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Mechanism of Methanol Dehydration Catalyzed by Al 8 O 12 Nodes Assisted by Linker Amine Groups of the Metal–Organic Framework CAU-1

Journal Article · · ACS Catalysis
 [1];  [2];  [3];  [3];  [3];  [2];  [4];  [5]
  1. College of Chemical Engineering, State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing Tech University, Nanjing, Jiangsu 21000, China; OSTI
  2. Department of Chemical Engineering and Materials Science, Department of Chemistry, and Chemical Theory Center, University of Minnesota─Twin Cities, Minneapolis, Minnesota 55455, United States
  3. College of Chemical Engineering, State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing Tech University, Nanjing, Jiangsu 21000, China
  4. Department of Chemistry, Pritzker School of Molecular Engineering, James Franck Institute, and Chicago Center for Theoretical Chemistry, University of Chicago, Chicago, Illinois 60637, United States
  5. Department of Chemical Engineering, University of California, Davis, California 95616, United States
+ Show Author Affiliations
Not provided.
Research Organization:
Univ. of Minnesota, Minneapolis, MN (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
SC0012702
OSTI ID:
2420262
Journal Information:
ACS Catalysis, Journal Name: ACS Catalysis Journal Issue: 20 Vol. 12; ISSN 2155-5435
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English

References (37)

How to Conceptualize Catalytic Cycles? The Energetic Span Model journal February 2011
[Al 4 (OH) 2 (OCH 3 ) 4 (H 2 N-bdc) 3 ]⋅ x  H 2 O: A 12-Connected Porous Metal-Organic Framework with an Unprecedented Aluminum-Containing Brick journal June 2009
Defining the Proton Topology of the Zr6-Based Metal–Organic Framework NU-1000 journal October 2014
Microcalorimetric and Fourier transform infrared spectroscopic studies of methanol adsorption on alumina journal December 1985
Defective Metal-Organic Frameworks journal January 2018
Balanced basis sets of split valence, triple zeta valence and quadruple zeta valence quality for H to Rn: Design and assessment of accuracy journal January 2005
MOF-enabled confinement and related effects for chemical catalyst presentation and utilization journal January 2022
Controlled modification of the inorganic and organic bricks in an Al-based MOF by direct and post-synthetic synthesis routes journal January 2012
Vapor-Phase Metalation by Atomic Layer Deposition in a Metal–Organic Framework
  • Mondloch, Joseph E.; Bury, Wojciech; Fairen-Jimenez, David
  • Journal of the American Chemical Society, Vol. 135, Issue 28, p. 10294-10297 https://doi.org/10.1021/ja4050828
journal May 2013
Properties of surface compounds in methanol conversion on γ-Al2O3: Data of in situ IR spectroscopy journal January 2009
Generalized Gradient Approximation Made Simple [Phys. Rev. Lett. 77, 3865 (1996)] journal February 1997
Life History of the Metal–Organic Framework UiO-66 Catalyzing Methanol Dehydration: Synthesis, Activation, Deactivation, and Demise journal March 2022
Kinetic Investigation of η-Al2O3 Catalyst for Dimethyl Ether Production journal February 2018
Structure and Dynamics of Zr 6 O 8 Metal–Organic Framework Node Surfaces Probed with Ethanol Dehydration as a Catalytic Test Reaction journal February 2018
Defect-Engineered Metal-Organic Frameworks journal June 2015
Metal–Organic Frameworks in Heterogeneous Catalysis: Recent Progress, New Trends, and Future Perspectives journal March 2020
Unusual and Highly Tunable Missing-Linker Defects in Zirconium Metal–Organic Framework UiO-66 and Their Important Effects on Gas Adsorption journal May 2013
Pair sites on Al3O nodes of the metal-organic framework MIL-100: Cooperative roles of defect and structural vacancy sites in methanol dehydration catalysis journal December 2021
Water Adsorption in Porous Metal–Organic Frameworks and Related Materials journal March 2014
Dehydration of Alcohols on Aluminum Oxide journal October 1968
Presence versus Proximity: The Role of Pendant Amines in the Catalytic Hydrolysis of a Nerve Agent Simulant journal January 2018
Intrinsic and global reaction rate of methanol dehydration over .gamma.-alumina pellets journal April 1992
Computational Design of Functionalized Metal–Organic Framework Nodes for Catalysis journal December 2017
Node-Accessible Zirconium MOFs journal December 2020
Metal–Organic Frameworks in Solid–Gas Phase Catalysis journal November 2018
Mechanistic Study of Alcohol Dehydration on γ-Al 2 O 3 journal July 2012
A new local density functional for main-group thermochemistry, transition metal bonding, thermochemical kinetics, and noncovalent interactions journal November 2006
Zr‐MOF‐808 as Catalyst for Amide Esterification journal December 2020
Alumina: Catalyst and Support. I. Alumina, its Intrinsic Acidity and Catalytic Activity 1 journal May 1960
The Chemistry and Applications of Metal-Organic Frameworks journal August 2013
Dialing in Catalytic Sites on Metal Organic Framework Nodes: MIL-53(Al) and MIL-68(Al) Probed with Methanol Dehydration Catalysis journal November 2020
Surface chemistry of carbon-templated mesoporous aluminas journal January 2009
Mechanistic Investigation of Isopropanol Conversion on Alumina Catalysts: Location of Active Sites for Alkene/Ether Production journal June 2015
Production of Syngas by Direct Catalytic Oxidation of Methane journal January 1993
Infrared spectra of surface hydroxyl groups and crystalline structure of oxides journal December 1973
Elucidating and Tuning Catalytic Sites on Zirconium- and Aluminum-Containing Nodes of Stable Metal–Organic Frameworks journal April 2021
Density Functional Theory-Computed Mechanisms of Ethylene and Diethyl Ether Formation from Ethanol on γ-Al 2 O 3 (100) journal August 2013

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