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Palladium−Duphos Structural and Enantioselective Hydroarylation Chemistry
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Amidine/Amidinate Cobalt Complexes: One-Pot Synthesis, Mechanism, and Photocatalytic Application for Hydrogen Production
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Metal–ligand cooperation in the trans addition of dihydrogen to a pincer Ir(i) complex: a DFT study
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Reaction of [Ru(CO)H(NCMe)2(PPh3)2]ClO4 with 1-hydroxymethyl-3,5-dimethylpyrazole. Formation of an amidine complex. The crystal structure of [Ru(CO)H{NHCMe(Me2pz)}(PPh3)2]ClO4
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Synthesis and characterization of acetamidine rhodium(III) cationic methyl complex, trans-[Rh(Acac)(PPh3)2(CH3){NHC(NH2)CH3}][BPh4], produced by ammination of acetonitrile ligand in trans-[Rh(Acac)(PPh3)2(CH3)(CH3CN)][BPh4]
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A Functional [NiFe]-Hydrogenase Model Compound That Undergoes Biologically Relevant Reversible Thiolate Protonation
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A Molecular Cavity for Tetrahedral and Y-Shaped Anions. Synthetic and Structural Studies of Macrocyclic Dicopper(I) and Disilver(I) Compounds of 1,6-Bis(diphenylphosphino)hexane
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Dihydrogen Complexes of Iridium and Rhodium
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From cyclic amines and acetonitrile to amidine zinc(ii) complexes
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A Synthetic Nickel Electrocatalyst with a Turnover Frequency Above 100,000 s-1 for H2 Production
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Bifunctional Imidazolylphosphine Ligands as Hydrogen Bond Donors Promote N−H and O−H Activation on Platinum
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Investigations of Iridium-Mediated Reversible C−H Bond Cleavage: Characterization of a 16-Electron Iridium(III) Methyl Hydride Complex
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A Novel Route to Cationic Four-Coordinate Rhodium(I) Complexes with Rh=C Bonds
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Snapshots of a Migrating H-Atom: Characterization of a Reactive Iron(III) Indenide Hydride and its Nearly Isoenergetic Ring-Protonated Iron(I) Isomer
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Dehydrogenation of Dimethylamine–Borane Catalyzed by Half-Sandwich Ir and Rh Complexes: Mechanism and the Role of Cp* Noninnocence
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Pentamethylcyclopentadienyl-rhodium and-iridium complexes XIV. The solvolysis of coordinated acetone solvent species to tris(μ-difluorophosphato)bis[η5-pentamethylcyclopentadienylrhodium(III)] hexafluorophosphate, to the η5-(2,4-dimethyl-1-oxapenta-1,3-dienyl)(pentamethylcyclopentadienyl)iridium cation, or to the η5-(2-hydroxy-4-methylpentadienyl)(η5-pentamethylcyclopentadienyl)iridium cation
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Rhenium-Mediated Coupling of Acetonitrile and Pyrazoles. New Molecular Clefts for Anion Binding
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Hydrazido(1-) and 2,2-dimethylhydrazido(1-) derivatives of permethylscandocene. Preparation and structural characterization of their products from reactions with acetonitrile: (.eta.5-C5Me5)2ScN(H)C(CH3)NNH2 and (.eta.5-C5Me5)2ScN(H)C(CH3)NNMe2
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σ-Bonded Metal Carbonyl Cations and Their Derivatives: Syntheses and Structural, Spectroscopic, and Bonding Principles
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Stereodynamics of trans-[tert-C4H9)2PR]2M(CO)X systems (R = H, CH3; M = Rh(I), Ir(I); X = Cl, Br, I). Assignment of conformational preferences and conformational exchange itineraries
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Characterization of a Rhodium(I) -Methane Complex in Solution
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