Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Charge and Solvent Effects on the Redox Behavior of Vanadyl Salen–Crown Complexes

Journal Article · · Journal of Physical Chemistry. A, Molecules, Spectroscopy, Kinetics, Environment, and General Theory
 [1];  [2];  [3];  [4];  [4];  [2];  [4]
  1. Department of Chemistry, University of California, Irvine, Irvine, California 92697, United States; OSTI
  2. Department of Chemistry and Biochemistry, University of California, Los Angeles, Los Angeles, California 90095, United States
  3. Department of Chemistry and Center of Excellence for Innovation in Chemistry, Faculty of Science, Mahidol University, Bangkok, 10400, Thailand
  4. Department of Chemistry, University of California, Irvine, Irvine, California 92697, United States

Not provided.

Research Organization:
Univ. of California, Los Angeles, CA (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
SC0019152
OSTI ID:
2420994
Journal Information:
Journal of Physical Chemistry. A, Molecules, Spectroscopy, Kinetics, Environment, and General Theory, Journal Name: Journal of Physical Chemistry. A, Molecules, Spectroscopy, Kinetics, Environment, and General Theory Journal Issue: 25 Vol. 127; ISSN 1089-5639
Publisher:
American Chemical Society
Country of Publication:
United States
Language:
English

References (94)

Synthesis, characterization and study of vanadyl tetradentate Schiff base complexes as catalyst in aerobic selective oxidation of olefins journal February 2002
Multielectron Redox Process of Vanadium Complexes in Oxidation of Low-Coordinate Vanadium(III) to Oxovanadium(V) with Dioxygen journal January 1996
An insight into the non-covalent interactions in the solid state structures of dinuclear cobalt(ii) complexes with N,O-donor ligands: application of the complexes in the fabrication of Schottky devices journal January 2023
Metallocenes as references for the determination of redox potentials by cyclic voltammetry — Permethylated iron and cobalt sandwich complexes, inhibition by polyamine dendrimers, and the role of hydroxy-containing ferrocenes journal February 2006
Linear Free Energy Relationships in Electrostatic Catalysis journal June 2022
Theoretical Study of Magnetic Properties of Oxovanadium(IV) Complex Self-Assemblies with Tetradentate Schiff Base Ligands journal June 2011
A journey into the electrochemistry of vanadium compounds journal October 2015
Oxovanadium(V)-Induced Oxidative Coupling of Organolithium and -magnesium Compounds journal November 1998
Hetero-Bimetallic Complexes Involving Vanadium(V) and Rhenium(VII) Centers, Connected by Unsupported μ-Oxido Bridge: Synthesis, Characterization, and Redox Study journal August 2008
Salophen and salen oxo vanadium complexes as catalysts of sulfides oxidation with H2O2: Mechanistic insights journal September 2012
Vanadium: History, chemistry, interactions with α-amino acids and potential therapeutic applications journal October 2018
VO(acac)2-Catalyzed Oxidative Coupling Reactions of Phosphonium Salts journal December 2001
Trivalent Lewis Acidic Cations Govern the Electronic Properties and Stability of Heterobimetallic Complexes of Nickel journal November 2017
Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides journal September 1976
X-ray crystallographic characterization of a stepwise, metal-assisted oxidative decarboxylation: vanadium complexes of ethylenebis[(o-hydroxyphenyl)glycine] and derivatives journal January 1986
SHELXT – Integrated space-group and crystal-structure determination journal January 2015
Vanadium-mediated oxygen atom transfer reactions journal March 1990
Promotion and Tuning of the Electrochemical Reduction of Hetero‐ and Homobimetallic Zinc Complexes** journal June 2021
Catalytic activities of Schiff base transition metal complexes journal July 2008
Oriented internal electrostatic fields: an emerging design element in coordination chemistry and catalysis journal January 2022
Incorporation of redox-inactive cations promotes iron catalyzed aerobic C–H oxidation at mild potentials journal January 2018
Balanced basis sets of split valence, triple zeta valence and quadruple zeta valence quality for H to Rn: Design and assessment of accuracy journal January 2005
Determining association constants from titration experiments in supramolecular chemistry journal January 2011
Cationic Charges Leading to an Inverse Free-Energy Relationship for N−N Bond Formation by Mn VI Nitrides journal October 2018
EasySpin, a comprehensive software package for spectral simulation and analysis in EPR journal January 2006
Coordination chemistry of vanadium in metallopharmaceutical candidate compounds journal October 2001
Electric Fields in Catalysis: From Enzymes to Molecular Catalysts journal August 2021
Electrochemical Investigations of the Complexes Resulting from the Acid-Promoted Deoxygenation and Dimerization of (N,N'-Ethylenebis(salicylideneaminato))oxovanadium(IV) journal March 1994
Heterobimetallic complexes with M III -(μ-OH)-M II cores (M III = Fe, Mn, Ga; M II = Ca, Sr, and Ba): structural, kinetic, and redox properties journal January 2013
Structural Design Criteria for Anion Hosts:  Strategies for Achieving Anion Shape Recognition through the Complementary Placement of Urea Donor Groups journal February 2005
Oxovanadium(IV) complexes of non-steroidal anti-inflammatory drugs: Synthesis, spectroscopy, and antimicrobial activity journal June 2008
Cationic Effects on the Net Hydrogen Atom Bond Dissociation Free Energy of High-Valent Manganese Imido Complexes journal January 2022
Pyridinediimine Iron Complexes with Pendant Redox-Inactive Metals Located in the Secondary Coordination Sphere journal December 2015
Reduction potentials of heterometallic manganese-oxido cubane complexes modulated by redox-inactive metals journal June 2013
Metallodrugs in Medicinal Inorganic Chemistry journal January 2014
Donor Properties of the Vanadyl Ion:  Reactions of Vanadyl Salicylaldimine β-Ketimine and Acetylacetonato Complexes with Groups 14 and 15 Lewis Acids journal January 2002
Measuring ion-pairing and hydration in variable charge supramolecular cages with microwave microfluidics journal May 2019
Crystal structure refinement with SHELXL journal January 2015
Electronic structure elucidation in oxidized metal–salen complexes journal December 2017
Direct and Post-Synthesis Incorporation of Chiral Metallosalen Catalysts into Metal-Organic Frameworks for Asymmetric Organic Transformations journal July 2015
Long-Range Corrected Hybrid Density Functionals with Improved Dispersion Corrections journal November 2012
Synthesis and Reactivity of Oxo-Peroxo-Vanadium(V) Bipyridine Compounds journal January 2010
A new oxovanadium(IV) complex containing an O,N-bidentate Schiff base ligand: Synthesis at ambient temperature, characterization, crystal structure and catalytic performance in selective oxidation of sulfides to sulfones using H2O2 under solvent-free conditions journal January 2016
Facile and Reversible Formation of Iron(III)-Oxo-Cerium(IV) Adducts from Nonheme Oxoiron(IV) Complexes and Cerium(III) journal June 2017
The ORCA program system: The ORCA program system journal June 2011
3d Transition Metals for C–H Activation journal October 2018
Crystal and molecular structure of the compound [(salen) VOVO(salen)][I5]·MeCN [salen =N,N′-ethylene-bis(salicylideneiminate)] and the preparation of similar complexes with other Schiff-base ligands journal January 1991
Redox Potential and Electronic Structure Effects of Proximal Nonredox Active Cations in Cobalt Schiff Base Complexes journal February 2017
Oxovanadium complexes in catalytic oxidations journal October 2011
Synthesis, structure, ESR spectra, and redox properties of (N,N'-ethylenebis(thiosalicylideneaminato))oxovanadium(IV) and of related {S,N} chelates of vanadium(IV) journal January 1988
3d–4f magnetic exchange interactions and anisotropy in a series of heterobimetallic vanadium(iv)–lanthanide(iii) Schiff base complexes journal January 2021
Redox-Inactive Metal Cations Modulate the Reduction Potential of the Uranyl Ion in Macrocyclic Complexes journal January 2020
Mechanism‐Guided Development of VO(salen)X Complexes as Catalysts for the Asymmetric Synthesis of Cyanohydrin Trimethylsilyl Ethers journal February 2009
Vanadium-Catalyzed Asymmetric Oxidation of α-Hydroxy Esters Using Molecular Oxygen as Stoichiometric Oxidant journal January 2005
Chemical Redox Agents for Organometallic Chemistry journal January 1996
Versatility of the Nature of the Magnetic Gadolinium(III)−Vanadium(IV) Interaction − Structure and Magnetic Properties of Two Heterobinuclear [Gd, V(O)] Complexes journal February 2001
Coordination of BF4- to Oxovanadium(V) Complexes, Evidenced by the Redox Potential of Oxovanadium(IV/V) Couples in CH2Cl2 journal January 2003
Solvent effects on redox potentials journal February 1983
Solvents and Solvent Effects in Organic Chemistry book October 2010
Oxovanadium(III–V) mononuclear complexes and their linear assemblies bearing tetradentate Schiff base ligands: structure and reactivity as multielectron redox catalysts journal February 2003
Co(III)/Alkali-Metal(I) Heterodinuclear Catalysts for the Ring-Opening Copolymerization of CO 2 and Propylene Oxide journal October 2020
Vanadium compounds in medicine journal October 2015
ShelXle : a Qt graphical user interface for SHELXL journal November 2011
Structural and magnetic properties of vanadyl dichloride solvates: from molecular units to extended hydrogen-bonded solids journal January 2004
Novel binuclear vanadium(V)–Schiff base cations containing single fluorine bridges and the structure of difluorodioxovanadate(1–) journal January 1994
Influence of non-covalent interactions on the coordination geometry of Ni(ii) in Ni(ii)–M(ii) complexes (M = Zn and Hg) with a salen-type N2O2 Schiff base ligand and thiocyanate ion as the coligand journal January 2023
Electrochemical Properties of Vanadium(III,IV,V)−Salen Complexes in Acetonitrile. Four-Electron Reduction of O 2 by V(III)−Salen journal January 2000
Crystal structure of a metal ion-bound oxoiron(IV) complex and implications for biological electron transfer journal July 2010
Catalytic Cycle of a Divanadium Complex with Salen Ligands in O 2 Reduction:  Two-Electron Redox Process of the Dinuclear Center (salen = N,N‘ -Ethylenebis(salicylideneamine)) journal January 1996
Simultispin: A versatile graphical user interface for the simulation of solid‐state continuous wave EPR spectra journal March 2020
Installation of internal electric fields by non-redox active cations in transition metal complexes journal January 2019
Vanadium complexes: Recent progress in oxidation catalysis journal October 2015
Synthesis and characterization of 8-quinolinolato vanadium(IV) complexes journal July 2009
Asymmetric compartmental macrocyclic ligands and related mononuclear and hetero-dinuclear complexes with d- and/or f-metal ions journal October 1999
Measuring Electric Fields and Noncovalent Interactions Using the Vibrational Stark Effect journal March 2015
Salan vs. salen metal complexes in catalysis and medicinal applications: Virtues and pitfalls journal June 2019
Combined effects of the lewis acidity and electric field of proximal redox innocent metal ions on the redox potential of vanadyl Schiff base complexes: an experimental and theoretical study journal January 2023
Aerobic Epoxidation of Olefins Catalyzed by Electronegative Vanadyl Salen Complexes journal December 1997
Binding of carbon dioxide to cobalt and nickel tetra-aza macrocycles journal January 1986
Solvent effects on the reactivities of organometallic compounds journal February 1976
Effect of Distortions on the Geometric and Electronic Structures of One-Electron Oxidized Vanadium(IV), Copper(II), and Cobalt(II)/(III) Salen Complexes journal March 2020
One-Electron Oxidation of Electronically Diverse Manganese(III) and Nickel(II) Salen Complexes: Transition from Localized to Delocalized Mixed-Valence Ligand Radicals journal June 2011
Comparison of silver and molybdenum microfocus X-ray sources for single-crystal structure determination journal January 2015
Enantioselective Alkynylation of Trifluoromethyl Ketones Catalyzed by Cation‐Binding Salen Nickel Complexes journal December 2019
VO(salen)(X) catalysed asymmetric cyanohydrin synthesis: an unexpected influence of the nature of anion X on the catalytic activity journal January 2006
Electrochemical properties of VO salen complexes journal August 2014
Magnetic property and crystal structure of bis [N-(4-chlorophenyl) salicylideneaminato] oxovanadium (IV) journal March 2010
Oxo-Vanadium(IV) Dimer of 3-Hydroxy-3-methylglutarate: X-ray Crystal Structure, Solid State Magnetism, and Solution Spectroscopy journal January 1995
Revealing the Influence of Diverse Secondary Metal Cations on Redox‐Active Palladium Complexes journal May 2022
Molecular Batteries Based on Carbon-Carbon Bond Formation and Cleavage in Titanium and Vanadium Schiff Base Complexes journal February 1999
Oxovanadium(IV) complexes with [ONNO]-chelating ligands as catalysts for ethylene homo- and copolymerization journal March 2014
Vanadium in Modern Organic Synthesis journal December 1997
Ferromagnetic Exchange Coupling of Vanadium(IV) dπ Spins across Pyrimidine Rings:  Dinuclear Complexes of Oxovanadium(IV) Bis(1,1,1,5,5,5-hexafluoropentane-2,4-dionate) Bridged by Pyrimidine Derivatives journal December 2001
Redox-Noninnocent Ligand-Supported Vanadium Catalysts for the Chemoselective Reduction of C═X (X = O, N) Functionalities journal September 2019

Similar Records

Salen complexes with dianionic counterions
Patent · 2016 · OSTI ID:1281088

Salen complexes with dianionic counterions
Patent · 2019 · OSTI ID:1600241

Complexation behavior of oppositely charged polyelectrolytes: Effect of charge distribution
Journal Article · 2015 · Journal of Chemical Physics · OSTI ID:22415881

Related Subjects