Engineering Soft, Elastic, and Conductive Polymers for Stretchable Electronics Using Ionic Compatibilization

Le, My Linh; Lapkriengkri, Intanon; Albanese, Kaitlin R.; Nguyen, Phong H.; Tran, Cassidy; Blankenship, Jacob R.; Segalman, Rachel A.; Bates, Christopher M.; Chabinyc, Michael L.

doi:10.1021/acs.chemmater.3c01685

Engineering Soft, Elastic, and Conductive Polymers for Stretchable Electronics Using Ionic Compatibilization

Journal Article · 29 August 2023 · Chemistry of Materials

DOI:https://doi.org/10.1021/acs.chemmater.3c01685· OSTI ID:2420507

^[1]; Lapkriengkri, Intanon ^[2]; ^[3]; Nguyen, Phong H. ^[4]; Tran, Cassidy ^[5]; Blankenship, Jacob R. ^[3]; ^[6]; ^[7]; ^[7]

Materials Department, University of California, Santa Barbara, California 93106, United States; OSTI
Materials Department, University of California, Santa Barbara, California 93106, United States
Department of Chemistry & Biochemistry, University of California, Santa Barbara, California 93106, United States; Materials Research Laboratory, University of California, Santa Barbara, California 93106, United States
Department of Chemical Engineering, University of California, Santa Barbara, California 93106, United States
Materials Research Laboratory, University of California, Santa Barbara, California 93106, United States
Materials Department, University of California, Santa Barbara, California 93106, United States; Department of Chemical Engineering, University of California, Santa Barbara, California 93106, United States; Materials Research Laboratory, University of California, Santa Barbara, California 93106, United States
Materials Department, University of California, Santa Barbara, California 93106, United States; Materials Research Laboratory, University of California, Santa Barbara, California 93106, United States

Not provided.

Research Organization:: Univ. of California, Santa Barbara, CA (United States); Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

DOE Contract Number:: SC0016390; SC0012704

OSTI ID:: 2420507

Journal Information:: Chemistry of Materials, Journal Name: Chemistry of Materials Journal Issue: 17 Vol. 35; ISSN 0897-4756

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: English

References (73)

Stretchable and Foldable Silicon Integrated Circuits Kim, D.-H.; Ahn, J.-H.; Choi, W. M. Science, Vol. 320, Issue 5875, p. 507-511 https://doi.org/10.1126/science.1154367	journal	April 2008
Role of Complexation Strength on the Photophysical and Transport Properties of Semiconducting Charged Polymer Complexes Le, My Linh; Warner, Caleigh; Segalman, Rachel A. Chemistry of Materials, Vol. 35, Issue 11 https://doi.org/10.1021/acs.chemmater.3c00627	journal	May 2023
Enhanced Thermoelectric Power Factor of Tensile Drawn Poly(3-hexylthiophene) Hynynen, Jonna; Järsvall, Emmy; Kroon, Renee ACS Macro Letters, Vol. 8, Issue 1 https://doi.org/10.1021/acsmacrolett.8b00820	journal	December 2018
Miktoarm Stars via Grafting-Through Copolymerization: Self-Assembly and the Star-to-Bottlebrush Transition Levi, Adam E.; Lequieu, Joshua; Horne, Jacob D. Macromolecules, Vol. 52, Issue 4 https://doi.org/10.1021/acs.macromol.8b02321	journal	February 2019
Polythiophene Nanofibril Bundles Surface-Embedded in Elastomer: A Route to a Highly Stretchable Active Channel Layer Shin, Minkwan; Oh, Jin Young; Byun, Kyung-Eun Advanced Materials, Vol. 27, Issue 7 https://doi.org/10.1002/adma.201404602	journal	January 2015
Elastomer–Polymer Semiconductor Blends for High-Performance Stretchable Charge Transport Networks Choi, Dalsu; Kim, Hyungchul; Persson, Nils Chemistry of Materials, Vol. 28, Issue 4 https://doi.org/10.1021/acs.chemmater.5b04804	journal	February 2016
Super-soft solvent-free bottlebrush elastomers for touch sensing Reynolds, Veronica G.; Mukherjee, Sanjoy; Xie, Renxuan Materials Horizons, Vol. 7, Issue 1 https://doi.org/10.1039/c9mh00951e	journal	January 2020
Stretchable and Conductive Polymer Films Prepared by Solution Blending Li, Pengcheng; Sun, Kuan; Ouyang, Jianyong ACS Applied Materials & Interfaces, Vol. 7, Issue 33 https://doi.org/10.1021/acsami.5b04492	journal	August 2015
Ionomeric blends. V. FTIR studies of ionic interactions in polyurethane-styrene blends Tannenbaum, Rina; Rutkowska, Maria; Eisenberg, Adi Journal of Polymer Science Part B: Polymer Physics, Vol. 25, Issue 3 https://doi.org/10.1002/polb.1987.090250316	journal	March 1987
Conductive Hydrogels—A Novel Material: Recent Advances and Future Perspectives Liu, Kaiquan; Wei, Shan; Song, Longxiang Journal of Agricultural and Food Chemistry, Vol. 68, Issue 28 https://doi.org/10.1021/acs.jafc.0c00642	journal	June 2020
Synthesis of Fluorine-18 Functionalized Nanoparticles for use as in vivo Molecular Imaging Agents Matson, John B.; Grubbs, Robert H. Journal of the American Chemical Society, Vol. 130, Issue 21 https://doi.org/10.1021/ja802010d	journal	May 2008
Electrical and mechanical properties of oriented poly(3-alkylthiophenes) I. Doping-enhanced stiffness of poly(3-octylthiophene) Moulton, Jeff; Smith, Paul Synthetic Metals, Vol. 40, Issue 1 https://doi.org/10.1016/0379-6779(91)91484-R	journal	March 1991
Investigation on sensitivity of a polymer/carbon nanotube composite strain sensor Hu, Ning; Karube, Yoshifumi; Arai, Masahiro Carbon, Vol. 48, Issue 3 https://doi.org/10.1016/j.carbon.2009.10.012	journal	March 2010
Intrinsically Stretchable Polymer Light-Emitting Devices Using Carbon Nanotube-Polymer Composite Electrodes Yu, Zhibin; Niu, Xiaofan; Liu, Zhitian Advanced Materials, Vol. 23, Issue 34 https://doi.org/10.1002/adma.201101986	journal	July 2011
Stretchable Polymeric Multielectrode Array for Conformal Neural Interfacing Guo, Liang; Ma, Mingming; Zhang, Ning Advanced Materials, Vol. 26, Issue 9 https://doi.org/10.1002/adma.201304140	journal	October 2013
Nonhalogenated Solvent Processable and Printable High-Performance Polymer Semiconductor Enabled by Isomeric Nonconjugated Flexible Linkers Wang, Ging-Ji Nathan; Molina-Lopez, Francisco; Zhang, Hongyi Macromolecules, Vol. 51, Issue 13 https://doi.org/10.1021/acs.macromol.8b00971	journal	June 2018
Miscibility enhancement in polymers via ionic interactions: Dynamic mechanical and NMR studies Natansohn, Almeria; Murali, Rajagopalan; Eisenberg, Adi Makromolekulare Chemie. Macromolecular Symposia, Vol. 16, Issue 1 https://doi.org/10.1002/masy.19880160113	journal	March 1988
3D printing of soft robotic systems Wallin, T. J.; Pikul, J.; Shepherd, R. F. Nature Reviews Materials, Vol. 3, Issue 6 https://doi.org/10.1038/s41578-018-0002-2	journal	May 2018
Electrostatic Manipulation of Phase Behavior in Immiscible Charged Polymer Blends Grzetic, Douglas J.; Delaney, Kris T.; Fredrickson, Glenn H. Macromolecules, Vol. 54, Issue 6 https://doi.org/10.1021/acs.macromol.1c00095	journal	March 2021
Structure of Liquid Coacervates Formed by Oppositely Charged Polyelectrolytes Rubinstein, Michael; Liao, Qi; Panyukov, Sergey Macromolecules, Vol. 51, Issue 23 https://doi.org/10.1021/acs.macromol.8b02059	journal	November 2018
Conjugation-Break Spacers in Semiconducting Polymers: Impact on Polymer Processability and Charge Transport Properties Zhao, Yan; Zhao, Xikang; Zang, Yaping Macromolecules, Vol. 48, Issue 7 https://doi.org/10.1021/acs.macromol.5b00194	journal	March 2015
Bottlebrush Elastomers: A New Platform for Freestanding Electroactuation Vatankhah-Varnoosfaderani, Mohammad; Daniel, William F. M.; Zhushma, Alexandr P. Advanced Materials, Vol. 29, Issue 2 https://doi.org/10.1002/adma.201604209	journal	November 2016
Deuterium- and Tritium-Labelled Compounds: Applications in the Life Sciences Atzrodt, Jens; Derdau, Volker; Kerr, William J. Angewandte Chemie International Edition, Vol. 57, Issue 7 https://doi.org/10.1002/anie.201704146	journal	January 2018
Nanophase-Separated Supramolecular Assemblies of Two Functionalized Polymers via Acid–Base Complexation Noro, Atsushi; Ishihara, Koji; Matsushita, Yushu Macromolecules, Vol. 44, Issue 16 https://doi.org/10.1021/ma201440v	journal	August 2011
Rational Design of a Printable, Highly Conductive Silicone-based Electrically Conductive Adhesive for Stretchable Radio-Frequency Antennas Li, Zhuo; Le, Taoran; Wu, Zhenkun Advanced Functional Materials, Vol. 25, Issue 3 https://doi.org/10.1002/adfm.201403275	journal	November 2014
Electrostatic Interactions Control the Nanostructure of Conjugated Polyelectrolyte–Polymeric Ionic Liquid Blends Le, My Linh; Grzetic, Douglas J.; Delaney, Kris T. Macromolecules, Vol. 55, Issue 18 https://doi.org/10.1021/acs.macromol.2c01142	journal	September 2022
Design, fabrication and control of soft robots Rus, Daniela; Tolley, Michael T. Nature, Vol. 521, Issue 7553 https://doi.org/10.1038/nature14543	journal	May 2015
Two-dimensional spatial coherence of excitons in semicrystalline polymeric semiconductors: Effect of molecular weight Paquin, Francis; Yamagata, Hajime; Hestand, Nicholas J. Physical Review B, Vol. 88, Issue 15 https://doi.org/10.1103/PhysRevB.88.155202	journal	October 2013
Aqueous Formulation of Concentrated Semiconductive Fluid Using Polyelectrolyte Coacervation Le, My Linh; Rawlings, Dakota; Danielsen, Scott P. O. ACS Macro Letters, Vol. 10, Issue 8 https://doi.org/10.1021/acsmacrolett.1c00354	journal	July 2021
Polymer Nanocomposites Containing Carbon Nanotubes Moniruzzaman, Mohammad; Winey, Karen I. Macromolecules, Vol. 39, Issue 16 https://doi.org/10.1021/ma060733p	journal	August 2006
Conductive and elastic bottlebrush elastomers for ultrasoft electronics Xu, Pengfei; Wang, Shaojia; Lin, Angela Nature Communications, Vol. 14, Issue 1 https://doi.org/10.1038/s41467-023-36214-8	journal	February 2023
Nuclear magnetic resonance studies of ionomers: 2. Proton transfer in polyurethane-poly(styrene-co-styrene sulphonic acid) mixtures in solution Natansohn, Almeria; Rutkowska, Maria; Eisenberg, Adi Polymer, Vol. 28, Issue 6 https://doi.org/10.1016/0032-3861(87)90158-3	journal	May 1987
Stretchable and Transparent Conductive PEDOT:PSS‐Based Electrodes for Organic Photovoltaics and Strain Sensors Applications Dauzon, Emilie; Lin, Yuanbao; Faber, Hendrik Advanced Functional Materials, Vol. 30, Issue 28 https://doi.org/10.1002/adfm.202001251	journal	May 2020
Highly stretchable polymer semiconductor films through the nanoconfinement effect Xu, Jie; Wang, Sihong; Wang, Ging-Ji Nathan Science, Vol. 355, Issue 6320 https://doi.org/10.1126/science.aah4496	journal	January 2017
Nuclear magnetic resonance studies of ionomers. 1. Interactions between poly(methyl methacrylate-co-4-vinylpyridine) and poly(styrene-co-styrenesulfonic acid) in dimethyl sulfoxide solution Natansohn, Almeria.; Eisenberg, Adi. Macromolecules, Vol. 20, Issue 2 https://doi.org/10.1021/ma00168a015	journal	February 1987
Conductive polymer blends prepared by in situ polymerization of pyrrole: A review De Jesus, M. C.; Fu, Y.; Weiss, R. A. Polymer Engineering & Science, Vol. 37, Issue 12 https://doi.org/10.1002/pen.11844	journal	December 1997
Extraordinarily High Conductivity of Stretchable Fibers of Polyurethane and Silver Nanoflowers Ma, Rujun; Kang, Byeongguk; Cho, Suik ACS Nano, Vol. 9, Issue 11 https://doi.org/10.1021/acsnano.5b03864	journal	October 2015
Ionomeric blends. 3. Miscibility enhancement via ionic interactions in polyurethane-styrene blends Rutkowska, M.; Eisenberg, A. Macromolecules, Vol. 17, Issue 4 https://doi.org/10.1021/ma00134a050	journal	April 1984
Stretchable and Transparent Organic Semiconducting Thin Film with Conjugated Polymer Nanowires Embedded in an Elastomeric Matrix Song, Eunjoo; Kang, Boseok; Choi, Hyun Ho Advanced Electronic Materials, Vol. 2, Issue 1 https://doi.org/10.1002/aelm.201500250	journal	October 2015
Electrochemical Stability Window of Imidazolium-Based Ionic Liquids as Electrolytes for Lithium Batteries Kazemiabnavi, Saeed; Zhang, Zhengcheng; Thornton, Katsuyo The Journal of Physical Chemistry B, Vol. 120, Issue 25 https://doi.org/10.1021/acs.jpcb.6b03433	journal	June 2016
Hydrogen-Bonding Bottlebrush Networks: Self-Healing Materials from Super-Soft to Stiff Xie, Renxuan; Lapkriengkri, Intanon; Pramanik, Nabendu B. Macromolecules, Vol. 55, Issue 23 https://doi.org/10.1021/acs.macromol.2c01886	journal	November 2022
Conducting polymer composites of soluble polythiophenes in polystyrene Hotta, S.; Rughooputh, S. D. D. V.; Heeger, A. J. Synthetic Metals, Vol. 22, Issue 1 https://doi.org/10.1016/0379-6779(87)90573-X	journal	November 1987
Polymer Physics Rubinstein, Michael; Colby, Ralph H. https://doi.org/10.1093/oso/9780198520597.001.0001	book	June 2003
A comparative study of thermodynamic, conformational, and structural properties of bottlebrush with star and ring polymer melts Chremos, Alexandros; Douglas, Jack F. The Journal of Chemical Physics, Vol. 149, Issue 4 https://doi.org/10.1063/1.5034794	journal	July 2018
Kirigami-patterned highly stretchable conductors from flexible carbon nanotube-embedded polymer films Wang, Zhihui; Zhang, Ling; Duan, Shasha J. Mater. Chem. C, Vol. 5, Issue 34 https://doi.org/10.1039/c7tc01727h	journal	January 2017
A Stretchable Form of Single-Crystal Silicon for High-Performance Electronics on Rubber Substrates Khang, Dahl-Young; Jiang, Hanqing; Huang, Young Science, Vol. 311, Issue 5758, p. 208-212 https://doi.org/10.1126/science.1121401	journal	January 2006
Mixed Conductive Soft Solids by Electrostatically Driven Network Formation of a Conjugated Polyelectrolyte Danielsen, Scott P. O.; Sanoja, Gabriel E.; McCuskey, Samantha R. Chemistry of Materials, Vol. 30, Issue 4 https://doi.org/10.1021/acs.chemmater.7b05303	journal	February 2018
High-Performance Organic Electrochemical Transistors Based on Conjugated Polyelectrolyte Copolymers Schmode, Philip; Ohayon, David; Reichstein, Paul M. Chemistry of Materials, Vol. 31, Issue 14 https://doi.org/10.1021/acs.chemmater.9b01722	journal	June 2019
Non-Conjugated Flexible Linkers in Semiconducting Polymers: A Pathway to Improved Processability without Compromising Device Performance Schroeder, Bob C.; Chiu, Yu-Cheng; Gu, Xiaodan Advanced Electronic Materials, Vol. 2, Issue 7 https://doi.org/10.1002/aelm.201600104	journal	May 2016
Efficient Synthesis of Asymmetric Miktoarm Star Polymers Levi, Adam E.; Fu, Liangbing; Lequieu, Joshua Macromolecules, Vol. 53, Issue 2 https://doi.org/10.1021/acs.macromol.9b02380	journal	January 2020
Conjugated polymers and composites for stretchable organic electronics Wang, Min; Baek, Paul; Akbarinejad, Alireza Journal of Materials Chemistry C, Vol. 7, Issue 19 https://doi.org/10.1039/c9tc00709a	journal	January 2019
Hydrogel bioelectronics Yuk, Hyunwoo; Lu, Baoyang; Zhao, Xuanhe Chemical Society Reviews, Vol. 48, Issue 6 https://doi.org/10.1039/c8cs00595h	journal	January 2019
Tuning of the elastic modulus of a soft polythiophene through molecular doping Zokaei, Sepideh; Kim, Donghyun; Järsvall, Emmy Materials Horizons, Vol. 9, Issue 1 https://doi.org/10.1039/d1mh01079d	journal	January 2022
The Effects of Chemical Substitution and Polymerization on the p K _a Values of Sulfonic Acids Dong, Haitao; Du, Hongbo; Wickramasinghe, Sumith Ranil The Journal of Physical Chemistry B, Vol. 113, Issue 43 https://doi.org/10.1021/jp906087c	journal	September 2009
Modular and Reconfigurable Stretchable Electronic Systems Kang, Jiheong; Son, Donghee; Vardoulis, Orestis Advanced Materials Technologies, Vol. 4, Issue 3 https://doi.org/10.1002/admt.201800417	journal	December 2018
Mechanics of noncoplanar mesh design for stretchable electronic circuits Song, J.; Huang, Y.; Xiao, J. Journal of Applied Physics, Vol. 105, Issue 12, Article No. 123516 https://doi.org/10.1063/1.3148245	journal	June 2009
Ionic Compatibilization of Polymers Fredrickson, Glenn H.; Xie, Shuyi; Edmund, Jerrick ACS Polymers Au, Vol. 2, Issue 5 https://doi.org/10.1021/acspolymersau.2c00026	journal	July 2022
Thermally Activated in Situ Doping Enables Solid-State Processing of Conducting Polymers Kroon, Renee; Hofmann, Anna I.; Yu, Liyang Chemistry of Materials, Vol. 31, Issue 8 https://doi.org/10.1021/acs.chemmater.8b04895	journal	April 2019
Highly Conductive, Stretchable, and Transparent PEDOT:PSS Electrodes Fabricated with Triblock Copolymer Additives and Acid Treatment Lee, Jin Ho; Jeong, Yu Ra; Lee, Geumbee ACS Applied Materials & Interfaces, Vol. 10, Issue 33 https://doi.org/10.1021/acsami.8b07287	journal	July 2018
Interconnecting semiconducting molecules with non-conjugated soft linkers: a way to improve film formation quality without sacrifice in charge mobility Xiao, Wen-Jing; Wang, Jiandong; Li, Hong-Jiao RSC Advances, Vol. 8, Issue 42 https://doi.org/10.1039/C8RA04405H	journal	January 2018
Intermolecular cross-polarization studies of the miscibility enhancement of PS/PMMA blends through ionic interactions Zhang, Xinsheng; Natansohn, Almeria; Eisenberg, Adi Macromolecules, Vol. 23, Issue 2 https://doi.org/10.1021/ma00204a010	journal	January 1990
The microstructure of block copolymers formed via ionic interactions Russell, T. P.; Jerome, R.; Charlier, P. Macromolecules, Vol. 21, Issue 6 https://doi.org/10.1021/ma00184a030	journal	June 1988
Highly conductive, stretchable, and breathable epidermal electrode based on hierarchically interactive nano-network Fan, You Jun; Yu, Peng Tao; Liang, Fei Nanoscale, Vol. 12, Issue 30 https://doi.org/10.1039/d0nr03189e	journal	January 2020
Percolation of conducting polymers on a gel Suzuki, Yasuo Y.; Heeger, Alan J.; Pincus, P. Macromolecules, Vol. 23, Issue 21 https://doi.org/10.1021/ma00223a037	journal	October 1990
Stretchable Conductive Polymers and Composites Based on PEDOT and PEDOT:PSS Kayser, Laure V.; Lipomi, Darren J. Advanced Materials, Vol. 31, Issue 10 https://doi.org/10.1002/adma.201806133	journal	January 2019
Simple and cost-effective method of highly conductive and elastic carbon nanotube/polydimethylsiloxane composite for wearable electronics Kim, Jeong Hun; Hwang, Ji-Young; Hwang, Ha Ryeon Scientific Reports, Vol. 8, Issue 1 https://doi.org/10.1038/s41598-017-18209-w	journal	January 2018
Characterization of NaX (X: TFSI, FSI) – PEO based solid polymer electrolytes for sodium batteries Boschin, Andrea; Johansson, Patrik Electrochimica Acta, Vol. 175 https://doi.org/10.1016/j.electacta.2015.03.228	journal	September 2015
Brønsted-Acid-Catalyzed Exchange in Polyester Dynamic Covalent Networks Self, Jeffrey L.; Dolinski, Neil D.; Zayas, Manuel S. ACS Macro Letters, Vol. 7, Issue 7 https://doi.org/10.1021/acsmacrolett.8b00370	journal	June 2018
Effect of Broken Conjugation on the Stretchability of Semiconducting Polymers Savagatrup, Suchol; Zhao, Xikang; Chan, Esther Macromolecular Rapid Communications, Vol. 37, Issue 19 https://doi.org/10.1002/marc.201600377	journal	August 2016
Elastomeric Conductive Composites Based on Carbon Nanotube Forests Shin, Min Kyoon; Oh, Jiyoung; Lima, Marcio Advanced Materials, Vol. 22, Issue 24 https://doi.org/10.1002/adma.200904270	journal	May 2010
Carbon Nanotube Composites with Bottlebrush Elastomers for Compliant Electrodes Self, Jeffrey L.; Reynolds, Veronica G.; Blankenship, Jacob ACS Polymers Au, Vol. 2, Issue 1 https://doi.org/10.1021/acspolymersau.1c00034	journal	November 2021
Recent developments in polyurethane-based conducting composites Njuguna, J.; Pielichowski, K. Journal of Materials Science, Vol. 39, Issue 13 https://doi.org/10.1023/B:JMSC.0000033387.51728.de	journal	July 2004
Highly conductive, stretchable and biocompatible Ag–Au core–sheath nanowire composite for wearable and implantable bioelectronics Choi, Suji; Han, Sang Ihn; Jung, Dongjun Nature Nanotechnology, Vol. 13, Issue 11 https://doi.org/10.1038/s41565-018-0226-8	journal	August 2018

Similar Records

Ionic Compatibilization of Polymers

Journal Article · 2022 · ACS Polymers Au · OSTI ID:1877712

Related Subjects

Chemistry
Materials Science

Engineering Soft, Elastic, and Conductive Polymers for Stretchable Electronics Using Ionic Compatibilization

Citation Formats

References (73)

Similar Records

Related Subjects