Design and Performance of Di- and Tricationic Poly(ionic liquid) + Ionic Liquid Composite Membranes for CO 2 Separation

Ravula, Sudhir; Wise, Kevin W.; Shinde, Pravin S.; Bara, Jason E.

doi:10.1021/acs.macromol.3c00850

Design and Performance of Di- and Tricationic Poly(ionic liquid) + Ionic Liquid Composite Membranes for CO ₂ Separation

Journal Article · 28 July 2023 · Macromolecules

DOI:https://doi.org/10.1021/acs.macromol.3c00850· OSTI ID:2421527

^[1]; ^[2]; ^[2]; ^[2]

Department of Chemical & Biological Engineering, University of Alabama, Tuscaloosa, Alabama 35487-0203, United States; OSTI
Department of Chemical & Biological Engineering, University of Alabama, Tuscaloosa, Alabama 35487-0203, United States

Not provided.

Research Organization:: Univ. of South Alabama, Mobile, AL (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

DOE Contract Number:: SC0020282

OSTI ID:: 2421527

Journal Information:: Macromolecules, Journal Name: Macromolecules Journal Issue: 15 Vol. 56; ISSN 0024-9297

Publisher:: American Chemical Society

Country of Publication:: United States

Language:: English

References (62)

Harnessing Poly(ionic liquid)s for Sensing Applications Guterman, Ryan; Ambrogi, Martina; Yuan, Jiayin Macromolecular Rapid Communications, Vol. 37, Issue 14 https://doi.org/10.1002/marc.201600172	journal	May 2016
Performance of nitrile-containing anions in task-specific ionic liquids for improved CO2/N2 separation Mahurin, Shannon M.; Lee, Je Seung; Baker, Gary A. Journal of Membrane Science, Vol. 353, Issue 1-2 https://doi.org/10.1016/j.memsci.2010.02.045	journal	May 2010
Imidazolium‐Based Poly(ionic liquid)s as New Alternatives for CO₂ Capture Privalova, Elena I.; Karjalainen, Erno; Nurmi, Mari ChemSusChem, Vol. 6, Issue 8 https://doi.org/10.1002/cssc.201300120	journal	July 2013
Enhanced performance of dicationic ionic liquid electrolytes by organic solvents Li, Song; Zhang, Pengfei; Fulvio Pasquale, F. Journal of Physics: Condensed Matter, Vol. 26, Issue 28 https://doi.org/10.1088/0953-8984/26/28/284105	journal	June 2014
Gas permeation processes in biogas upgrading: A short review Kárászová, Magda; Sedláková, Zuzana; Izák, Pavel Chemical Papers, Vol. 69, Issue 10 https://doi.org/10.1515/chempap-2015-0141	journal	January 2015
Enantioselective Catalytic Desymmetrization of Maleimides by Temporary Removal of an Internal Mirror Plane and Stereoablative Over-reduction: Synthesis of (R)-Pyrrolam A Marsh, Barrie J.; Adams, Harry; Barker, Mike D. Organic Letters, Vol. 16, Issue 14 https://doi.org/10.1021/ol5016702	journal	June 2014
Ionic liquids in supported liquid membrane technology Malik, Maqsood Ahmad; Hashim, Mohd Ali; Nabi, Firdosa Chemical Engineering Journal, Vol. 171, Issue 1 https://doi.org/10.1016/j.cej.2011.03.041	journal	June 2011
Substituted polynorbornene membranes: a modular template for targeted gas separations Wang, Xinyi; Wilson, Trevor J.; Alentiev, Dmitry Polymer Chemistry, Vol. 12, Issue 20 https://doi.org/10.1039/D1PY00278C	journal	January 2021
On the limits of gas separation in CO2/CH4, N2/CH4 and CO2/N2 binary mixtures using polyimide membranes Cecopierigomez, M.; Palaciosalquisira, J.; Dominguez, J. Journal of Membrane Science, Vol. 293, Issue 1-2 https://doi.org/10.1016/j.memsci.2007.01.034	journal	April 2007
Gas separation properties of supported liquid membranes prepared with unconventional ionic liquids Cserjési, Petra; Nemestóthy, Nándor; Bélafi-Bakó, Katalin Journal of Membrane Science, Vol. 349, Issue 1-2 https://doi.org/10.1016/j.memsci.2009.10.044	journal	March 2010
Synthesis and characterization of imidazolium-mediated Tröger's base containing poly(amide)-ionenes and composites with ionic liquids for CO₂ separation membranes Kammakakam, Irshad; Bara, Jason E.; Jackson, Enrique M. Polymer Chemistry, Vol. 11, Issue 46 https://doi.org/10.1039/D0PY01038C	journal	January 2020
Effect of Anion on Gas Separation Performance of Polymer−Room-Temperature Ionic Liquid Composite Membranes Bara, Jason E.; Gin, Douglas L.; Noble, Richard D. Industrial & Engineering Chemistry Research, Vol. 47, Issue 24 https://doi.org/10.1021/ie801019x	journal	December 2008
CO₂ Capture by a Task-Specific Ionic Liquid Bates, Eleanor D.; Mayton, Rebecca D.; Ntai, Ioanna Journal of the American Chemical Society, Vol. 124, Issue 6, p. 926-927 https://doi.org/10.1021/ja017593d	journal	February 2002
Imidazolium-Based Copoly(Ionic Liquid) Membranes for CO ₂ /N ₂ Separation Nellepalli, Pothanagandhi; Tomé, Liliana C.; Vijayakrishna, Kari Industrial & Engineering Chemistry Research, Vol. 58, Issue 5 https://doi.org/10.1021/acs.iecr.8b05093	journal	January 2019
Main-chain imidazolium polymer membranes for CO2 separations: An initial study of a new ionic liquid-inspired platform Carlisle, Trevor K.; Bara, Jason E.; Lafrate, Andrew L. Journal of Membrane Science, Vol. 359, Issue 1-2 https://doi.org/10.1016/j.memsci.2009.10.022	journal	September 2010
Effect of molecular structures on polyimide properties: Comparison between estimations and experiments Xu, Yexin; Chen, Cuixian; Zhang, Pengxia Journal of Applied Polymer Science, Vol. 103, Issue 2 https://doi.org/10.1002/app.25289	journal	January 2006
Improving CO2 selectivity in polymerized room-temperature ionic liquid gas separation membranes through incorporation of polar substituents Bara, Jason E.; Gabriel, Christopher J.; Hatakeyama, Evan S. Journal of Membrane Science, Vol. 321, Issue 1 https://doi.org/10.1016/j.memsci.2007.12.033	journal	August 2008
Room-Temperature Ionic Liquids: Solvents for Synthesis and Catalysis. 2 Hallett, Jason P.; Welton, Tom Chemical Reviews, Vol. 111, Issue 5 https://doi.org/10.1021/cr1003248	journal	May 2011
Why Is CO ₂ So Soluble in Imidazolium-Based Ionic Liquids? Cadena, Cesar; Anthony, Jennifer L.; Shah, Jindal K. Journal of the American Chemical Society, Vol. 126, Issue 16 https://doi.org/10.1021/ja039615x	journal	April 2004
Effect of the CO2-philic ionic liquid [BMIM][Tf2N] on the single and mixed gas transport in PolyActive™ membranes Klepić, Martina; Fuoco, Alessio; Monteleone, Marcello Separation and Purification Technology, Vol. 256 https://doi.org/10.1016/j.seppur.2020.117813	journal	February 2021
Poly(ionic liquid)s as new materials for CO₂ absorption Tang, Jianbin; Tang, Huadong; Sun, Weilin Journal of Polymer Science Part A: Polymer Chemistry, Vol. 43, Issue 22, p. 5477-5489 https://doi.org/10.1002/pola.21031	journal	January 2005
The distillation and volatility of ionic liquids Earle, Martyn J.; Esperança, José M. S. S.; Gilea, Manuela A. Nature, Vol. 439, Issue 7078 https://doi.org/10.1038/nature04451	journal	February 2006
CO2 capture by task specific ionic liquids (TSILs) and polymerized ionic liquids (PILs and AAPILs) Raja Shahrom, Maisara Shahrom; Wilfred, Cecilia Devi; Taha, AboBakr Khidir Ziyada Journal of Molecular Liquids, Vol. 219 https://doi.org/10.1016/j.molliq.2016.02.046	journal	July 2016
Polymeric ionic liquids with mixtures of counter-anions: a new straightforward strategy for designing pyrrolidinium-based CO2 separation membranes Tomé, Liliana C.; Aboudzadeh, M. Ali; Rebelo, Luís Paulo N. Journal of Materials Chemistry A, Vol. 1, Issue 35 https://doi.org/10.1039/C3TA12174G	journal	January 2013
CO ₂ Separation from Flue Gas Using Polyvinyl-(Room Temperature Ionic Liquid)–Room Temperature Ionic Liquid Composite Membranes Li, Pei; Pramoda, K. P.; Chung, Tai-Shung Industrial & Engineering Chemistry Research, Vol. 50, Issue 15 https://doi.org/10.1021/ie2005884	journal	August 2011
Vapor Pressure Mapping of Ionic Liquids and Low-Volatility Fluids Using Graded Isothermal Thermogravimetric Analysis Ravula, Sudhir; Larm, Nathaniel E.; Mottaleb, Mohammad A. ChemEngineering, Vol. 3, Issue 2 https://doi.org/10.3390/chemengineering3020042	journal	April 2019
High Ionic Liquid Content Polymeric Gel Membranes: Preparation and Performance Jansen, Johannes Carolus; Friess, Karel; Clarizia, Gabriele Macromolecules, Vol. 44, Issue 1 https://doi.org/10.1021/ma102438k	journal	January 2011
Determination of the upper limits, benchmarks, and critical properties for gas separations using stabilized room temperature ionic liquid membranes (SILMs) for the purpose of guiding future research Scovazzo, Paul Journal of Membrane Science, Vol. 343, Issue 1-2 https://doi.org/10.1016/j.memsci.2009.07.028	journal	November 2009
The upper bound revisited Robeson, Lloyd M. Journal of Membrane Science, Vol. 320, Issue 1-2, p. 390-400 https://doi.org/10.1016/j.memsci.2008.04.030	journal	July 2008
Synthesis and application of dicationic ionic liquids Liu, Qingbin; van Rantwijk, Fred; Sheldon, Roger A. Journal of Chemical Technology & Biotechnology, Vol. 81, Issue 3 https://doi.org/10.1002/jctb.1411	journal	January 2006
Tailored CO ₂ -Philic Anionic Poly(ionic liquid) Composite Membranes: Synthesis, Characterization, and Gas Transport Properties Kammakakam, Irshad; Bara, Jason E.; Jackson, Enrique M. ACS Sustainable Chemistry & Engineering, Vol. 8, Issue 15 https://doi.org/10.1021/acssuschemeng.0c00327	journal	March 2020
Green processing using ionic liquids and CO2 Blanchard, Lynnette A.; Hancu, Dan; Beckman, Eric J. Nature, Vol. 399, Issue 6731 https://doi.org/10.1038/19887	journal	May 1999
Equimolar CO₂ Absorption by Anion-Functionalized Ionic Liquids Gurkan, Burcu E.; de la Fuente, Juan C.; Mindrup, Elaine M. Journal of the American Chemical Society, Vol. 132, Issue 7, p. 2116-2117 https://doi.org/10.1021/ja909305t	journal	February 2010
Room-Temperature Ionic Liquids and Composite Materials: Platform Technologies for CO ₂ Capture Bara, Jason E.; Camper, Dean E.; Gin, Douglas L. Accounts of Chemical Research, Vol. 43, Issue 1 https://doi.org/10.1021/ar9001747	journal	January 2010
Ionic liquid-based materials: a platform to design engineered CO ₂ separation membranes Tomé, Liliana C.; Marrucho, Isabel M. Chemical Society Reviews, Vol. 45, Issue 10 https://doi.org/10.1039/C5CS00510H	journal	January 2016
Pyrrolidinium-based polymeric ionic liquid materials: New perspectives for CO2 separation membranes Tomé, Liliana C.; Mecerreyes, David; Freire, Carmen S. R. Journal of Membrane Science, Vol. 428 https://doi.org/10.1016/j.memsci.2012.10.044	journal	February 2013
Synthesis and light gas separations in cross-linked gemini room temperature ionic liquid polymer membranes Bara, Jason E.; Hatakeyama, Evan S.; Gabriel, Christopher J. Journal of Membrane Science, Vol. 316, Issue 1-2 https://doi.org/10.1016/j.memsci.2007.08.052	journal	May 2008
Versatile and Scalable Method for Producing N -Functionalized Imidazoles Bara, Jason E. Industrial & Engineering Chemistry Research, Vol. 50, Issue 24 https://doi.org/10.1021/ie102535c	journal	December 2011
Synthesis and Performance of Polymerizable Room-Temperature Ionic Liquids as Gas Separation Membranes Bara, Jason E.; Lessmann, Sonja; Gabriel, Christopher J. Industrial & Engineering Chemistry Research, Vol. 46, Issue 16 https://doi.org/10.1021/ie0704492	journal	August 2007
Catalytic Transformation of Lignocellulose into Chemicals and Fuel Products in Ionic Liquids Zhang, Zhanrong; Song, Jinliang; Han, Buxing Chemical Reviews, Vol. 117, Issue 10 https://doi.org/10.1021/acs.chemrev.6b00457	journal	November 2016
Combustible ionic liquids by design: is laboratory safety another ionic liquid myth? Smiglak, Marcin; Reichert, W. Mathew; Holbrey, John D. Chemical Communications, Issue 24 https://doi.org/10.1039/B602086K	journal	January 2006
CO2/light gas separation performance of cross-linked poly(vinylimidazolium) gel membranes as a function of ionic liquid loading and cross-linker content Carlisle, Trevor K.; Nicodemus, Garret D.; Gin, Douglas L. Journal of Membrane Science, Vol. 397-398 https://doi.org/10.1016/j.memsci.2012.01.006	journal	April 2012
Poly(ionic liquid)s with Dicationic Pendants as Gas Separation Membranes Ravula, Sudhir; O’Harra, Kathryn E.; Watson, Keith A. Membranes, Vol. 12, Issue 3 https://doi.org/10.3390/membranes12030264	journal	February 2022
Novel pyrrolidinium-based polymeric ionic liquids with cyano counter-anions: High performance membrane materials for post-combustion CO2 separation Tomé, Liliana C.; Isik, Mehmet; Freire, Carmen S. R. Journal of Membrane Science, Vol. 483 https://doi.org/10.1016/j.memsci.2015.02.020	journal	June 2015
Gas permeation studies in supported ionic liquid membranes Neves, Luísa A.; Crespo, João G.; Coelhoso, Isabel M. Journal of Membrane Science, Vol. 357, Issue 1-2 https://doi.org/10.1016/j.memsci.2010.04.016	journal	July 2010
Structure and Properties of High Stability Geminal Dicationic Ionic Liquids Anderson, Jared L.; Ding, Rongfang; Ellern, Arkady Journal of the American Chemical Society, Vol. 127, Issue 2 https://doi.org/10.1021/ja046521u	journal	January 2005
An experimental study of gas transport and separation properties of ionic liquids supported on nanofiltration membranes Gan, Quan; Rooney, David; Xue, Minliang Journal of Membrane Science, Vol. 280, Issue 1-2 https://doi.org/10.1016/j.memsci.2006.03.015	journal	September 2006
Ionic Polyimides: Hybrid Polymer Architectures and Composites with Ionic Liquids for Advanced Gas Separation Membranes Mittenthal, Max S.; Flowers, Brian S.; Bara, Jason E. Industrial & Engineering Chemistry Research, Vol. 56, Issue 17 https://doi.org/10.1021/acs.iecr.7b00462	journal	April 2017
Enhanced CO ₂ Separation Selectivity in Oligo(ethylene glycol) Functionalized Room-Temperature Ionic Liquids Bara, Jason E.; Gabriel, Christopher J.; Lessmann, Sonja Industrial & Engineering Chemistry Research, Vol. 46, Issue 16 https://doi.org/10.1021/ie070437g	journal	August 2007
Permeation and sorption properties of CO2-selective blend membranes based on polyvinyl alcohol (PVA) and 1-ethyl-3-methylimidazolium dicyanamide ([EMIM][DCA]) ionic liquid for effective CO2/H2 separation Klepić, Martina; Setničková, Kateřina; Lanč, Marek Journal of Membrane Science, Vol. 597 https://doi.org/10.1016/j.memsci.2019.117623	journal	March 2020
Gas separations in fluoroalkyl-functionalized room-temperature ionic liquids using supported liquid membranes Bara, Jason E.; Gabriel, Christopher J.; Carlisle, Trevor K. Chemical Engineering Journal, Vol. 147, Issue 1 https://doi.org/10.1016/j.cej.2008.11.021	journal	April 2009
Energy-efficient polymeric gas separation membranes for a sustainable future: A review Sanders, David F.; Smith, Zachary P.; Guo, Ruilan Polymer, Vol. 54, Issue 18 https://doi.org/10.1016/j.polymer.2013.05.075	journal	August 2013
Introduction: Ionic Liquids Lei, Zhigang; Chen, Biaohua; Koo, Yoon-Mo Chemical Reviews, Vol. 117, Issue 10 https://doi.org/10.1021/acs.chemrev.7b00246	journal	February 2017
Application of Ionic Liquids to Energy Storage and Conversion Materials and Devices Watanabe, Masayoshi; Thomas, Morgan L.; Zhang, Shiguo Chemical Reviews, Vol. 117, Issue 10 https://doi.org/10.1021/acs.chemrev.6b00504	journal	January 2017
Effect of polymer molecular weight on the physical properties and CO2/N2 separation of pyrrolidinium-based poly(ionic liquid) membranes Tomé, Liliana C.; Guerreiro, Diogo C.; Teodoro, Raquel M. Journal of Membrane Science, Vol. 549 https://doi.org/10.1016/j.memsci.2017.12.019	journal	March 2018
Ideal CO ₂ /Light Gas Separation Performance of Poly(vinylimidazolium) Membranes and Poly(vinylimidazolium)-Ionic Liquid Composite Films Carlisle, Trevor K.; Wiesenauer, Erin F.; Nicodemus, Garret D. Industrial & Engineering Chemistry Research, Vol. 52, Issue 3 https://doi.org/10.1021/ie202305m	journal	January 2012
Guide to CO ₂ Separations in Imidazolium-Based Room-Temperature Ionic Liquids Bara, Jason E.; Carlisle, Trevor K.; Gabriel, Christopher J. Industrial & Engineering Chemistry Research, Vol. 48, Issue 6 https://doi.org/10.1021/ie8016237	journal	March 2009
Dual Anion–Cation Crosslinked Poly(ionic liquid) Composite Membranes for Enhanced CO ₂ Separation Kammakakam, Irshad; Bara, Jason E.; Jackson, Enrique M. ACS Applied Polymer Materials, Vol. 2, Issue 11 https://doi.org/10.1021/acsapm.0c00877	journal	October 2020
Polymeric ionic liquid-based membranes: Influence of polycation variation on gas transport and CO2 selectivity properties Tomé, Liliana C.; Gouveia, Andreia S. L.; Freire, Carmen S. R. Journal of Membrane Science, Vol. 486 https://doi.org/10.1016/j.memsci.2015.03.026	journal	July 2015
Poly(ionic liquid)s: Polymers expanding classical property profiles Yuan, Jiayin; Antonietti, Markus Polymer, Vol. 52, Issue 7 https://doi.org/10.1016/j.polymer.2011.01.043	journal	March 2011
Improving CO ₂ permeability in polymerized room-temperature ionic liquid gas separation membranes through the formation of a solid composite with a room-temperature ionic liquid Bara, Jason E.; Hatakeyama, Evan S.; Gin, Douglas L. Polymers for Advanced Technologies, Vol. 19, Issue 10 https://doi.org/10.1002/pat.1209	journal	October 2008
Design and Synthesis of Imidazolium-Mediated Tröger’s Base-Containing Ionene Polymers for Advanced CO ₂ Separation Membranes Kammakakam, Irshad; O’Harra, Kathryn E.; Bara, Jason E. ACS Omega, Vol. 4, Issue 2 https://doi.org/10.1021/acsomega.8b03700	journal	February 2019

Similar Records

Dual Anion–Cation Crosslinked Poly(ionic liquid) Composite Membranes for Enhanced CO ₂ Separation

Journal Article · 2020 · ACS Applied Polymer Materials · OSTI ID:1853545

Tailored CO ₂ -Philic Anionic Poly(ionic liquid) Composite Membranes: Synthesis, Characterization, and Gas Transport Properties

Journal Article · 2020 · ACS Sustainable Chemistry & Engineering · OSTI ID:1803950

Designing Ionic Liquid-Derived Polymer Composites from Poly(Ionic Liquid)–Ionene Semi-interpenetrating Networks

Journal Article · 2021 · ACS Applied Polymer Materials · OSTI ID:1853546

Related Subjects

Polymer Science

Design and Performance of Di- and Tricationic Poly(ionic liquid) + Ionic Liquid Composite Membranes for CO 2 Separation

Citation Formats

References (62)

Similar Records

Related Subjects

Design and Performance of Di- and Tricationic Poly(ionic liquid) + Ionic Liquid Composite Membranes for CO ₂ Separation