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Synthesis and Characterization of Organolanthanidocene(III) (Ln = La, Ce, Pr, Nd) Complexes Containing the 1,4-Cyclohexa-2,5-dienyl Ligand (Benzene 1,4-Dianion): Structures of [K([18]-crown-6)][Ln{η 5 -C 5 H 3 (SiMe 3 ) 2 -1,3} 2 (C 6 H 6 )] [Cp‘ ‘ = η 5 -C 5 H 3 (SiMe 3 ) 2 -1,3; Ln = La, Ce, Nd]
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December 1999 |
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Intermediate Valence States in Lanthanide Compounds
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February 2021 |
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The electrochemical behavior of cerium(III/IV) complexes: Thermodynamics, kinetics and applications in synthesis
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February 2014 |
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A Facile Route toward Ceric Silylamide [Ce{N(SiHMe2)2}4]
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November 2019 |
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Lanthanide Metallocene Complexes of the 1,3,4,6,7,8-Hexahydro-2H-pyrimido[1,2-a]pyrimidinato Ligand, (hpp)1−
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November 2008 |
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A strategy to improve the performance of cerium( iii ) photocatalysts
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January 2019 |
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Bis(pentamethylcyclopentadienyl) complexes of cerium(III). Crystal structure of (C5Me5)2CeCH(SiMe3)2
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December 1988 |
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Coordination Chemistry of a Strongly-Donating Hydroxylamine with Early Actinides: An Investigation of Redox Properties and Electronic Structure
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March 2018 |
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SHELXT – Integrated space-group and crystal-structure determination
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January 2015 |
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Lanthanide tri-benzyl complexes: structural variations and useful precursors to phosphorus-stabilised lanthanide carbenes
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January 2010 |
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On the large‐gradient behavior of the density functional exchange energy
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December 1986 |
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Optimized Slater-type basis sets for the elements 1-118
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May 2003 |
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Stable gold(III) catalysts by oxidative addition of a carbon–carbon bond
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January 2015 |
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Tuning Organocerium Electrochemical Potentials by Extending Tris(cyclopentadienyl) Scaffolds with Terminal Halogenido, Siloxy, and Alkoxy Ligands
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May 2021 |
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Rare Earth Starting Materials and Methodologies for Synthetic Chemistry
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January 2022 |
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The first metal complexes containing the 1,4-cyclohexa-2,5-dienyl ligand (benzene 1,4-dianion); synthesis and structures of [K(18-crown-6)][Ln{η 5 -C 5 H 3 (SiMe 3 ) 2 -1,3} 2 (C 6 H 6 )](Ln = La, Ce)
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January 1996 |
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Stabilization of Cerium(IV) in the Presence of an Iodide Ligand: Remarkable Effects of Lewis Acidity on Valence State
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December 1999 |
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Electronic structure studies reveal 4f/5d mixing and its effect on bonding characteristics in Ce-imido and -oxo complexes
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January 2022 |
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Organocopper(III) Spiro Complexes: Synthesis, Structural Characterization, and Redox Transformation
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September 2017 |
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Rare-Earth Metal Triflates in Organic Synthesis
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June 2002 |
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Lanthanide and Actinide Chemistry
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January 2006 |
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CeCl3/n‐BuLi: Unraveling Imamoto's Organocerium Reagent
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June 2021 |
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Self-Contained Kondo Effect in Single Molecules
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December 2005 |
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NBO 6.0 : Natural bond orbital analysis program
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March 2013 |
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The duality of electron localization and covalency in lanthanide and actinide metallocenes
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January 2020 |
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Challenges for Density Functional Theory
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December 2011 |
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Probing Multiconfigurational States by Spectroscopy: The Cerium XAS L 3 ‐edge Puzzle
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March 2021 |
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Relativistic regular two‐component Hamiltonians
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September 1993 |
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Lanthanocene and Cerocene Alkyl Complexes: Synthesis, Structure, and Reactivity Studies
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June 2019 |
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Facile Access to Tetravalent Cerium Compounds: One-Electron Oxidation Using Iodine(III) Reagents
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October 2010 |
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Tetraanionic Biphenyl Lanthanide Complexes as Single-Molecule Magnets
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February 2015 |
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Molybdenum(0)‐Promoted Carbonylative Cyclization of o‐Haloaryl‐ and β‐Haloalkenylimine Derivatives by Oxidative Addition of a Carbon(sp2)Halogen Bond: Preparation of Two Types of γ‐Lactams
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September 2009 |
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Synthesis and x-ray crystal structure of an unusual oligomeric bis(pentamethylcyclopentadienyl) halide complex of cerium: [(C5Me5)2CeCl2K(THF)]n
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March 1988 |
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Fluorine for Hydrogen Exchange in the Hydrofluorobenzene Derivatives C 6 H x F (6- x ), where x = 2, 3, 4 and 5 by Monomeric [1,2,4-(Me 3 C) 3 C 5 H 2 ] 2 CeH: The Solid State Isomerization of [1,2,4-(Me 3 C) 3 C 5 H 2 ] 2 Ce(2,3,4,5-C 6 HF 4 ) to [1,2,4-(Me 3 C) 3 C 5 H 2 ] 2 Ce(2,3,4,6-C 6 HF 4 )
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June 2008 |
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An implementation of the conductor-like screening model of solvation within the Amsterdam density functional package
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May 1999 |
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Pentamethylcyclopentadienyl Complexes of Cerium(IV): Synthesis, Reactivity, and Electrochemistry
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November 2021 |
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Lanthanide Photocatalysis
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October 2018 |
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Actinide 2-metallabiphenylenes that satisfy Hückel’s rule
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February 2020 |
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Selective and catalytic carbon dioxide and heteroallene activation mediated by cerium N-heterocyclic carbene complexes
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January 2018 |
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Oxidative Addition of Carbon–Carbon Bonds with a Redox-Active Bis(imino)pyridine Iron Complex
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October 2012 |
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Photocatalytic C–H activation and the subtle role of chlorine radical complexation in reactivity
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May 2021 |
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Open questions on bonding involving lanthanide atoms
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February 2022 |
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Synthetic and structural experiments on yttrium, cerium and magnesium trimethylsilylmethyls and their reaction products with nitriles; with a note on two cerium β-diketiminates
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January 2004 |
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The zero‐order regular approximation for relativistic effects: The effect of spin–orbit coupling in closed shell molecules
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October 1996 |
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Development of the Colle-Salvetti correlation-energy formula into a functional of the electron density
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January 1988 |
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Isolation and characterization of a covalent CeIV-Aryl complex with an anomalous 13C chemical shift
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March 2021 |
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Multiple Bonding in Lanthanides and Actinides: Direct Comparison of Covalency in Thorium(IV)- and Cerium(IV)-Imido Complexes
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May 2019 |
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Two interpretations of the cerocene electronic ground state
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February 2014 |
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Controlled Redox Chemistry at Cerium within a Tripodal Nitroxide Ligand Framework
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October 2015 |
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1,2-Addition or Enolization? Variable Reactivity of a Cerium Acetylide Complex toward Carbonyl Compounds
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June 2016 |
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A six-carbon 10π-electron aromatic system supported by group 3 metals
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February 2013 |
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Bis(oxazolinyl)phenyl-Ligated Rare-Earth-Metal Complexes: Highly Regioselective Catalysts for cis-1,4-Polymerization of Isoprene
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March 2013 |
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Cerocene Revisited: The Electronic Structure of and Interconversion Between Ce 2 (C 8 H 8 ) 3 and Ce(C 8 H 8 ) 2
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February 2009 |
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Hydrogen for Fluorine Exchange in C 6 F 6 and C 6 F 5 H by Monomeric [1,3,4-(Me 3 C) 3 C 5 H 2 ] 2 CeH: Experimental and Computational Studies
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January 2005 |
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Synthesis of Heteroleptic Cerium(III) Anionic Amido-Tethered N-Heterocyclic Carbene Complexes
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April 2005 |
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Cerium–quinone redox couples put under scrutiny
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January 2021 |
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A convenient synthesis of biphenylene
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November 2005 |
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Density-functional exchange-energy approximation with correct asymptotic behavior
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September 1988 |
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The Impact of Ligand Reorganization on Cerium(III) Oxidation Chemistry
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August 2012 |
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Tetravalent cerium carbene complexes
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January 2007 |
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Relativistic effects in structural chemistry
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May 1988 |
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Homoleptic Rare-Earth Metal Complexes Containing Ln−C σ-Bonds †
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October 2010 |
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Comparison of silver and molybdenum microfocus X-ray sources for single-crystal structure determination
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January 2015 |
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A Ligand Field Series for the 4f-Block from Experimental and DFT Computed Ce(IV/III) Electrochemical Potentials
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February 2015 |
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Four Homologous Zirconium 2,2‘-Biphenyldiyls: Synthesis, Structure, and Reactivity
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July 2006 |
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Effect of the damping function in dispersion corrected density functional theory
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March 2011 |
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Pentamethylcyclopentadienyl-Supported Cerocene(III) Complexes: Pentamethylcyclopentadienyl-Supported Cerocene(III) Complexes
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February 2017 |
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The reaction of bis(1,2,4-tri-t-butylcyclopentadienyl)ceriumbenzyl, Cp′2CeCH2Ph, with methylhalides: a metathesis reaction that does not proceed by a metathesis transition state
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January 2010 |
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Synthesis of a Bis(cyclopentadienyl)lanthanum Aryl Complex with a Pseudofacially Bound Bis(ortho)-Chelating Aryldiamine Ligand. X-ray Structure of (η5-C5H5)2La(C6H3{CH2NMe2}2-2,6)
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March 1996 |
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The difficult search for organocerium( iv ) compounds
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January 2017 |
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Synthesis, Electrochemistry, and Reactivity of Cerium(III/IV) Methylene-Bis-Phenolate Complexes
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April 2013 |
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A Cerium(IV)-Carbon Multiple Bond
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October 2013 |