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Suppressing Water Uptake and Increasing Hydroxide Conductivity in Ring-Opened Polynorbornene Ion-Exchange Materials via Backbone Design

Journal Article · · ACS Applied Polymer Materials
 [1];  [2];  [2];  [2]
  1. Department of Chemistry, Carnegie Mellon University, 4400 Fifth Ave, Pittsburgh, Pennsylvania 15213-2617, United States; OSTI
  2. Department of Chemistry, Carnegie Mellon University, 4400 Fifth Ave, Pittsburgh, Pennsylvania 15213-2617, United States
Not provided.
Research Organization:
Cornell Univ., Ithaca, NY (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
SC0019445
OSTI ID:
2421312
Journal Information:
ACS Applied Polymer Materials, Journal Name: ACS Applied Polymer Materials Journal Issue: 11 Vol. 4; ISSN 2637-6105
Publisher:
ACS Publications
Country of Publication:
United States
Language:
English

References (51)

Anion exchange membrane fuel cells: Current status and remaining challenges journal January 2018
Multiblock Copolymer Anion-Exchange Membranes Derived from Vinyl Addition Polynorbornenes journal September 2021
Electrocatalysis in Alkaline Media and Alkaline Membrane-Based Energy Technologies journal February 2022
Stability of quaternary onium salts under phase-transfer conditions in the presence of aqueous alkaline solutions journal August 1986
Metal-Cation-Based Anion Exchange Membranes journal March 2012
Exploring the Effects of Bulky Cations Tethered to Semicrystalline Polymers: The Case of Tetraaminophosphoniums with Ring-Opened Polynorbornenes journal September 2020
Molecular design by cycloaddition reactions. 30. Photochemical cycloadditions of quadricyclane to aromatic hydrocarbons and o-quinones. First example of photochemical pericyclic [4.pi. + 2.sigma. + 2.sigma.] addition journal February 1977
Highly Conducting Anion-Exchange Membranes Based on Cross-Linked Poly(norbornene): Ring Opening Metathesis Polymerization journal February 2019
Cationic Metallo-Polyelectrolytes for Robust Alkaline Anion-Exchange Membranes journal January 2018
Versatile Route to Functionalized Vinylic Addition Polynorbornenes journal September 2010
Extremely Base-Resistant Organic Phosphazenium Cations journal January 2006
Anion-exchange membranes in electrochemical energy systems journal January 2014
Synthesis of Novel Cyclic Olefin Copolymer (COC) with High Performance via Effective Copolymerization of Ethylene with Bulky Cyclic Olefin journal June 2012
Highly conductive and chemically stable alkaline anion exchange membranes via ROMP of trans -cyclooctene derivatives journal April 2019
Decoupling Ionic Conductivity from Structural Relaxation: A Way to Solid Polymer Electrolytes? journal June 2011
Crosslinked metallo-polyelectrolytes with enhanced flexibility and dimensional stability for anion-exchange membranes journal January 2020
Water Uptake and Ion Mobility in Cross-Linked Bis(terpyridine)ruthenium-Based Anion Exchange Membranes journal November 2013
Alkaline Anion-Exchange Membrane Fuel Cells: Challenges in Electrocatalysis and Interfacial Charge Transfer journal November 2019
Interplay Between Hydroxyl Density and Relaxations in Poly(vinylbenzyltrimethylammonium)- b -poly(methylbutylene) Membranes for Electrochemical Applications journal January 2018
Anion-exchange membranes derived from main group and metal-based cations journal May 2022
Poly(bis-arylimidazoliums) possessing high hydroxide ion exchange capacity and high alkaline stability journal May 2019
A Ring-Opening Metathesis Polymerization Route to Alkaline Anion Exchange Membranes: Development of Hydroxide-Conducting Thin Films from an Ammonium-Functionalized Monomer journal September 2009
Utilizing thiol–ene chemistry for crosslinked nickel cation‐based anion exchange membranes journal November 2017
A Versatile Precursor for the Synthesis of New Ruthenium Olefin Metathesis Catalysts journal December 2001
Determination of the Tacticity of Ring-opened Metathesis Polymers of Norbornene and Norbornadiene by13C NMR Spectroscopy of their Hydrogenated Derivatives journal September 1996
Thermodynamics of Counterion Release Is Critical for Anion Exchange Membrane Conductivity journal May 2018
Phosphonium-Functionalized Polyethylene: A New Class of Base-Stable Alkaline Anion Exchange Membranes journal October 2012
Synthesis of Novel Cyclic Olefin Polymer with High Glass Transition Temperature via Ring‐Opening Metathesis Polymerization journal November 2016
Solvent Processable Tetraalkylammonium-Functionalized Polyethylene for Use as an Alkaline Anion Exchange Membrane journal September 2010
Synthesis of Alkaline Anion Exchange Membranes with Chemically Stable Imidazolium Cations: Unexpected Cross-Linked Macrocycles from Ring-Fused ROMP Monomers journal April 2018
Synthesis and Properties of Well-Defined Elastomeric Poly(alkylnorbornene)s and Their Hydrogenated Derivatives journal November 2005
Review of cell performance in anion exchange membrane fuel cells journal January 2018
Rational Synthesis of Metallo-Cations Toward Redox- and Alkaline-Stable Metallo-Polyelectrolytes journal December 2019
Ionic aggregation in random copolymers containing phosphonium ionic liquid monomers journal October 2011
A Simple and Universal Gel Permeation Chromatography Technique for Precise Molecular Weight Characterization of Well-Defined Poly(ionic liquid)s journal March 2013
Synthesis of cyclic olefin polymers with high glass transition temperature by ring-opening metathesis copolymerization and subsequent hydrogenation journal June 2014
Expanding metal cation options in polymeric anion exchange membranes journal January 2017
Anion Exchange Membranes’ Evolution toward High Hydroxide Ion Conductivity and Alkaline Resiliency journal June 2018
Synthesis and characterization of anion-exchange membranes based on hydrogenated poly(norbornene) journal January 2017
Photo-oxidative degradation of polynorbornene (part I) journal January 1982
Tunable High Performance Cross-Linked Alkaline Anion Exchange Membranes for Fuel Cell Applications journal March 2010
Alkaline-stable anion exchange membranes: A review of synthetic approaches journal January 2020
Ring-opening metathesis polymerization of cobaltocenium derivative to prepare anion exchange membrane with high ionic conductivity journal May 2020
Rapid Analysis of Tetrakis(dialkylamino)phosphonium Stability in Alkaline Media journal October 2017
Controlled Living Ring-Opening-Metathesis Polymerization by a Fast-Initiating Ruthenium Catalyst journal April 2003
Tetrakis(dialkylamino)phosphonium Polyelectrolytes Prepared by Reversible Addition–Fragmentation Chain Transfer Polymerization journal January 2016
Influence of Counteranion on the Thermal and Solution Behavior of Poly(2-(dimethylamino)ethyl methacrylate)-Based Polyelectrolytes journal November 2010
Hydrogenated Ring-Opened Polynorbornene:  A Highly Crystalline Atactic Polymer journal February 2005
Alkaline polymer electrolyte membranes for fuel cell applications journal January 2013
Strategies for Developing New Anion Exchange Membranes and Electrode Ionomers journal January 2017
Orbital interactions. 7. The Birch reduction as a tool for exploring orbital interactions through bonds. Through-four-, -five-, and -six-bond interactions journal January 1980