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Homoleptic Al(III) Photosensitizers for Durable CO 2 Photoreduction

Journal Article · · Journal of the American Chemical Society
DOI:https://doi.org/10.1021/jacs.2c11740· OSTI ID:2419184
 [1];  [2];  [3];  [2];  [4];  [5];  [6];  [3];  [3];  [3];  [3];  [7];  [8];  [2];  [8];  [2]
  1. College of Chemistry and Chemical Engineering, Central South University, Changsha410083, China; Institute of Chemical Research of Catalonia (ICIQ), Barcelona Institute of Science and Technology (BIST), Tarragona43007, Spain; OSTI
  2. College of Chemistry and Chemical Engineering, Central South University, Changsha410083, China
  3. Department of Chemistry, Emory University, 1515 Dickey Drive, Northeast, Atlanta, Georgia30322, United States
  4. Institute of Chemical Research of Catalonia (ICIQ), Barcelona Institute of Science and Technology (BIST), Tarragona43007, Spain
  5. Institute of Physical Chemistry, Friedrich Schiller University Jena, Helmholtzweg 4, Jena07743, Germany
  6. Department of Energy Conversion, Institute of Physical and Theoretical Chemistry, Technische Universität Braunschweig, Braunschweig38106, Germany
  7. Department of Chemistry, Shantou University Medical College, Shantou515041, China
  8. KLGHEI of Environment and Energy Chemistry, School of Chemistry, Sun Yat-Sen University, Guangzhou510275, China
Not provided.
Research Organization:
Emory Univ., Atlanta, GA (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
FG02-07ER15906
OSTI ID:
2419184
Journal Information:
Journal of the American Chemical Society, Journal Name: Journal of the American Chemical Society Journal Issue: 1 Vol. 145; ISSN 0002-7863
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English

References (92)

Visible-Light Photocatalytic Conversion of Carbon Dioxide by Ni(II) Complexes with N4S2 Coordination: Highly Efficient and Selective Production of Formate journal October 2020
Chemical composition of Earth, Venus, and Mercury journal December 1980
A CdSe/ZnS quantum dot-based platform for the delivery of aluminum phthalocyanines to bacterial cells journal October 2018
Selectivity control of CO versus HCOO− production in the visible-light-driven catalytic reduction of CO2 with two cooperative metal sites journal August 2019
Temperature dependence of the singlet excited state lifetime in alq3 journal June 1999
An Unusual and Facile Synthetic Route to Alumoles journal April 2020
Ligand Exchange Dynamics in Aluminum Tris-(Quinoline-8-olate):  A Solution State NMR Study journal January 2003
Highly Luminescent Heavier Main Group Analogues of Boron-Dipyrromethene journal May 2019
Co-facial π–π Interaction Expedites Sensitizer-to-Catalyst Electron Transfer for High-Performance CO2 Photoreduction journal April 2022
Earth-Abundant Photocatalytic CO 2 Reduction by Multielectron Chargeable Cobalt Porphyrin Catalysts: High CO/H 2 Selectivity in Water Based on Phase Mismatch in Frontier MO Association journal August 2021
Photocatalytic CO2 Reduction Using a Robust Multifunctional Iridium Complex toward the Selective Formation of Formic Acid journal May 2020
Function-Integrated Ru Catalyst for Photochemical CO 2 Reduction journal November 2018
Luminescent Tris(8-hydroxyquinolates) of Bismuth(III) journal October 2013
Electrocatalytic and homogeneous approaches to conversion of CO 2 to liquid fuels journal January 2009
Copper’s rapid ascent in visible-light photoredox catalysis journal May 2019
Promoting photocatalytic CO2 reduction with a molecular copper purpurin chromophore journal March 2021
Visible-light Homogeneous Photocatalytic Conversion of CO 2 into CO in Aqueous Solutions with an Iron Catalyst journal October 2017
Photo- and Electrochemical Properties of a CO 2 Reducing Ruthenium-Rhenium Quaterpyridine-Based Catalyst journal February 2018
Design of BODIPY dyes as triplet photosensitizers: electronic properties tailored for solar energy conversion, photoredox catalysis and photodynamic therapy journal January 2021
Selective and Efficient Photocatalytic CO 2 Reduction to CO Using Visible Light and an Iron-Based Homogeneous Catalyst journal November 2014
Photocatalytic CO 2 Reduction Using Cu(I) Photosensitizers with a Fe(II) Catalyst journal March 2016
Towards molecular understanding of local chemical environment effects in electro- and photocatalytic CO2 reduction journal September 2020
Efficient Visible-Light-Driven CO 2 Reduction by a Cobalt Molecular Catalyst Covalently Linked to Mesoporous Carbon Nitride journal March 2020
Direct triplet sensitization of oligothiophene by quantum dots journal January 2019
Heteroleptic copper complexes with nitrogen and phosphorus ligands in photocatalysis: Overview and perspectives journal July 2021
Selective Earth-Abundant System for CO 2 Reduction: Comparing Photo- and Electrocatalytic Processes journal January 2019
Luminescent First-Row Transition Metal Complexes journal September 2021
Highly Efficient and Robust Photocatalytic Systems for CO 2 Reduction Consisting of a Cu(I) Photosensitizer and Mn(I) Catalysts journal November 2018
Photophysics and photochemistry with Earth-abundant metals – fundamentals and concepts journal January 2020
Photocatalytic Conversion of CO2 to CO by a Copper(II) Quaterpyridine Complex journal September 2017
Dinuclear Metal Synergistic Catalysis Boosts Photochemical CO 2 -to-CO Conversion journal November 2018
Improving Photocatalysis for the Reduction of CO 2 through Non-covalent Supramolecular Assembly journal September 2019
Electro- and Solar-Driven Fuel Synthesis with First Row Transition Metal Complexes journal October 2018
Syngas Production with a Highly-Robust Nickel(II) Homogeneous Electrocatalyst in a Water-Containing System journal July 2018
Assessment of the Electronic Structure of 2,2′-Pyridylpyrrolides as Ligands journal September 2011
Earth-abundant photocatalytic systems for the visible-light-driven reduction of CO 2 to CO journal January 2017
Molecular Catalysis of the Electrochemical and Photochemical Reduction of CO 2 with Earth-Abundant Metal Complexes. Selective Production of CO vs HCOOH by Switching of the Metal Center journal August 2015
Photocatalytic CO2 reduction with high turnover frequency and selectivity of formic acid formation using Ru(II) multinuclear complexes journal August 2012
Photochemical CO 2 Reduction Driven by Water-Soluble Copper(I) Photosensitizer with the Catalysis Accelerated by Multi-Electron Chargeable Cobalt Porphyrin journal October 2019
Improving photosensitization for photochemical CO2-to-CO conversion journal May 2020
Death and Rebirth: Photocatalytic Hydrogen Production by a Self-Organizing Copper–Iron System journal April 2014
A Highly Fluorescent Dinuclear Aluminium Complex with Near‐Unity Quantum Yield** journal February 2022
Systematic Control of the Overlapping Energy Region for an Efficient Intramolecular Energy Transfer: Functionalized Salen–Al/Triphenylamine Guest–Host Assemblies journal January 2019
Neutral Cyclometalated Ir(III) Complexes with Pyridylpyrrole Ligand for Photocatalytic Hydrogen Generation from Water journal April 2021
Highly Selective Molecular Catalysts for the CO 2 -to-CO Electrochemical Conversion at Very Low Overpotential. Contrasting Fe vs Co Quaterpyridine Complexes upon Mechanistic Studies journal March 2018
Proton nuclear magnetic resonance studies of 8-quinolinol and several of its metal complexes journal November 1968
Mechanistic Insights into Co and Fe Quaterpyridine-Based CO 2 Reduction Catalysts: Metal–Ligand Orbital Interaction as the Key Driving Force for Distinct Pathways journal January 2021
A rhenium catalyst with bifunctional pyrene groups boosts natural light-driven CO2 reduction journal January 2020
Combination of Organic Dye and Iron for CO2 Reduction with Pentanuclear Fe2Na3 Purpurin Photocatalysts journal March 2022
Synthesis and Properties of Salen–Aluminum Complexes as a Novel Class of Color‐Tunable Luminophores journal June 2009
Photoredox Catalysis with Metal Complexes Made from Earth-Abundant Elements journal November 2017
Visible-Light-Driven Conversion of CO 2 to CH 4 with an Organic Sensitizer and an Iron Porphyrin Catalyst journal December 2018
Water Reduction Systems Associated with Homoleptic Cyclometalated Iridium Complexes of Various 2‐Phenylpyridines journal July 2013
Open for Bismuth: Main Group Metal-to-Ligand Charge Transfer journal June 2021
Synthesis of a new family of ionophores based on aluminum–dipyrrin complexes (ALDIPYs) and their strong recognition of alkaline earth ions journal January 2016
An earth-abundant system for light-driven CO2 reduction to CO using a pyridinophane iron catalyst journal January 2019
Durable Solar-Powered Systems with Ni-Catalysts for Conversion of CO 2 or CO to CH 4 journal March 2019
Bright luminescent lithium and magnesium carbene complexes journal January 2021
Dinuclear Triple‐Stranded Helicates Composed of Tetradentate Ligands with Aluminum(III) Chromophores: Optical Resolution and Multi‐color Circularly Polarized Luminescence Properties journal December 2020
Photocatalytic reduction of CO2 using metal complexes journal December 2015
Selective Photoactivation of Trithiocarbonates Mediated by Metal Naphthalocyanines and Overcoming Activation Barriers Using Thermal Energy journal January 2022
Efficient and selective electron mediation of cobalt complexes with cyclam and related macrocycles in the p-terphenyl-catalyzed photoreduction of carbon dioxide journal January 1993
Photoactive mono- and polynuclear Cu(i)–phenanthrolines. A viable alternative to Ru(ii)–polypyridines? journal January 2001
Highly Efficient and Selective Photocatalytic CO 2 Reduction by Iron and Cobalt Quaterpyridine Complexes journal July 2016
Heteroleptic Copper(I) Complexes Prepared from Phenanthroline and Bis-Phosphine Ligands journal September 2013
Luminescence and reactivity of a charge-transfer excited iron complex with nanosecond lifetime journal November 2018
Cobalt and nickel complexes of 2,2′ : 6′,2″ : 6″,2‴-quaterpyridine as catalysts for electrochemical reduction of carbon dioxide journal January 1995
Metal-complex chromophores for solar hydrogen generation journal January 2017
Facile electron delivery from graphene template to ultrathin metal-organic layers for boosting CO2 photoreduction journal February 2021
Intensely Photoluminescent Diamidophosphines of the Alkaline‐Earth Metals, Aluminum, and Zinc journal September 2018
A luminescent aluminium salen complex allows for monitoring dynamic vesicle trafficking from the Golgi apparatus to lysosomes in living cells journal January 2018
Rapid electron transfer via dynamic coordinative interaction boosts quantum efficiency for photocatalytic CO2 reduction journal July 2021
Tailored self-assembled photocatalytic nanofibres for visible-light-driven hydrogen production journal November 2020
Mechanistic Insights Into Iron(II) Bis(pyridyl)amine‐Bipyridine Skeleton for Selective CO 2 Photoreduction journal November 2021
Heteroleptic diimine–diphosphine Cu(I) complexes as an alternative towards noble-metal based photosensitizers: Design strategies, photophysical properties and perspective applications journal February 2018
Highly Efficient Photocatalytic Reduction of CO2 to CO by In Situ Formation of a Hybrid Catalytic System Based on Molecular Iron Quaterpyridine Covalently Linked to Carbon Nitride journal January 2022
Delayed fluorescence from a zirconium(iv) photosensitizer with ligand-to-metal charge-transfer excited states journal March 2020
Photocatalytic Reduction of Low Concentration of CO 2 journal October 2016
Novel Series of Mononuclear Aluminum Complexes for High‐Performance Solution‐Processed Organic Light‐Emitting Devices journal January 2021
Photocatalytic Hydrogen Evolution with a Self‐Assembling Reductant–Sensitizer–Catalyst System journal June 2013
Aluminum(III) Salen Complexes as Active Photoredox Catalysts journal September 2019
Electrons, Photons, Protons and Earth-Abundant Metal Complexes for Molecular Catalysis of CO 2 Reduction journal November 2016
Exploitation of Long-Lived 3 IL Excited States for Metal–Organic Photodynamic Therapy: Verification in a Metastatic Melanoma Model journal October 2013
Electronic structure and molecular orbital study of the first excited state of the high‐efficiency blue OLED material bis(2‐methyl‐8‐quinolinolato)aluminum(III) hydroxide complex from ab initio and TD‐B3LYP journal December 2003
Quantum Dot-Sensitized Photoreduction of CO 2 in Water with Turnover Number > 80,000 journal October 2021
Photoactive Complexes with Earth-Abundant Metals journal September 2018
Versatile copper complexes as a convenient springboard for both dyes and redox mediators in dye sensitized solar cells journal September 2016
A Local Proton Source Enhances CO 2 Electroreduction to CO by a Molecular Fe Catalyst journal October 2012
Domino electroreduction of CO2 to methanol on a molecular catalyst journal November 2019
Comparison of two photosensitizers Al(III) phthalocyanine chloride tetrasulfonic acid and meso-tetrakis(4-sulfonatophenyl)porphyrin in the photooxidation of n-butylparaben journal September 2011
A salen–Al/carbazole dyad-based guest–host assembly: enhancement of luminescence efficiency via intramolecular energy transfer journal January 2018
Elucidating the Nature of the Excited State of a Heteroleptic Copper Photosensitizer by using Time-Resolved X-ray Absorption Spectroscopy journal April 2018

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