Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Catalytic Potential of [B 12 X 11 ] 2– ( X = F, Cl, Br, I, CN) Dianions

Journal Article · · Journal of Physical Chemistry Letters
 [1];  [2]
  1. Department of Physics, Virginia Commonwealth University, Richmond, Virginia 23284-2000, United States; OSTI
  2. Department of Physics, Virginia Commonwealth University, Richmond, Virginia 23284-2000, United States
Not provided.
Research Organization:
Virginia Commonwealth Univ., Richmond, VA (United States); Univ. of California, Oakland, CA (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
FG02-96ER45579; AC02-05CH11231
OSTI ID:
2419471
Journal Information:
Journal of Physical Chemistry Letters, Journal Name: Journal of Physical Chemistry Letters Journal Issue: 39 Vol. 14; ISSN 1948-7185
Publisher:
American Chemical Society
Country of Publication:
United States
Language:
English

References (24)

From an Icosahedron to a Plane: Flattening Dodecaiodo-dodecaborate by Successive Stripping of Iodine journal September 2012
Superhalogens as Building Blocks of Halogen-Free Electrolytes in Lithium-Ion Batteries journal October 2014
Polyhedral skeletal electron pair approach journal September 1984
Superelectrophilic Behavior of an Anion Demonstrated by the Spontaneous Binding of Noble Gases to [B 12 Cl 11 ] journal May 2017
Doubly charged negative ions of carbon-60 journal September 1991
High resolution photoelectron spectroscopy of C60− journal May 1999
THE ISOLATION OF THE ICOSAHEDRAL B 12 H 12 -2 ION journal June 1960
Properties of gaseous closo -[B 6 X 6 ] 2− dianions (X = Cl, Br, I) journal January 2020
Relevance of π‐Backbonding for the Reactivity of Electrophilic Anions [B 12 X 11 ] (X=F, Cl, Br, I, CN) journal June 2021
Synthesis and Applications of Perfunctionalized Boron Clusters journal February 2018
The structural significance of the number of skeletal bonding electron-pairs in carboranes, the higher boranes and borane anions, and various transition-metal carbonyl cluster compounds journal January 1971
NMR Confirmation for Formation of [B 12 H 12 ] 2- Complexes during Hydrogen Desorption from Metal Borohydrides journal March 2008
Rational design of an argon-binding superelectrophilic anion journal April 2019
Development of the Colle-Salvetti correlation-energy formula into a functional of the electron density journal January 1988
STRUCTURE OF B 12 H 12 - 2 ION journal August 1960
Synthesis of [B12H12]2− based extractants and their application for the treatment of nuclear wastes journal September 2002
Collision-induced gas-phase reactions of perhalogenated closo-dodecaborate clusters – a comparative study journal January 2011
Binding of noble gas atoms by superhalogens journal July 2021
Gas phase fragmentation of adducts between dioxygen and closo-borate radical anions journal February 2019
A Unifying Electron-Counting Rule for Macropolyhedral Boranes, Metallaboranes, and Metallocenes
  • Jemmis, Eluvathingal D.; Balakrishnarajan, Musiri M.; Pancharatna, Pattath D.
  • Journal of the American Chemical Society, Vol. 123, Issue 18 https://doi.org/10.1021/ja003233z
journal May 2001
Stability of B 12 (CN) 12 2− : Implications for Lithium and Magnesium Ion Batteries journal February 2016
Chemische Synthese mit Gasförmigen Molekularen Ionen: Gewinnung von [B12Br11N2] aus einem Massenspektrometer journal August 2023
Role of ligands in the stability of B n X n and CB n−1 X n (n = 5–10; X = H, F, CN) and their potential as building blocks of electrolytes in lithium ion batteries journal January 2017
Spermidinium closo-dodecaborate-encapsulating liposomes as efficient boron delivery vehicles for neutron capture therapy journal January 2014

Similar Records

B 12 (SCN) 12 : An Ultrastable Weakly Coordinating Dianion
Journal Article · 2017 · Journal of Physical Chemistry. C · OSTI ID:1480464

Properties of gaseous closo -[B 6 X 6 ] 2− dianions (X = Cl, Br, I)
Journal Article · 2020 · Physical Chemistry Chemical Physics. PCCP · OSTI ID:1644133

Synthesis, Electronic Properties and Reactivity of [B12X11(NO2)]2– (X=F–I) Dianions
Journal Article · 2020 · Chemistry - A European Journal · OSTI ID:1770561