Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Flux Synthesis, UV–vis Absorbance, and Magnetism of Cesium Copper Silicates with an Isolated Super-Super Exchange Spin Dimer in Cs 6 Cu 2 Si 9 O 23

Journal Article · · Inorganic Chemistry
 [1];  [2];  [2];  [3];  [4]
  1. Center for Hierarchical Waste form Materials, Columbia, South Carolina 29208, United States; Department of Chemistry and Biochemistry, University of South Carolina, Columbia, South Carolina 29208, United States; OSTI
  2. Department of Chemistry and Biochemistry, University of South Carolina, Columbia, South Carolina 29208, United States
  3. Department of Chemistry and Chemical Biology, McMaster University, Hamilton, Ontario L8S 4M1, Canada
  4. Center for Hierarchical Waste form Materials, Columbia, South Carolina 29208, United States; Department of Chemistry and Biochemistry, University of South Carolina, Columbia, South Carolina 29208, United States

Not provided.

Research Organization:
Univ. of South Carolina, Columbia, SC (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
SC0016574
OSTI ID:
2420551
Journal Information:
Inorganic Chemistry, Journal Name: Inorganic Chemistry Journal Issue: 29 Vol. 62; ISSN 0020-1669
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English

References (27)

Uranyl Titanate Silicates: Syntheses, Structures, and Family Relations journal January 2022
The influence of the Jahn–Teller effect at Fe2+ on the structure of chromite at high pressure journal November 2011
SHELXT – Integrated space-group and crystal-structure determination journal January 2015
Marinite Li 2 M(SO 4 ) 2 (M = Co, Fe, Mn) and Li 1 Fe(SO 4 ) 2 : Model Compounds for Super-Super-Exchange Magnetic Interactions journal August 2013
Luminescent Materials book January 1994
OLEX2 : a complete structure solution, refinement and analysis program journal January 2009
The Fascinating Noncentrosymmetric Copper(II) Phosphates Synthesized via CsCl Salt-Inclusion journal February 2003
Single-crystal structure validation with the program PLATON journal January 2003
Detailed absorption, reflectance, and UV photoelectron spectroscopic and theoretical studies of the charge-transfer transitions of tetrachlorocuprate(2-) ion: correlation of the square-planar and the tetrahedral limits journal July 1983
Expanding the Chemistry of Salt-Inclusion Materials: Utilizing the Titanyl Ion as a Structure Directing Agent for the Targeted Synthesis of Salt-Inclusion Titanium Silicates journal November 2020
Relation between structure and spectra of pseudo-tetrahedral copper(II) complexes. Crystal structure of bis(di-2-pyridylamido)copper(II) journal January 1981
Cu2+, a Chameleon in Coordination Chemistry journal June 1983
Disordering in the structure of cesium silicate Cs6Si10O23 journal June 2007
Hydrothermal single crystal growth and structural investigation of the stuffed tridymite family as NLO materials journal July 2022
Noncentrosymmetric salt inclusion oxides: Role of salt lattices and counter ions in bulk polarity journal November 2012
Revision of the structure of Cs2CuSi5O12 leucite as orthorhombic Pbca journal January 2010
Hydrothermal synthesis and structures of the open-framework copper silicates Na2[Cu2Si4O11](H2O)2 (CuSH-2Na), Na2[CuSi3O8] (CuSH-3Na), Cs2Na4[Cu2Si12O27(OH)2](OH)2 (CuSH-4NaCs), and Na2[Cu2Si5O13](H2O)3 (CuSH-6Na) journal November 2005
Understanding the Formation of Salt-Inclusion Phases: An Enhanced Flux Growth Method for the Targeted Synthesis of Salt-Inclusion Cesium Halide Uranyl Silicates journal May 2016
Halocuprates(II) of the N-phenylpiperazinium mono- and dications: crystal and molecular structure of N-phenylpiperazinium tetrachloro cuprate(II). Correlation of the electronic spectrum vs. distortion of the CuCl42- anions from tetrahedral symmetry journal January 1979
Magnetic Structural Studies of the Two Polymorphs of Li3Fe2(PO4)3:  Analysis of the Magnetic Ground State from Super-Super Exchange Interactions journal November 2001
Salt-Templated Open Frameworks (CU-2):  Novel Phosphates and Arsenates Containing M 3 (X 2 O 7 ) 2 2- (M = Mn, Cu; X = P, As) Micropores 5.3 Å and 12.7 Å in Diameter journal November 1999
A short history of SHELX journal December 2007
Flux Growth of [NaK 6 F][(UO 2 ) 3 (Si 2 O 7 ) 2 ] and [KK 6 Cl][(UO 2 ) 3 (Si 2 O 7 ) 2 ]: The Effect of Surface Area to Volume Ratios on Reaction Products journal January 2016
Paramagnetic resonance in diluted copper salts I. Hyperfine structure in diluted copper Tutton salts
  • Bleaney, Brebis; Bowers, K. D.; Ingram, D. J. E.
  • Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, Vol. 228, Issue 1173, p. 147-157 https://doi.org/10.1098/rspa.1955.0039
journal February 1955
A New Class of Hybrid Materials via Salt Inclusion:  Novel Copper(II) Arsenates Na 5 ACu 4 (AsO 4 ) 4 Cl 2 (A = Rb, Cs) Composed of Alternating Covalent and Ionic Lattices journal October 2002
Crystal Growth of Four Oxovanadium(IV) Tartrates Prepared via a Mild Two-Step Hydrothermal Method: Observation of Spin-Dimer Behavior and Second Harmonic Generation journal March 2015
Simple correction for the sample shape and radial offset effects on SQUID magnetometers: Magnetic measurements on Ln2O3 (Ln=Gd, Dy, Er) standards journal January 2015