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Replacing Trimethylsilyl with Triisopropylsilyl Provides Crystalline (C 5 H 4 SiR 3 ) 3 Th Complexes of Th(III) and Th(II)

Journal Article · · Organometallics
 [1];  [2];  [2];  [2];  [2];  [2]
  1. Department of Chemistry, University of California, Irvine, California 92697-2025, United States; OSTI
  2. Department of Chemistry, University of California, Irvine, California 92697-2025, United States
+ Show Author Affiliations

Not provided.

Research Organization:
Univ. of California, Irvine, CA (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
SC0004739
OSTI ID:
2419654
Journal Information:
Organometallics, Journal Name: Organometallics Journal Issue: 19 Vol. 42; ISSN 0276-7333
Publisher:
American Chemical Society
Country of Publication:
United States
Language:
English

References (57)

A Room-Temperature Stable Y(II) Aryloxide: Using Steric Saturation to Kinetically Stabilize Y(II) Complexes journal February 2020
Expanding Thorium Hydride Chemistry Through Th 2+ , Including the Synthesis of a Mixed-Valent Th 4+ /Th 3+ Hydride Complex journal March 2016
Isolation of U( ii ) compounds using strong donor ligands, C 5 Me 4 H and N(SiMe 3 ) 2 , including a three-coordinate U( ii ) complex journal January 2019
Structural, Spectroscopic, and Theoretical Comparison of Traditional vs Recently Discovered Ln 2+ Ions in the [K(2.2.2-cryptand)][(C 5 H 4 SiMe 3 ) 3 Ln] Complexes: The Variable Nature of Dy 2+ and Nd 2+ journal December 2014
Organometallic chemistry of the actinides journal January 1998
An improved method for the computation of ligand steric effects based on solid angles journal January 2006
Synthesis and Characterization of a Neutral U(II) Arene Sandwich Complex journal November 2018
Comparative assessment of a new nonempirical density functional: Molecules and hydrogen-bonded complexes journal December 2003
Synthesis, Structure, and Reactivity of the Sterically Crowded Th 3+ Complex (C 5 Me 5 ) 3 Th Including Formation of the Thorium Carbonyl, [(C 5 Me 5 ) 3 Th(CO)][BPh 4 ] journal February 2017
New developments in actinide alkoxide chemistry journal March 1992
The synthesis and characterisation, including X-ray diffraction study, of [Th{η-C 5 H 3 (SiMe 3 ) 2 } 3 ]; the first thorium( III ) crystal structure journal January 1986
Delivery of a Masked Uranium(II) by an Oxide‐Bridged Diuranium(III) Complex journal December 2020
TURBOMOLE: Modular program suite for ab initio quantum-chemical and condensed-matter simulations journal May 2020
Isolation of a Square-Planar Th(III) Complex: Synthesis and Structure of [Th(OC 6 H 2 t Bu 2 -2,6-Me-4) 4 ] 1– journal July 2019
Chemistry of Tris(pentamethylcyclopentadienyl) f-Element Complexes, (C 5 Me 5 ) 3 M journal June 2002
Reactions of potassium-graphite journal March 1978
Electrochemical studies of tris(cyclopentadienyl)thorium and uranium complexes in the +2, +3, and +4 oxidation states journal January 2021
COSMO Implementation in TURBOMOLE: Extension of an efficient quantum chemical code towards liquid systems journal January 2000
Room-Temperature Stable Ln(II) Complexes Supported by 2,6-Diadamantyl Aryloxide Ligands journal January 2023
Expanding the Chemistry of Molecular U 2+ Complexes: Synthesis, Characterization, and Reactivity of the {[C 5 H 3 (SiMe 3 ) 2 ] 3 U} − Anion journal December 2015
Tutorial on the Role of Cyclopentadienyl Ligands in the Discovery of Molecular Complexes of the Rare-Earth and Actinide Metals in New Oxidation States journal September 2016
Chemical structure and bonding in a thorium( iii )–aluminum heterobimetallic complex journal January 2018
Synthesis, properties and structures of the tris(cyclopentadienyl)thorium(III) complexes [Th{η5-C5H3(SiMe2R)2-1,3}3] (R=Me or tBu) journal November 2001
Importance of Energy Level Matching for Bonding in Th 3+ -Am 3+ Actinide Metallocene Amidinates, (C 5 Me 5 ) 2 [ i PrNC(Me)N i Pr]An journal November 2010
A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu journal April 2010
In search of tris(trimethylsilylcyclopentadienyl) thorium journal January 2019
Auxiliary basis sets for main row atoms and transition metals and their use to approximate Coulomb potentials
  • Eichkorn, Karin; Weigend, Florian; Treutler, Oliver
  • Theoretical Chemistry Accounts: Theory, Computation, and Modeling (Theoretica Chimica Acta), Vol. 97, Issue 1-4 https://doi.org/10.1007/s002140050244
journal October 1997
The synthesis and versatile reducing power of low-valent uranium complexes journal January 2020
Complex of Dinitrogen with Trivalent Uranium journal January 1998
Pentamethylcyclopentadienyl organoactinides. Trivalent uranium organometallic chemistry and the unusual structure of bis(pentamethylcyclopentadienyl)uranium monochloride journal August 1979
Synthesis, structure, and catalytic activity of an organothorium hydride complex journal November 2011
The coordination and organometallic chemistry of UI3 and U{N(SiMe3)2}3: Synthetic reagents par excellence journal December 2012
Sterically encumbered mixed sandwich compounds of uranium(III): Synthesis and reactivity with small molecules journal February 2018
The First Example of a Crystalline Subvalent Organolanthanum Complex:  [K([18]crown-6)- (η 2 -C 6 H 6 ) 2 ][(LaCp tt 2 ) 2 (μ-η 6 :η 6 -C 6 H 6 )]•2C 6 H 6 (Cp tt = η 5 -C 5 H 3 Bu t 2 -1,3) journal December 1998
Actinide Metallocene Hydride Chemistry: C–H Activation in Tetramethylcyclopentadienyl Ligands to Form [μ-η 5 -C 5 Me 3 H(CH 2 )- κC ] 2– Tuck-over Ligands in a Tetrathorium Octahydride Complex journal October 2013
Actinide covalency measured by pulsed electron paramagnetic resonance spectroscopy journal December 2016
Segmented contraction scheme for small-core actinide pseudopotential basis sets journal March 2004
Spectra of Na-, K-, and e-solv in amines and ethers journal October 1972
Trimethylsilylcyclopentadienyl (Cp ′ ) Uranium Chemistry: Synthetic and Structural Studies of Cp ′ 4 U and Cp ′ 3 U X ( X = Cl, I, Me) : Trimethylsilylcyclopentadienyl (Cp journal June 2015
Expanding the chemistry of U3+ reducing agents journal April 2006
A Uranium(II) Arene Complex That Acts as a Uranium(I) Synthon journal November 2021
Efficient use of the correlation consistent basis sets in resolution of the identity MP2 calculations journal February 2002
Synthesis and characterization of trimethylsilylmethyl-, bis(trimethylsilyl)methyl-and silyl-substituted cyclopentadienes and their alkali metal complexes1Dedicated to Professor Ken Wade, as a mark of friendship and as a recognition of his many contributions to chemistry.1 journal January 1998
Synthesis and Characterization of a Uranium(II) Monoarene Complex Supported by δ  Backbonding journal May 2014
CRC Handbook of Chemistry and Physics book June 2016
Synthesis, Characterization, and Structures of Uranium(III) N , N -Dimethylaminodiboranates journal June 2010
Facile solution routes to hydrocarbon-soluble Lewis base adducts of thorium tetrahalides. Synthesis, characterization, and x-ray structure of ThBr4(THF)4 journal April 1992
Identification of the +2 Oxidation State for Uranium in a Crystalline Molecular Complex, [K(2.2.2-Cryptand)][(C 5 H 4 SiMe 3 ) 3 U] journal August 2013
Metallboranate und Boranatometallate. 13 [1]. Darstellung und Molek�lstruktur von Uran(III)-tetrahydridoborat-3-Tetrahydrofuran journal December 1986
A crystalline tri-thorium cluster with σ-aromatic metal–metal bonding journal August 2021
Isolation of a Perfectly Linear Uranium(II) Metallocene journal February 2020
Synthesis, structure, and reactivity of crystalline molecular complexes of the {[C 5 H 3 (SiMe 3 ) 2 ] 3 Th} 1− anion containing thorium in the formal +2 oxidation state journal January 2015
Synthesis and Characterization of the First Sandwich Complex of Trivalent Thorium:  A Structural Comparison with the Uranium Analogue journal July 1999
The Triisopropylsilyl Group in Organic Chemistry: Just a Protective Group, or More? journal June 1995
Semiempirical GGA-type density functional constructed with a long-range dispersion correction journal January 2006
One‐Step Synthesis and Schlenk‐Type Equilibrium of Cyclopentadienylmagnesium Bromides journal October 2021
An Improved Synthesis of Sodium and Potassium Cyclopentadienide journal January 2003

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