2009
Characteristics of submicron particulate matter at the urban roadside in downtown Hong Kong-Overview of 4 months of continuous high-resolution aerosol mass spectrometer measurements: NR-PM1 AT URBAN ROADSIDE IN HONG KONG Lee, Berto P.; Li, Yong Jie; Yu, Jian Zhen Journal of Geophysical Research: Atmospheres, Vol. 120, Issue 14 https://doi.org/10.1002/2015JD023311	journal	July 2015
Molecular composition and volatility of isoprene photochemical oxidation secondary organic aerosol under low- and high-NO _x conditions D'Ambro, Emma L.; Lee, Ben H.; Liu, Jiumeng Atmospheric Chemistry and Physics, Vol. 17, Issue 1 https://doi.org/10.5194/acp-17-159-2017	journal	January 2017
Photochemical Aging of α-pinene and β-pinene Secondary Organic Aerosol formed from Nitrate Radical Oxidation Nah, Theodora; Sanchez, Javier; Boyd, Christopher M. Environmental Science & Technology, Vol. 50, Issue 1 https://doi.org/10.1021/acs.est.5b04594	journal	December 2015
Molecular transformations of phenolic SOA during photochemical aging in the aqueous phase: competition among oligomerization, functionalization, and fragmentation Yu, Lu; Smith, Jeremy; Laskin, Alexander Atmospheric Chemistry and Physics, Vol. 16, Issue 7 https://doi.org/10.5194/acp-16-4511-2016	journal	January 2016
Secondary organic aerosol formation from the β-pinene+NO ₃ system: effect of humidity and peroxy radical fate Boyd, C. M.; Sanchez, J.; Xu, L. Atmospheric Chemistry and Physics, Vol. 15, Issue 13 https://doi.org/10.5194/acp-15-7497-2015	journal	January 2015
Highly functionalized organic nitrates in the southeast United States: Contribution to secondary organic aerosol and reactive nitrogen budgets Lee, Ben H.; Mohr, Claudia; Lopez-Hilfiker, Felipe D. Proceedings of the National Academy of Sciences, Vol. 113, Issue 6 https://doi.org/10.1073/pnas.1508108113	journal	January 2016
Production of extremely low volatile organic compounds from biogenic emissions: Measured yields and atmospheric implications Jokinen, Tuija; Berndt, Torsten; Makkonen, Risto Proceedings of the National Academy of Sciences, Vol. 112, Issue 23 https://doi.org/10.1073/pnas.1423977112	journal	May 2015
A Chemical Ionization High-Resolution Time-of-Flight Mass Spectrometer Coupled to a Micro Orifice Volatilization Impactor (MOVI-HRToF-CIMS) for Analysis of Gas and Particle-Phase Organic Species Yatavelli, Reddy L. N.; Lopez-Hilfiker, Felipe; Wargo, Julia D. Aerosol Science and Technology, Vol. 46, Issue 12 https://doi.org/10.1080/02786826.2012.712236	journal	December 2012
Secondary Organic Aerosol Formation and Organic Nitrate Yield from NO ₃ Oxidation of Biogenic Hydrocarbons Fry, Juliane L.; Draper, Danielle C.; Barsanti, Kelley C. Environmental Science & Technology, Vol. 48, Issue 20 https://doi.org/10.1021/es502204x	journal	October 2014
Comparison of dimension reduction techniques in the analysis of mass spectrometry data Isokääntä, Sini; Kari, Eetu; Buchholz, Angela Atmospheric Measurement Techniques, Vol. 13, Issue 6 https://doi.org/10.5194/amt-13-2995-2020	journal	June 2020
Chamber-based insights into the factors controlling epoxydiol (IEPOX) secondary organic aerosol (SOA) yield, composition, and volatility D'Ambro, Emma L.; Schobesberger, Siegfried; Gaston, Cassandra J. Atmospheric Chemistry and Physics, Vol. 19, Issue 17 https://doi.org/10.5194/acp-19-11253-2019	journal	January 2019
Organic nitrate aerosol formation via NO₃ + biogenic volatile organic compounds in the southeastern United States Ayres, B. R.; Allen, H. M.; Draper, D. C. Atmospheric Chemistry and Physics, Vol. 15, Issue 23 https://doi.org/10.5194/acp-15-13377-2015	journal	January 2015
Influences of emission sources and meteorology on aerosol chemistry in a polluted urban environment: results from DISCOVER-AQ California Young, D. E.; Kim, H.; Parworth, C. Atmospheric Chemistry and Physics Discussions, Vol. 15, Issue 23 https://doi.org/10.5194/acpd-15-35057-2015	journal	January 2015
Biogenic Volatile Organic Compounds (VOC): An Overview on Emission, Physiology and Ecology Kesselmeier, J.; Staudt, M. Journal of Atmospheric Chemistry, Vol. 33, Issue 1, p. 23-88 https://doi.org/10.1023/A:1006127516791	journal	January 1999
Chemistry of secondary organic aerosol: Formation and evolution of low-volatility organics in the atmosphere Kroll, Jesse H.; Seinfeld, John H. Atmospheric Environment, Vol. 42, Issue 16 https://doi.org/10.1016/j.atmosenv.2008.01.003	journal	May 2008
A chemical element balance for the Pasadena aerosol Miller, M. S.; Friedlander, S. K.; Hidy, G. M. Journal of Colloid and Interface Science, Vol. 39, Issue 1 https://doi.org/10.1016/0021-9797(72)90152-X	journal	April 1972
Chemical characterization of secondary organic aerosol at a rural site in the southeastern US: insights from simultaneous high-resolution time-of-flight aerosol mass spectrometer (HR-ToF-AMS) and FIGAERO chemical ionization mass spectrometer (CIMS) measurements Chen, Yunle; Takeuchi, Masayuki; Nah, Theodora Atmospheric Chemistry and Physics, Vol. 20, Issue 14 https://doi.org/10.5194/acp-20-8421-2020	journal	July 2020
Analyzing experimental data and model parameters: implications for predictions of SOA using chemical transport models Barsanti, K. C.; Carlton, A. G.; Chung, S. H. Atmospheric Chemistry and Physics, Vol. 13, Issue 23 https://doi.org/10.5194/acp-13-12073-2013	journal	January 2013
Experimental and model estimates of the contributions from biogenic monoterpenes and sesquiterpenes to secondary organic aerosol in the southeastern United States Xu, Lu; Pye, Havala O. T.; He, Jia Atmospheric Chemistry and Physics, Vol. 18, Issue 17 https://doi.org/10.5194/acp-18-12613-2018	journal	January 2018
Efficient Isoprene Secondary Organic Aerosol Formation from a Non-IEPOX Pathway Liu, Jiumeng; D’Ambro, Emma L.; Lee, Ben H. Environmental Science & Technology, Vol. 50, Issue 18 https://doi.org/10.1021/acs.est.6b01872	journal	September 2016
A satellite view of aerosols in the climate system Kaufman, Yoram J.; Tanré, Didier; Boucher, Olivier Nature, Vol. 419, Issue 6903 https://doi.org/10.1038/nature01091	journal	September 2002
Deconvolution of FIGAERO–CIMS thermal desorption profiles using positive matrix factorisation to identify chemical and physical processes during particle evaporation Buchholz, Angela; Ylisirniö, Arttu; Huang, Wei Atmospheric Chemistry and Physics, Vol. 20, Issue 13 https://doi.org/10.5194/acp-20-7693-2020	journal	January 2020
Indoor air pollutant sources using blind source separation methods Ouaret, Rachid; Ionescu, Anda; Ramalho, Olivier figshare https://doi.org/10.6084/m9.figshare.11365757.v1	other	January 2019
Organic aerosol source apportionment in Zurich using an extractive electrospray ionization time-of-flight mass spectrometer (EESI-TOF-MS) – Part 2: Biomass burning influences in winter Qi, Lu; Chen, Mindong; Stefenelli, Giulia Atmospheric Chemistry and Physics, Vol. 19, Issue 12 https://doi.org/10.5194/acp-19-8037-2019	journal	January 2019
Sources and chemistry of NO_x in the upper troposphere over the United States Jaeglé, L.; Jacob, D. J.; Wang, Y. Geophysical Research Letters, Vol. 25, Issue 10 https://doi.org/10.1029/97GL03591	journal	May 1998
Aerosol characterization over the southeastern United States using high-resolution aerosol mass spectrometry: spatial and seasonal variation of aerosol composition and sources with a focus on organic nitrates Xu, L.; Suresh, S.; Guo, H. Atmospheric Chemistry and Physics, Vol. 15, Issue 13 https://doi.org/10.5194/acp-15-7307-2015	journal	January 2015
High-resolution mass spectrometry analysis of secondary organic aerosol generated by ozonolysis of isoprene Nguyen, Tran B.; Bateman, Adam P.; Bones, David L. Atmospheric Environment, Vol. 44, Issue 8 https://doi.org/10.1016/j.atmosenv.2009.12.019	journal	March 2010
Health Effects of Fine Particulate Air Pollution: Lines that Connect Pope, C. Arden; Dockery, Douglas W. Journal of the Air & Waste Management Association, Vol. 56, Issue 6 https://doi.org/10.1080/10473289.2006.10464485	journal	June 2006
Trends in sulfate and organic aerosol mass in the Southeast U.S.: Impact on aerosol optical depth and radiative forcing: Aerosol mass and optical depth in SE US Attwood, A. R.; Washenfelder, R. A.; Brock, C. A. Geophysical Research Letters, Vol. 41, Issue 21 https://doi.org/10.1002/2014GL061669	journal	November 2014
Validation of an efficient non-negative matrix factorization method and its preliminary application in Central California Liang, Jinyou; Fairley, David Atmospheric Environment, Vol. 40, Issue 11 https://doi.org/10.1016/j.atmosenv.2005.11.035	journal	April 2006
SugarsDominant Water-Soluble Organic Compounds in Soils and Characterization as Tracers in Atmospheric Particulate Matter Simoneit, Bernd R. T.; Elias, Vladimir O.; Kobayashi, Minoru Environmental Science & Technology, Vol. 38, Issue 22 https://doi.org/10.1021/es0403099	journal	November 2004
Sources, seasonality, and trends of southeast US aerosol: an integrated analysis of surface, aircraft, and satellite observations with the GEOS-Chem chemical transport model Kim, P. S.; Jacob, D. J.; Fisher, J. A. Atmospheric Chemistry and Physics, Vol. 15, Issue 18 https://doi.org/10.5194/acp-15-10411-2015	journal	January 2015
Resolving Ambient Organic Aerosol Formation and Aging Pathways with Simultaneous Molecular Composition and Volatility Observations Lee, Ben H.; D’Ambro, Emma L.; Lopez-Hilfiker, Felipe D. ACS Earth and Space Chemistry, Vol. 4, Issue 3 https://doi.org/10.1021/acsearthspacechem.9b00302	journal	February 2020
Epoxide as a precursor to secondary organic aerosol formation from isoprene photooxidation in the presence of nitrogen oxides Lin, Y. -H.; Zhang, H.; Pye, H. O. T. Proceedings of the National Academy of Sciences, Vol. 110, Issue 17 https://doi.org/10.1073/pnas.1221150110	journal	April 2013
Phase partitioning and volatility of secondary organic aerosol components formed from α-pinene ozonolysis and OH oxidation: the importance of accretion products and other low volatility compounds Lopez-Hilfiker, F. D.; Mohr, C.; Ehn, M. Atmospheric Chemistry and Physics, Vol. 15, Issue 14 https://doi.org/10.5194/acp-15-7765-2015	journal	January 2015
Gas-phase tropospheric chemistry of biogenic volatile organic compounds: a review Atkinson, Roger; Arey, Janet Atmospheric Environment, Vol. 37 https://doi.org/10.1016/S1352-2310(03)00391-1	journal	January 2003
Formation of Low Volatility Organic Compounds and Secondary Organic Aerosol from Isoprene Hydroxyhydroperoxide Low-NO Oxidation Krechmer, Jordan E.; Coggon, Matthew M.; Massoli, Paola Environmental Science & Technology, Vol. 49, Issue 17 https://doi.org/10.1021/acs.est.5b02031	journal	July 2015
2-Hydroxyterpenylic Acid: An Oxygenated Marker Compound for α-Pinene Secondary Organic Aerosol in Ambient Fine Aerosol Kahnt, Ariane; Iinuma, Yoshiteru; Blockhuys, Frank Environmental Science & Technology, Vol. 48, Issue 9 https://doi.org/10.1021/es500377d	journal	April 2014
Atmospheric budget of primary biological aerosol particles from fungal spores Heald, Colette L.; Spracklen, Dominick V. Geophysical Research Letters, Vol. 36, Issue 9 https://doi.org/10.1029/2009GL037493	journal	January 2009
A novel method for online analysis of gas and particle composition: description and evaluation of a Filter Inlet for Gases and AEROsols (FIGAERO) Lopez-Hilfiker, F. D.; Mohr, C.; Ehn, M. Atmospheric Measurement Techniques, Vol. 7, Issue 4 https://doi.org/10.5194/amt-7-983-2014	journal	January 2014
Effect of humidity on the composition of isoprene photooxidation secondary organic aerosol Nguyen, T. B.; Roach, P. J.; Laskin, J. Atmospheric Chemistry and Physics, Vol. 11, Issue 14 https://doi.org/10.5194/acp-11-6931-2011	journal	January 2011
Contributions from transport, solid fuel burning and cooking to primary organic aerosols in two UK cities Allan, J. D.; Williams, P. I.; Morgan, W. T. Atmospheric Chemistry and Physics, Vol. 10, Issue 2 https://doi.org/10.5194/acp-10-647-2010	journal	January 2010
Gas-Phase Reactions of Isoprene and Its Major Oxidation Products Wennberg, Paul O.; Bates, Kelvin H.; Crounse, John D. Chemical Reviews, Vol. 118, Issue 7 https://doi.org/10.1021/acs.chemrev.7b00439	journal	February 2018
A global perspective on aerosol from low-volatility organic compounds Pye, H. O. T.; Seinfeld, J. H. Atmospheric Chemistry and Physics, Vol. 10, Issue 9 https://doi.org/10.5194/acp-10-4377-2010	journal	January 2010
Ambient observations of dimers from terpene oxidation in the gas phase: Implications for new particle formation and growth: Ambient Observations of Gas-Phase Dimers Mohr, Claudia; Lopez-Hilfiker, Felipe D.; Yli-Juuti, Taina Geophysical Research Letters, Vol. 44, Issue 6 https://doi.org/10.1002/2017GL072718	journal	March 2017
Role of the Terrestrial Biosphere in Atmospheric Chemistry and Climate Steiner, Allison L. Accounts of Chemical Research, Vol. 53, Issue 7 https://doi.org/10.1021/acs.accounts.0c00116	journal	June 2020
Formation of secondary organic aerosols from anthropogenic precursors in laboratory studies Srivastava, Deepchandra; Vu, Tuan V.; Tong, Shengrui npj Climate and Atmospheric Science, Vol. 5, Issue 1 https://doi.org/10.1038/s41612-022-00238-6	journal	March 2022
Coupled Partitioning, Dilution, and Chemical Aging of Semivolatile Organics Donahue, N. M.; Robinson, A. L.; Stanier, C. O. Environmental Science & Technology, Vol. 40, Issue 8 https://doi.org/10.1021/es052297c	journal	April 2006

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