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Reversible O–O Bond Scission and O 2 Evolution at MOF-Supported Tetramanganese Clusters

Journal Article · · Journal of the American Chemical Society
DOI:https://doi.org/10.1021/jacs.3c05374· OSTI ID:2420268
 [1];  [2];  [3];  [2];  [2];  [3];  [2]
  1. Department of Chemistry, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, Massachusetts 02139, United States; OSTI
  2. Department of Chemistry, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, Massachusetts 02139, United States
  3. Department of Chemical Engineering, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, Massachusetts 02139, United States
+ Show Author Affiliations
Not provided.
Research Organization:
Univ. of Minnesota, Minneapolis, MN (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
SC0012702
OSTI ID:
2420268
Journal Information:
Journal of the American Chemical Society, Journal Name: Journal of the American Chemical Society Journal Issue: 30 Vol. 145; ISSN 0002-7863
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English

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A Mn(iii)–superoxo complex of a zwitterionic calix[4]arene with an unprecedented linear end-on Mn(iii)–O2 arrangement and good catalytic performance for alkene epoxidation journal January 2011
A synthetic Mn4Ca-cluster mimicking the oxygen-evolving center of photosynthesis journal May 2015
A Tricopper(I) Complex Competent for O Atom Transfer, C–H Bond Activation, and Multiple O2 Activation Steps journal May 2018
Structures of the intermediates of Kok’s photosynthetic water oxidation clock journal November 2018
Metal-templated ligand architectures for trinuclear chemistry: tricopper complexes and their O 2 reactivity journal January 2013
Characterization of the O 2 -Evolving Reaction Catalyzed by [(terpy)(H 2 O)Mn III (O) 2 Mn IV (OH 2 )(terpy)](NO 3 ) 3 (terpy = 2,2‘:6,2‘ ‘-Terpyridine) journal January 2001
A bioinspired soluble manganese cluster as a water oxidation electrocatalyst with low overpotential journal November 2017
Artificial photosynthesis: opportunities and challenges of molecular catalysts journal January 2019
Synthetic Fe/Cu Complexes: Toward Understanding Heme-Copper Oxidase Structure and Function journal October 2018
Planar three-coordinate iron sulfide in a synthetic [4Fe-3S] cluster with biomimetic reactivity journal October 2019
Development of Bioinspired Mn 4 O 4 −Cubane Water Oxidation Catalysts: Lessons from Photosynthesis journal December 2009
A Monomeric Mn III −Peroxo Complex Derived Directly from Dioxygen journal July 2008
Quantification of Site-Specific Cation Exchange in Metal–Organic Frameworks Using Multi-Wavelength Anomalous X-ray Dispersion journal July 2013
Dioxygen Activation by Nonheme Diiron Enzymes: Diverse Dioxygen Adducts, High-Valent Intermediates, and Related Model Complexes journal December 2017
A Trinuclear Intermediate in the Copper-Mediated Reduction of O 2 : Four Electrons from Three Coppers journal September 1996
Reversible Cleavage and Formation of the Dioxygen O-O Bond Within a Dicopper Complex journal March 1996
Synthetic model of the asymmetric [Mn3CaO4] cubane core of the oxygen-evolving complex of photosystem II journal January 2012
Characterization of Metastable Intermediates Formed in the Reaction between a Mn(II) Complex and Dioxygen, Including a Crystallographic Structure of a Binuclear Mn(III)–Peroxo Species journal April 2013
Introduction to Reticular Chemistry journal January 2019
Testing the Polynuclear Hypothesis: Multielectron Reduction of Small Molecules by Triiron Reaction Sites journal August 2013
High-Enthalpy Hydrogen Adsorption in Cation-Exchanged Variants of the Microporous Metal−Organic Framework Mn 3 [(Mn 4 Cl) 3 (BTT) 8 (CH 3 OH) 10 ] 2 journal September 2007
A Synthetic Model of the Mn3Ca Subsite of the Oxygen-Evolving Complex in Photosystem II journal August 2011
A Cytochrome c Oxidase Model Catalyzes Oxygen to Water Reduction Under Rate-Limiting Electron Flux journal March 2007
Hydrogen Storage in a Microporous Metal−Organic Framework with Exposed Mn 2+ Coordination Sites journal December 2006
Crystallographic and spectroscopic characterization and reactivities of a mononuclear non-haem iron(III)-superoxo complex journal December 2014
A ligand field chemistry of oxygen generation by the oxygen-evolving complex and synthetic active sites
  • Betley, Theodore A.; Surendranath, Yogesh; Childress, Montana V.
  • Philosophical Transactions of the Royal Society B: Biological Sciences, Vol. 363, Issue 1494 https://doi.org/10.1098/rstb.2007.2226
journal October 2007
Copper–Oxygen Complexes Revisited: Structures, Spectroscopy, and Reactivity journal January 2017
Molecular Catalysts for Water Oxidation journal July 2015

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