Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

High Temperature Reaction of Individual Graphite Nanoparticles with N 2 O: Etching, Passivation, Sublimation, and Comparison to O 2

Journal Article · · Journal of Physical Chemistry. C
 [1];  [2];  [2]
  1. Department of Chemistry, University of Utah, 315 S 1400 E, Salt Lake City, Utah 84112, United States; OSTI
  2. Department of Chemistry, University of Utah, 315 S 1400 E, Salt Lake City, Utah 84112, United States

Not provided.

Research Organization:
Univ. of Utah, Salt Lake City, UT (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
SC0018049
OSTI ID:
2420695
Journal Information:
Journal of Physical Chemistry. C, Journal Name: Journal of Physical Chemistry. C Journal Issue: 31 Vol. 127; ISSN 1932-7447
Publisher:
American Chemical Society
Country of Publication:
United States
Language:
English

References (47)

Heterogeneous Chemical Kinetics of NO2 on Amorphous Carbon at Ambient Temperature journal June 1994
O2-Oxidation of Individual Graphite and Graphene Nanoparticles in the 1200 – 2200 K Range: Particle-to-Particle Variations and the Evolution of the Reaction Rates and Optical Properties journal October 2020
Reactions of Modulated Molecular Beams with Pyrolytic Graphite. II Oxidation of the Prism Plane journal July 1972
In situ STM imaging of high temperature oxygen etching of Si(111)(7 × 7) surfaces journal May 1992
NO and N2O decomposition over coal char at fluidized-bed combustion conditions journal December 1994
Role of Oxygen in the Nitrous Oxide/Carbon Reaction journal February 2002
Strongly bonded oxygen in graphite: detection by high-temperature TPD and characterization journal December 1992
Control of sp2/sp3 Carbon Ratio and Surface Chemistry of Nanodiamond Powders by Selective Oxidation in Air journal September 2006
Nondestructive high-resolution and absolute mass determination of single charged particles in a three-dimensional quadrupole trap journal November 2001
On the thermal stability of some ammonium salts journal October 2001
Carbon onions produced by heat treatment of carbon soot and their relation to the 217.5 nm interstellar absorption feature journal May 1993
Structure and electronic properties of carbon onions journal May 2001
Molecular Species Evaporating from a Carbon Surface journal July 1953
Role of N2O and equivalence ratio on NOx formation of methane/nitrous oxide premixed flames journal January 2021
First-Principles Kinetics of CO Desorption from Oxygen Species on Carbonaceous Surface journal April 2002
Rate and Heat of Vaporization of Graphite above 3000°K journal October 1969
Mechanistic Study of Defect-Induced Oxidation of Graphite journal November 1999
The reactivity of graphite surfaces with atoms and molecules of hydrogen, oxygen and nitrogen journal May 1971
Carbon Vapor Pressure and Heat of Vaporization journal May 1950
Analysis of the Reaction of Carbon with NO/N2O Using Ab Initio Molecular Orbital Theory journal April 1999
Onion-like carbon from ultra-disperse diamond journal May 1994
CO Desorption from Oxygen Species on Carbonaceous Surface:  1. Effects of the Local Structure of the Active Site and the Surface Coverage journal July 2001
Kinetics of C−NO and C−N2O Reactions journal October 2001
Reactions of Modulated Molecular Beams with Pyrolytic Graphite. I. Oxidation of the Basal Plane journal July 1972
Surface reactivity of oxygen on cleaved and sputtered graphite journal January 1992
O2 Oxidation and Sublimation Kinetics of Single Silicon Nanoparticles at 1200–2050 K: Variation of Reaction Rates, Evolution of Structural and Optical Properties, and the Active-to-Passive Transition journal November 2022
Opposite Roles of O2 in NO− and N2O−Carbon Reactions:  An Ab Initio Study journal January 2001
Oxidation of carbon by NOx, with particular reference to NO2 and N2O journal February 2008
Single CdSe/ZnS Nanocrystals in an Ion Trap: Charge and Mass Determination and Photophysics Evolution with Changing Mass, Charge, and Temperature journal January 2014
Thermal emission spectroscopy for single nanoparticle temperature measurement: optical system design and calibration journal January 2019
Thermal effect and oxygen-enriched effect of N2O decomposition on soot formation in ethylene diffusion flames journal December 2022
Density Functional Study of the Reaction of Carbon Surface Oxides:  The Behavior of Ketones journal April 2005
A Study of the N2 Formation Mechanism in Carbon−N2O Reaction by Using Isotope Gases journal June 1999
Mass Spectrometric Study of Carbon Vapor journal October 1959
Dynamics of Graphite Oxidation at High Temperature journal February 2018
Nitrous oxide as a rocket propellant journal March 2001
Ab Initio Molecular Orbital Study of the Unified Mechanism and Pathways for Gas−Carbon Reactions journal July 1998
High-Temperature Oxidation of Single Carbon Nanoparticles: Dependence on the Surface Structure and Probing Real-Time Structural Evolution via Kinetics journal March 2022
TPD and XPS studies of O2, CO2, and H2O adsorption on clean polycrystalline graphite journal January 1988
Vanadium as a catalyst for NO, N2O and CO2 reaction with activated carbon journal April 2000
Conversion efficiency of graphite atomic-scale defects to etched pits in thermal oxidation reaction journal July 1999
A DFT Study of Interaction of Carbon Monoxide with Carbonaceous Materials journal January 2004
Sublimation Kinetics for Individual Graphite and Graphene Nanoparticles (NPs): NP-to-NP Variations and Evolving Structure-Kinetics and Structure-Emissivity Relationships journal July 2020
Thermal Emission Spectroscopy of Single, Isolated Carbon Nanoparticles: Effects of Particle Size, Material, Charge, Excitation Wavelength, and Thermal History journal December 2019
Thermogravimetric Studies on the Global Kinetics of Carbon Gasification in Nitrous Oxide journal March 1997
Kinetics of Graphite Oxidation:  Monolayer and Multilayer Etch Pits in HOPG Studied by STM journal December 1998
Impact of nitrogen oxides (NO, NO2, N2O) on the formation of soot journal January 2014