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Comparing Square-Planar Rh I and Ir I : Metal–Ligand Proton Tautomerism, Fluxionality, and Reactivity

Journal Article · · Organometallics
 [1];  [2];  [2];  [2]
  1. Department of Chemistry, University of Pennsylvania, Philadelphia, Pennsylvania 19104, United States; OSTI
  2. Department of Chemistry, University of Pennsylvania, Philadelphia, Pennsylvania 19104, United States

Not provided.

Research Organization:
Univ. of Pennsylvania, Philadelphia, PA (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
SC0018057
OSTI ID:
2420698
Journal Information:
Organometallics, Journal Name: Organometallics Journal Issue: 22 Vol. 41; ISSN 0276-7333
Publisher:
American Chemical Society
Country of Publication:
United States
Language:
English

References (57)

Going beyond Structure: Nickel-Substituted Rubredoxin as a Mechanistic Model for the [NiFe] Hydrogenases journal July 2018
Palladium−Duphos Structural and Enantioselective Hydroarylation Chemistry journal February 2002
Amidine/Amidinate Cobalt Complexes: One-Pot Synthesis, Mechanism, and Photocatalytic Application for Hydrogen Production journal September 2020
Heterobimetallic complexes from the reaction of iridium(I) and iridium(III) 3,5-dimethylpyrazolates with gold(I) or gold(III) journal May 1987
Metal–ligand cooperation in the trans addition of dihydrogen to a pincer Ir(i) complex: a DFT study journal January 2009
Changes in Coordination of Sterically Demanding Hybrid Imidazolylphosphine Ligands on Pd(0) and Pd(II) journal December 2005
Metal–CO Bonding in Mononuclear Transition Metal Carbonyl Complexes journal April 2021
Reaction of [Ru(CO)H(NCMe)2(PPh3)2]ClO4 with 1-hydroxymethyl-3,5-dimethylpyrazole. Formation of an amidine complex. The crystal structure of [Ru(CO)H{NHCMe(Me2pz)}(PPh3)2]ClO4 journal August 1986
Ir(III)-Induced C-Bound to N-Bound Tautomerization of a N-Heterocyclic Carbene journal July 2007
Iridium PCsp3P-type Complexes with a Hemilabile Anisole Tether journal June 2015
Electrochemical Detection of Transient Cobalt Hydride Intermediates of Electrocatalytic Hydrogen Production journal June 2016
Stereoselective formation of iridium(III) amides and ligand-assisted heterolytic splitting of dihydrogen journal May 1983
Synthesis and characterization of acetamidine rhodium(III) cationic methyl complex, trans-[Rh(Acac)(PPh3)2(CH3){NHC(NH2)CH3}][BPh4], produced by ammination of acetonitrile ligand in trans-[Rh(Acac)(PPh3)2(CH3)(CH3CN)][BPh4] journal July 2013
Reactions of Pd(II) with Chelate-Tethered 2,6-Diaminopurine Derivatives: N3-Coordination and Reaction of the Purine System journal October 2009
Role of Phosphine Sterics in Strained Aminophosphine Chelate Formation journal February 2019
Role of Ligand Protonation in Dihydrogen Evolution from a Pentamethylcyclopentadienyl Rhodium Catalyst journal September 2017
A Functional [NiFe]-Hydrogenase Model Compound That Undergoes Biologically Relevant Reversible Thiolate Protonation journal December 2012
Cis addition of dimethylamine to the coordinated nitriles of cis- and trans-[PtCl2(NCMe)2]. X-ray structure of the amidine complex cis-[PtCl2{E-N(H)C(NMe2)Me}2]·CH2Cl2 journal June 2001
The underappreciated influence of ancillary halide on metal–ligand proton tautomerism journal January 2022
Regioselectivity of the Addition of O2 on SPS-Based Rhodium(I) and Iridium(I) Complexes journal February 2005
Stereodynamics of the ligand-metal bond. Phosphorus-31 DNMR studies of internal rotation about rhodium-phosphorus bonds in trans-[RhX(CO)L2] complexes (X = halogen; L = tertiary phosphine) journal October 1981
Metal complexes of Co, Ni and Cu with the pincer ligand HN(CH2CH2PiPr2)2: preparation, characterization and electrochemistry journal January 2011
Principles of structure, bonding, and reactivity for metal nitrosyl complexes journal September 1974
Cyclopentadienyl-Ruthenium and -Osmium Chemistry. XXX. Synthesis and X-Ray Structure of [Ru(dppm-P)(dppm-P,P')(η-C5H5)][PF6]0.5[PO2F2]0.5 journal January 1988
Cyclopentadiene-mediated hydride transfer from rhodium complexes journal January 2016
A Molecular Cavity for Tetrahedral and Y-Shaped Anions. Synthetic and Structural Studies of Macrocyclic Dicopper(I) and Disilver(I) Compounds of 1,6-Bis(diphenylphosphino)hexane journal March 1995
Dihydrogen Complexes of Iridium and Rhodium journal February 2012
From cyclic amines and acetonitrile to amidine zinc(ii) complexes journal January 2020
Metal/Ligand Proton Tautomerism Facilitates Dinuclear H 2 Reductive Elimination journal December 2020
A Synthetic Nickel Electrocatalyst with a Turnover Frequency Above 100,000 s-1 for H2 Production journal August 2011
Bifunctional Imidazolylphosphine Ligands as Hydrogen Bond Donors Promote N−H and O−H Activation on Platinum journal October 2006
Reducing Power of Three-Coordinate Cobalt(I) journal April 2006
Thermodynamics of the Metal–Hydrogen Bonds in (η 5 -C 5 H 5 )M(CO) 2 H (M = Fe, Ru, Os) journal June 2011
Investigations of Iridium-Mediated Reversible C−H Bond Cleavage: Characterization of a 16-Electron Iridium(III) Methyl Hydride Complex journal June 2009
Proton–hydride tautomerism in hydrogen evolution catalysis journal May 2016
Hydrogenases journal March 2014
A Series of monohapto pyrazolates of iridium(I) and iridium(III) journal July 1984
A Novel Route to Cationic Four-Coordinate Rhodium(I) Complexes with Rh=C Bonds journal April 1999
Oxidative-addition reactions of transition metal complexes journal November 1970
Snapshots of a Migrating H-Atom: Characterization of a Reactive Iron(III) Indenide Hydride and its Nearly Isoenergetic Ring-Protonated Iron(I) Isomer journal September 2019
Dehydrogenation of Dimethylamine–Borane Catalyzed by Half-Sandwich Ir and Rh Complexes: Mechanism and the Role of Cp* Noninnocence journal February 2018
Manganese cationic pyrazolylamidino complexes journal September 2008
Amine addition to coordinated nitriles in tungsten(II) alkyne complexes journal May 1993
Ligand substitution catalysis via hard acid-hard base interaction journal February 1970
Proton-Catalyzed Hydrogenation of a d 8 Ir(I) Complex Yields a trans Ir(III) Dihydride journal April 2010
Pentamethylcyclopentadienyl-rhodium and-iridium complexes XIV. The solvolysis of coordinated acetone solvent species to tris(μ-difluorophosphato)bis[η5-pentamethylcyclopentadienylrhodium(III)] hexafluorophosphate, to the η5-(2,4-dimethyl-1-oxapenta-1,3-dienyl)(pentamethylcyclopentadienyl)iridium cation, or to the η5-(2-hydroxy-4-methylpentadienyl)(η5-pentamethylcyclopentadienyl)iridium cation journal July 1977
Preparation, Characterization, and Electrochemical Activation of a Model [Cp*Rh] Hydride journal September 2018
Solution homolytic bond dissociation energies of organotransition-metal hydrides journal August 1989
Activation of Acetonitrile in [Cp*Ir(η3-CH2CHCHPh)(NCMe)]+:  Crystal Structures of Iridium−Amidine, Imino−Ether, Amido, and Amide Complexes journal January 2000
Rhenium-Mediated Coupling of Acetonitrile and Pyrazoles. New Molecular Clefts for Anion Binding journal July 2006
New synthetic routes to face-to-face and open-book triazenide-bridged dirhodium bipyridyl complexes with the [Rh2]4+ core journal January 1994
Metal−Ligand Cooperation in C−H and H 2 Activation by an Electron-Rich PNP Ir(I) System:  Facile Ligand Dearomatization−Aromatization as Key Steps journal December 2006
Energetics of Third-Row Transition Metal Methylidene Ions MCH2+ (M = La, Hf, Ta, W, Re, Os, Ir, Pt, Au) journal September 1994
Hydrazido(1-) and 2,2-dimethylhydrazido(1-) derivatives of permethylscandocene. Preparation and structural characterization of their products from reactions with acetonitrile: (.eta.5-C5Me5)2ScN(H)C(CH3)NNH2 and (.eta.5-C5Me5)2ScN(H)C(CH3)NNMe2 journal October 1990
σ-Bonded Metal Carbonyl Cations and Their Derivatives:  Syntheses and Structural, Spectroscopic, and Bonding Principles journal August 2003
Stereodynamics of trans-[tert-C4H9)2PR]2M(CO)X systems (R = H, CH3; M = Rh(I), Ir(I); X = Cl, Br, I). Assignment of conformational preferences and conformational exchange itineraries journal May 1986
Characterization of a Rhodium(I)  -Methane Complex in Solution journal October 2009

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