Air-Stable Cu(I) Metal–Organic Framework for Hydrogen Storage

Sengupta, Debabrata; Melix, Patrick; Bose, Saptasree; Duncan, Joshua; Wang, Xingjie; Mian, Mohammad Rasel; Kirlikovali, Kent O.; Joodaki, Faramarz; Islamoglu, Timur; Yildirim, Taner; Snurr, Randall Q.; Farha, Omar K.

doi:10.1021/jacs.3c06393

Air-Stable Cu(I) Metal–Organic Framework for Hydrogen Storage

Journal Article · 06 September 2023 · Journal of the American Chemical Society

DOI:https://doi.org/10.1021/jacs.3c06393· OSTI ID:2418691

^[1]; ^[2]; ^[3]; ^[3]; ^[3]; ^[3]; ^[3]; Joodaki, Faramarz ^[4]; ^[3]; Yildirim, Taner ^[5]; ^[4]; ^[6]

Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, United States; OSTI
Department of Chemical and Biological Engineering, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, United States; Wilhelm-Ostwald-Institut für Physikalische und Theoretische Chemie, Universität Leipzig, Linnéstraße 2, 04103 Leipzig, Germany
Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, United States
Department of Chemical and Biological Engineering, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, United States
NIST Center for Neutron Research, National Institute of Standards and Technology, Gaithersburg, Maryland 20899, United States
Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, United States; International Institute of Nanotechnology, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, United States; Department of Chemical and Biological Engineering, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, United States

Not provided.

Research Organization:: Northwestern Univ., Evanston, IL (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE)

DOE Contract Number:: EE0008816; SC0001329

OSTI ID:: 2418691

Journal Information:: Journal of the American Chemical Society, Journal Name: Journal of the American Chemical Society Journal Issue: 37 Vol. 145; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: English

References (41)

A Bis-Acetonitrile Two-Coordinate Copper(I) Complex: Synthesis and Characterization of Highly Soluble B(C₆F₅)₄^- Salts of [Cu(MeCN)₂]⁺ and [Cu(MeCN)₄]⁺ Liang, Hong-Chang; Kim, Eunsuk; Incarvito, Christopher D. Inorganic Chemistry, Vol. 41, Issue 8 https://doi.org/10.1021/ic010816g	journal	March 2002
Observation of an Intermediate to H ₂ Binding in a Metal–Organic Framework Barnett, Brandon R.; Evans, Hayden A.; Su, Gregory M. Journal of the American Chemical Society, Vol. 143, Issue 36 https://doi.org/10.1021/jacs.1c07223	journal	August 2021
Variable temperature infrared spectroscopy: A convenient tool for studying the thermodynamics of weak solid–gas interactions Garrone, Edoardo; Otero Areán, Carlos Chemical Society Reviews, Vol. 34, Issue 10 https://doi.org/10.1039/b407049f	journal	January 2005
Are you using the right probe molecules for assessing the textural properties of metal–organic frameworks? Islamoglu, Timur; Idrees, Karam B.; Son, Florencia A. Journal of Materials Chemistry A, Vol. 10, Issue 1 https://doi.org/10.1039/D1TA08021K	journal	January 2022
Modeling High-Pressure Hydrogen Uptake by Nanoporous Metal–Organic Frameworks: Implications for Hydrogen Storage and Delivery Ramirez-Vidal, Pamela; Canevesi, Rafael L. S.; Celzard, Alain ACS Applied Nano Materials, Vol. 5, Issue 1 https://doi.org/10.1021/acsanm.1c03493	journal	January 2022
Is catenation beneficial for hydrogen storage in metal–organic frameworks? Ryan, Patrick; Broadbelt, Linda J.; Snurr, Randall Q. Chemical Communications, Issue 35 https://doi.org/10.1039/b804343d	journal	January 2008
A spin transition mechanism for cooperative adsorption in metal–organic frameworks Reed, Douglas A.; Keitz, Benjamin K.; Oktawiec, Julia Nature, Vol. 550, Issue 7674 https://doi.org/10.1038/nature23674	journal	September 2017
Nanoporous Materials for the Onboard Storage of Natural Gas Kumar, K. Vasanth; Preuss, Kathrin; Titirici, Maria-Magdalena Chemical Reviews, Vol. 117, Issue 3 https://doi.org/10.1021/acs.chemrev.6b00505	journal	January 2017
Scorpionate-Type Coordination in MFU-4 l Metal-Organic Frameworks: Small-Molecule Binding and Activation upon the Thermally Activated Formation of Open Metal Sites Denysenko, Dmytro; Grzywa, Maciej; Jelic, Jelena Angewandte Chemie International Edition, Vol. 53, Issue 23 https://doi.org/10.1002/anie.201310004	journal	May 2014
Elucidating Gating Effects for Hydrogen Sorption in MFU-4-Type Triazolate-Based Metal-Organic Frameworks Featuring Different Pore Sizes Denysenko, Dmytro; Grzywa, Maciej; Tonigold, Markus Chemistry - A European Journal, Vol. 17, Issue 6 https://doi.org/10.1002/chem.201001872	journal	January 2011
Infrared spectra of hydrogen–rare-gas Van der Waals molecules McKellar, A. Robert W. Faraday Discuss. Chem. Soc., Vol. 73, Issue 0 https://doi.org/10.1039/DC9827300089	journal	January 1982
Role of Exposed Metal Sites in Hydrogen Storage in MOFs Vitillo, Jenny G.; Regli, Laura; Chavan, Sachin Journal of the American Chemical Society, Vol. 130, Issue 26, p. 8386-8396 https://doi.org/10.1021/ja8007159	journal	July 2008
Capture of heavy hydrogen isotopes in a metal-organic framework with active Cu(I) sites Weinrauch, I.; Savchenko, I.; Denysenko, D. Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms14496	journal	March 2017
Benchmark Study of Hydrogen Storage in Metal–Organic Frameworks under Temperature and Pressure Swing Conditions García-Holley, Paula; Schweitzer, Benjamin; Islamoglu, Timur ACS Energy Letters, Vol. 3, Issue 3 https://doi.org/10.1021/acsenergylett.8b00154	journal	February 2018
High Volumetric Hydrogen Storage Capacity using Interpenetrated Metal-Organic Frameworks Balderas-Xicohténcatl, Rafael; Schmieder, Phillip; Denysenko, Dmytro Energy Technology, Vol. 6, Issue 3 https://doi.org/10.1002/ente.201700608	journal	December 2017
Metal–organic frameworks with wine-rack motif: What determines their flexibility and elastic properties? Ortiz, Aurélie U.; Boutin, A.; Fuchs, Alain H. The Journal of Chemical Physics, Vol. 138, Issue 17 https://doi.org/10.1063/1.4802770	journal	May 2013
Experimental and Theoretical Studies of Gas Adsorption in Cu ₃ (BTC) ₂ : An Effective Activation Procedure Liu, Jinchen; Culp, Jeffrey T.; Natesakhawat, Sittichai The Journal of Physical Chemistry C, Vol. 111, Issue 26 https://doi.org/10.1021/jp071449i	journal	July 2007
The role of metal–organic frameworks in a carbon-neutral energy cycle Schoedel, Alexander; Ji, Zhe; Yaghi, Omar M. Nature Energy, Vol. 1, Issue 4 https://doi.org/10.1038/nenergy.2016.34	journal	April 2016
Highly Stable Porous Polymer Networks with Exceptionally High Gas-Uptake Capacities Yuan, Daqiang; Lu, Weigang; Zhao, Dan Advanced Materials, Vol. 23, Issue 32 https://doi.org/10.1002/adma.201101759	journal	July 2011
An assessment of strategies for the development of solid-state adsorbents for vehicular hydrogen storage Allendorf, Mark D.; Hulvey, Zeric; Gennett, Thomas Energy & Environmental Science, Vol. 11, Issue 10 https://doi.org/10.1039/C8EE01085D	journal	January 2018
Towards Non-Mechanical Hybrid Hydrogen Compression for Decentralized Hydrogen Facilities Sdanghi, Giuseppe; Maranzana, Gaël; Celzard, Alain Energies, Vol. 13, Issue 12 https://doi.org/10.3390/en13123145	journal	June 2020
Balancing volumetric and gravimetric uptake in highly porous materials for clean energy Chen, Zhijie; Li, Penghao; Anderson, Ryther Science, Vol. 368, Issue 6488 https://doi.org/10.1126/science.aaz8881	journal	April 2020
Hydrogen storage in metal–organic frameworks Murray, Leslie J.; Dincă, Mircea; Long, Jeffrey R. Chemical Society Reviews, Vol. 38, Issue 5, p. 1294-1314 https://doi.org/10.1039/b802256a	journal	January 2009
Cost and potential of metal–organic frameworks for hydrogen back-up power supply Peng, Peng; Anastasopoulou, Aikaterini; Brooks, Kriston Nature Energy, Vol. 7, Issue 5 https://doi.org/10.1038/s41560-022-01013-w	journal	April 2022
Porous materials for hydrogen storage Chen, Zhijie; Kirlikovali, Kent O.; Idrees, Karam B. Chem, Vol. 8, Issue 3 https://doi.org/10.1016/j.chempr.2022.01.012	journal	March 2022
Optimization of the Pore Structures of MOFs for Record High Hydrogen Volumetric Working Capacity Zhang, Xin; Lin, Rui-Biao; Wang, Jing Advanced Materials https://doi.org/10.1002/adma.201907995	journal	March 2020
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set Kresse, G.; Furthmüller, J. Physical Review B, Vol. 54, Issue 16, p. 11169-11186 https://doi.org/10.1103/PhysRevB.54.11169	journal	October 1996
Hydrogen storage in several microporous zeolites Dong, J.; Wang, X.; Xu, H. International Journal of Hydrogen Energy, Vol. 32, Issue 18 https://doi.org/10.1016/j.ijhydene.2007.08.009	journal	December 2007
A Practice of Reticular Chemistry: Construction of a Robust Mesoporous Palladium Metal–Organic Framework via Metal Metathesis He, Tao; Kong, Xiang-Jing; Zhou, Jian Journal of the American Chemical Society, Vol. 143, Issue 26 https://doi.org/10.1021/jacs.1c04077	journal	June 2021
The coordination- and photochemistry of copper(i) complexes: variation of N^N ligands from imidazole to tetrazole Bergmann, Larissa; Braun, Carolin; Nieger, Martin Dalton Transactions, Vol. 47, Issue 2 https://doi.org/10.1039/C7DT03682E	journal	January 2018
Microporous Manganese Formate: A Simple Metal−Organic Porous Material with High Framework Stability and Highly Selective Gas Sorption Properties Dybtsev, Danil N.; Chun, Hyungphil; Yoon, Sun Hong Journal of the American Chemical Society, Vol. 126, Issue 1 https://doi.org/10.1021/ja038678c	journal	January 2004
Materials Informatics with PoreBlazer v4.0 and the CSD MOF Database Sarkisov, Lev; Bueno-Perez, Rocio; Sutharson, Mythili Chemistry of Materials, Vol. 32, Issue 23 https://doi.org/10.1021/acs.chemmater.0c03575	journal	November 2020
Natural climate solutions for the United States Fargione, Joseph E.; Bassett, Steven; Boucher, Timothy Science Advances, Vol. 4, Issue 11 https://doi.org/10.1126/sciadv.aat1869	journal	November 2018
Department of Energy Hydrogen Program Plan McQueen, Shawna; Stanford, Joseph; Satyapal, Sunita https://doi.org/10.2172/1721803	report	November 2020
Effect of the damping function in dispersion corrected density functional theory Grimme, Stefan; Ehrlich, Stephan; Goerigk, Lars Journal of Computational Chemistry, Vol. 32, Issue 7 https://doi.org/10.1002/jcc.21759	journal	March 2011
Record High Hydrogen Storage Capacity in the Metal–Organic Framework Ni ₂ ( m -dobdc) at Near-Ambient Temperatures Kapelewski, Matthew T.; Runčevski, Tomče; Tarver, Jacob D. Chemistry of Materials, Vol. 30, Issue 22 https://doi.org/10.1021/acs.chemmater.8b03276	journal	October 2018
Generalized Gradient Approximation Made Simple Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868 https://doi.org/10.1103/PhysRevLett.77.3865	journal	October 1996
Evaluating topologically diverse metal–organic frameworks for cryo-adsorbed hydrogen storage Gómez-Gualdrón, Diego A.; Colón, Yamil J.; Zhang, Xu Energy & Environmental Science, Vol. 9, Issue 10 https://doi.org/10.1039/C6EE02104B	journal	January 2016
Molecular Spectra and Molecular Structure Huber, K. P.; Herzberg, G. https://doi.org/10.1007/978-1-4757-0961-2	book	January 1979
Fine-Tuning a Robust Metal–Organic Framework toward Enhanced Clean Energy Gas Storage Chen, Zhijie; Mian, Mohammad Rasel; Lee, Seung-Joon Journal of the American Chemical Society, Vol. 143, Issue 45 https://doi.org/10.1021/jacs.1c08749	journal	November 2021
Ambient-Temperature Hydrogen Storage via Vanadium(II)-Dihydrogen Complexation in a Metal–Organic Framework Jaramillo, David E.; Jiang, Henry Z. H.; Evans, Hayden A. Journal of the American Chemical Society, Vol. 143, Issue 16 https://doi.org/10.1021/jacs.1c01883	journal	April 2021

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