Evidence for Reactivity of Decamethylcobaltocene with Dichloromethane

Mikeska, Emily R.; Blakemore, James D.

doi:10.1021/acs.organomet.3c00176

Evidence for Reactivity of Decamethylcobaltocene with Dichloromethane

Journal Article · 05 June 2023 · Organometallics

DOI:https://doi.org/10.1021/acs.organomet.3c00176· OSTI ID:2421005

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Department of Chemistry, University of Kansas, 1567 Irving Hill Road, Lawrence, Kansas 66045, United States; OSTI
Department of Chemistry, University of Kansas, 1567 Irving Hill Road, Lawrence, Kansas 66045, United States

Not provided.

Research Organization:: Univ. of Kansas, Lawrence, KS (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

DOE Contract Number:: SC0019169

OSTI ID:: 2421005

Journal Information:: Organometallics, Journal Name: Organometallics Journal Issue: 13 Vol. 42; ISSN 0276-7333

Publisher:: American Chemical Society

Country of Publication:: United States

Language:: English

References (13)

Untersuchungen zur reaktivität organometallischer komplexe V. Zum sterischen verlauf der pseudocarboniumumlagerung der cyclopentadienyl[5-exo-(α-halogenalkyl)cyclopentadien]kobalt-komplexe Herberich, G. E.; Greiss, G.; Heil, H. F. Journal of Organometallic Chemistry, Vol. 22, Issue 3 https://doi.org/10.1016/S0022-328X(00)87731-1	journal	May 1970
Cp* Noninnocence Leads to a Remarkably Weak C–H Bond via Metallocene Protonation Chalkley, Matthew J.; Oyala, Paul H.; Peters, Jonas C. Journal of the American Chemical Society, Vol. 141, Issue 11 https://doi.org/10.1021/jacs.9b00193	journal	February 2019
Reduction of Pentavalent Uranyl to U(IV) Facilitated by Oxo Functionalization Schnaars, David D.; Wu, Guang; Hayton, Trevor W. Journal of the American Chemical Society, Vol. 131, Issue 48 https://doi.org/10.1021/ja906880d	journal	December 2009
Elements of Molecular and Biomolecular Electrochemistry Savéant, Jean-Michel https://doi.org/10.1002/0471758078	book	January 2006
Permethylmetallocene, II. Decamethylcobaltocen: Synthese und Umwandlung in methylierte (Aren)(cyclopentadienyl)cobalt‐Kationen Kölle, Ulrich; Khouzami, Fouad Chemische Berichte, Vol. 114, Issue 9 https://doi.org/10.1002/cber.19811140902	journal	September 1981
Pentamethylcyclopentadienyl transition-metal complexes. 7. Electrochemistry of transition-metal .pi.-complexes. 7. Cyclopentadienyl (arene)cobalt cations: preparation, electrochemical reduction, and spectroscopic investigation of the paramagnetic d7 monocations Koelle, U.; Fuss, B.; Rajasekharan, M. V. Journal of the American Chemical Society, Vol. 106, Issue 15 https://doi.org/10.1021/ja00327a014	journal	July 1984
(Tetramethylcyclobutadiene)cobalt Complexes with Five-Electron Carbo- and Heterocyclic Ligands Mutseneck, Elena V.; Loginov, Dmitry A.; Perekalin, Dmitry S. Organometallics, Vol. 23, Issue 25 https://doi.org/10.1021/om0495832	journal	October 2004
Chemical Redox Agents for Organometallic Chemistry Connelly, Neil G.; Geiger, William E. Chemical Reviews, Vol. 96, Issue 2 https://doi.org/10.1021/cr940053x	journal	January 1996
Reaction of 19-valence-electron sandwich complexes with alkyl halides. A radical-clock investigation Herberich, Gerhard E.; Carstensen, Tobias; Klein, Wolfram Organometallics, Vol. 12, Issue 4 https://doi.org/10.1021/om00028a071	journal	April 1993
Untersuchungen zur reaktivität organometallischer komplexe III. Über die reaktion von dicyclopentadienylkobalt mit halogenmethanen Herberich, G. E.; Bauer, E.; Schwarzer, J. Journal of Organometallic Chemistry, Vol. 17, Issue 3 https://doi.org/10.1016/S0022-328X(00)88230-3	journal	June 1969
Exploring the Effects of Reduction or Lewis Acid Coordination on the UO Bond of the Uranyl Moiety Hayton, Trevor W.; Wu, Guang Inorganic Chemistry, Vol. 48, Issue 7 https://doi.org/10.1021/ic802360y	journal	April 2009
New polynuclear U( iv )–U( v ) complexes from U( iv ) mediated uranyl( v ) disproportionation Mougel, Victor; Pécaut, Jacques; Mazzanti, Marinella Chem. Commun., Vol. 48, Issue 6 https://doi.org/10.1039/C1CC16646H	journal	January 2012
Preparation of the Paramagnetic Hydrides (Me ₅ C ₅ ) ₃ M ₃ (μ ₃ -CH)(μ-H) (M = Ni, Co) Smith, Michael E.; Andersen, Richard A. Organometallics, Vol. 15, Issue 12 https://doi.org/10.1021/om950944a	journal	January 1996

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