Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Programmed Polarizability Engineering in a Cyclen-Based Cubic Zr(IV) Metal–Organic Framework to Boost Xe/Kr Separation

Journal Article · · Journal of the American Chemical Society
DOI:https://doi.org/10.1021/jacs.2c13171· OSTI ID:2419252
 [1];  [2];  [3];  [3];  [3];  [3];  [3];  [4];  [2];  [4];  [5]
  1. School of Chemistry and Chemical Engineering, Frontiers Science Center for Transformative Molecules and State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, Shanghai 200240, China; Department of Chemistry and International Institute for Nanotechnology (IIN), Northwestern University, Evanston, Illinois 60208, United States; OSTI
  2. Department of Chemistry, University of Texas at San Antonio, One UTSA Circle, San Antonio, Texas 78249-0698, United States
  3. Department of Chemistry and International Institute for Nanotechnology (IIN), Northwestern University, Evanston, Illinois 60208, United States
  4. School of Chemistry and Chemical Engineering, Frontiers Science Center for Transformative Molecules and State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, Shanghai 200240, China
  5. Department of Chemistry and International Institute for Nanotechnology (IIN), Northwestern University, Evanston, Illinois 60208, United States; Department of Chemical & Biological Engineering, Northwestern University, Evanston, Illinois 60208, United States
Not provided.
Research Organization:
Northwestern Univ., Evanston, IL (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
FG02-08ER15967
OSTI ID:
2419252
Journal Information:
Journal of the American Chemical Society, Journal Name: Journal of the American Chemical Society Journal Issue: 4 Vol. 145; ISSN 0002-7863
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English

References (62)

Microporous Metal-Organic Framework Materials for Gas Separation journal February 2020
DOTA-Branched Organic Frameworks as Giant and Potent Metal Chelators journal December 2019
Efficient C 2 H 2 /CO 2 Separation in Ultramicroporous Metal–Organic Frameworks with Record C 2 H 2 Storage Density journal August 2021
Robust and Radiation-Resistant Hofmann-Type Metal–Organic Frameworks for Record Xenon/Krypton Separation journal February 2022
Xenon Gas Separation and Storage Using Metal-Organic Frameworks journal March 2018
Boosting Selective Adsorption of Xe over Kr by Double-Accessible Open-Metal Site in Metal–Organic Framework: Experimental and Theoretical Research journal July 2020
Propylene/propane plasticization in polyimide membranes journal March 2016
Rational design of mixed-matrix metal-organic framework membranes for molecular separations journal June 2022
Utilization of cationic microporous metal-organic framework for efficient Xe/Kr separation journal June 2022
A local hydrophobic environment in a metal–organic framework for boosting photocatalytic CO 2 reduction in the presence of water journal January 2019
Creating Optimal Pockets in a Clathrochelate-Based Metal–Organic Framework for Gas Adsorption and Separation: Experimental and Computational Studies journal February 2022
Employing an Unsaturated Th 4+ Site in a Porous Thorium-Organic Framework for Kr/Xe Uptake and Separation journal April 2018
Enhanced noble gas adsorption in Ag@MOF-74Ni journal January 2014
Metal–organic framework with optimally selective xenon adsorption and separation journal June 2016
Shell‐like Xenon Nano‐Traps within Angular Anion‐Pillared Layered Porous Materials for Boosting Xe/Kr Separation journal January 2022
Metal–Organic Framework Based Hydrogen-Bonding Nanotrap for Efficient Acetylene Storage and Separation journal December 2021
Porous metal–organic framework based on a macrocyclic tetracarboxylate ligand exhibiting selective CO2 uptake journal January 2012
Hydrocarbon Separation: Designer Metal–Organic Frameworks for Size‐Exclusion‐Based Hydrocarbon Separations: Progress and Challenges (Adv. Mater. 44/2020) journal November 2020
Selective gas adsorption and separation in metal–organic frameworks journal January 2009
Polarizability of the nitrate anion and its solvation at the air/water interface journal January 2003
Porous organic materials with ultra-small pores and sulfonic functionality for xenon capture with exceptional selectivity journal January 2018
Metal-Organic Frameworks for Separation journal March 2018
Noble Gas Adsorption in Metal–Organic Frameworks Containing Open Metal Sites
  • Perry, John J.; Teich-McGoldrick, Stephanie L.; Meek, Scott T.
  • The Journal of Physical Chemistry C, Vol. 118, Issue 22, p. 11685-11698 https://doi.org/10.1021/jp501495f
journal May 2014
Docking of Cu I and Ag I in Metal–Organic Frameworks for Adsorption and Separation of Xenon journal January 2021
Synthesis of MOF‐525 Derived Nanoporous Carbons with Different Particle Sizes for Supercapacitor Application journal October 2017
Breakthrough in Xenon Capture and Purification Using Adsorbent-Supported Silver Nanoparticles journal June 2016
Controlling guest conformation for efficient purification of butadiene journal June 2017
Potential of Metal–Organic Frameworks for Separation of Xenon and Krypton journal December 2014
Separation of Xe from Kr with Record Selectivity and Productivity in Anion‐Pillared Ultramicroporous Materials by Inverse Size‐Sieving journal January 2020
The first example of commensurate adsorption of atomic gas in a MOF and effective separation of xenon from other noble gases journal January 2014
A New Class of Metal-Cyclam-Based Zirconium Metal–Organic Frameworks for CO 2 Adsorption and Chemical Fixation journal January 2018
Energy-efficient separation alternatives: metal–organic frameworks and membranes for hydrocarbon separation journal January 2020
Robust Bimetallic Ultramicroporous Metal–Organic Framework for Separation and Purification of Noble Gases journal March 2020
Water-resistant porous coordination polymers for gas separation journal February 2017
A Robust Squarate-Based Metal–Organic Framework Demonstrates Record-High Affinity and Selectivity for Xenon over Krypton journal May 2019
Crystal Engineering of an nbo Topology Metal-Organic Framework for Chemical Fixation of CO 2 under Ambient Conditions journal February 2014
Synthesis, Structure, and Metalation of Two New Highly Porous Zirconium Metal–Organic Frameworks journal June 2012
Stabilizing Porosity in Organic Cages through Coordination Chemistry journal April 2021
Mechanical gas capture and release in a network solid via multiple single-crystalline transformations journal January 2008
Self‐Adjusting Metal–Organic Framework for Efficient Capture of Trace Xenon and Krypton journal January 2022
Hydrocarbon Separations in Metal–Organic Frameworks journal September 2013
Direct Observation of Xe and Kr Adsorption in a Xe-Selective Microporous Metal–Organic Framework journal May 2015
In Silico Study of (Mn, Fe, Co, Ni, Zn)-BTC Metal–Organic Frameworks for Recovering Xenon from Exhaled Anesthetic Gas journal September 2018
Hybrid Ultra-Microporous Materials for Selective Xenon Adsorption and Separation journal May 2016
Orbital Trap of Xenon: Driving Force Distinguishing between Xe and Kr Found at a Single Ag(I) Site in MFI Zeolite at Room Temperature journal May 2022
Metal–Organic Frameworks for Separations journal September 2011
Synergistic sorbent separation for one-step ethylene purification from a four-component mixture journal October 2019
Polarizable molecular dynamics simulations of ionic liquids: Influence of temperature control journal March 2020
Isoreticular chemistry within metal–organic frameworks for gas storage and separation journal September 2021
Introduction to Reticular Chemistry journal January 2019
Ab Initio Study of Adsorption of Fission Gas Atoms Xe and Kr on MoS2 Monolayer Functionalized with 3d Transition Metals journal January 2021
A comparative study of silver- and palladium-exchanged zeolites in propylene and nitrogen oxide adsorption and desorption for cold-start applications journal January 2021
The Chemistry and Applications of Metal-Organic Frameworks journal August 2013
Computational Modeling of Adsorption of Xe and Kr in M-MOF-74 Metal Organic Frame Works with Different Metal Atoms journal May 2016
Investigation of prototypal MOFs consisting of polyhedral cages with accessible Lewis-acid sites for quinoline synthesis journal January 2015
Trace removal of benzene vapour using double-walled metal–dipyrazolate frameworks journal April 2022
Optimizing Multivariate Metal–Organic Frameworks for Efficient C 2 H 2 /CO 2 Separation journal March 2020
Tailoring Pore Aperture and Structural Defects in Zirconium-Based Metal–Organic Frameworks for Krypton/Xenon Separation journal February 2020
Pore Space Partition in Metal–Organic Frameworks journal January 2017
Enhanced Adsorption and Separation of Xenon over Krypton via an Unsaturated Calcium Center in a Metal–Organic Framework journal January 2021
Recent Progress on Microfine Design of Metal–Organic Frameworks: Structure Regulation and Gas Sorption and Separation journal July 2020
Pore-Space-Partition-Enabled Exceptional Ethane Uptake and Ethane-Selective Ethane–Ethylene Separation journal January 2020

Similar Records

Squeezing the box: isoreticular contraction of pyrene-based linker in a Zr-based metal–organic framework for Xe/Kr separation
Journal Article · 2020 · Dalton Transactions · OSTI ID:1800556

Tröger’s Base Chemistry in Solution and in Zr(IV)-Based Metal–Organic Frameworks
Journal Article · 2022 · Journal of the American Chemical Society · OSTI ID:2419251

Related Subjects