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Propane Dehydrogenation on Pt x Sn y ( x , y ≤ 4) Clusters on Al 2 O 3 (110)

Journal Article · · ACS Catalysis
 [1];  [2];  [3];  [3];  [2]
  1. RAPID Manufacturing Institute, Catalysis Center for Energy Innovation, Delaware Energy Institute, Center for Plastics Innovation, University of Delaware, 221 Academy Street, Newark, Delaware 19716, United States; OSTI
  2. RAPID Manufacturing Institute, Catalysis Center for Energy Innovation, Delaware Energy Institute, Center for Plastics Innovation, University of Delaware, 221 Academy Street, Newark, Delaware 19716, United States; Department of Chemical and Biomolecular Engineering, University of Delaware, 150 Academy St., Newark, Delaware 19716, United States
  3. RAPID Manufacturing Institute, Catalysis Center for Energy Innovation, Delaware Energy Institute, Center for Plastics Innovation, University of Delaware, 221 Academy Street, Newark, Delaware 19716, United States

Not provided.

Research Organization:
American Institute of Chemical Engineers (AIChE), New York, NY (United States)
Sponsoring Organization:
USDOE Office of Energy Efficiency and Renewable Energy (EERE)
DOE Contract Number:
EE0007888
OSTI ID:
2418539
Journal Information:
ACS Catalysis, Journal Name: ACS Catalysis Journal Issue: 5 Vol. 13; ISSN 2155-5435
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English

References (53)

Effects of composition and metal particle size on ethane dehydrogenation over PtxSn100−x/Mg(Al)O (70⩽x⩽100) journal March 2014
On the Role of Sn Segregation of Pt-Sn Catalysts for Propane Dehydrogenation journal March 2021
Size-Dependent Reaction Mechanism and Kinetics for Propane Dehydrogenation over Pt Catalysts journal September 2015
Pt–Sn alloy phases and coke mobility over Pt–Sn/Al2O3 and Pt–Sn/ZnAl2O4 catalysts for propane dehydrogenation journal June 2011
Special points for Brillouin-zone integrations journal June 1976
Dual‐function catalysis in propane dehydrogenation over Pt 1 –Ga 2 O 3 catalyst: Insights from a microkinetic analysis journal May 2020
Anchored metal nanoparticles: Effects of support and size on their energy, sintering resistance and reactivity journal January 2013
A dimer method for finding saddle points on high dimensional potential surfaces using only first derivatives journal October 1999
Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set journal July 1996
Subnanometre platinum clusters as highly active and selective catalysts for the oxidative dehydrogenation of propane journal February 2009
Catalytic Dehydrogenation of Light Alkanes on Metals and Metal Oxides journal August 2014
First-Principles Calculations of Propane Dehydrogenation over PtSn Catalysts journal April 2012
Propane dehydrogenation over supported Pt-Sn nanoparticles journal November 2018
A climbing image nudged elastic band method for finding saddle points and minimum energy paths journal December 2000
Trends in Adhesion Energies of Metal Nanoparticles on Oxide Surfaces: Understanding Support Effects in Catalysis and Nanotechnology journal January 2017
Surface Hexagonal Pt1Sn1 Intermetallic on Pt Nanoparticles for Selective Propane Dehydrogenation journal May 2020
Finite-Temperature Structures of Supported Subnanometer Catalysts Inferred via Statistical Learning and Genetic Algorithm-Based Optimization journal October 2020
Identification of Pt-based catalysts for propane dehydrogenation via a probability analysis journal January 2018
From ultrasoft pseudopotentials to the projector augmented-wave method journal January 1999
Controlling the acid-base properties of alumina for stable PtSn-based propane dehydrogenation catalysts journal February 2019
Modulation of catalyst particle structure upon support hydroxylation: Ab initio insights into Pd13 and Pt13/γ-Al2O3 journal August 2010
Tuning Adsorption and Catalytic Properties of α-Cr 2 O 3 and ZnO in Propane Dehydrogenation by Creating Oxygen Vacancy and Doping Single Pt Atom: A Comparative First-Principles Study journal May 2019
Ceria Maintains Smaller Metal Catalyst Particles by Strong Metal-Support Bonding journal August 2010
Size effect of TS-1 supports on the catalytic performance of PtSn/TS-1 catalysts for propane dehydrogenation journal August 2017
Van der Waals density functionals applied to solids journal May 2011
Kinetics of propane dehydrogenation over Pt–Sn/Al2O3 catalyst journal May 2011
Propane Dehydrogenation on Single-Site [PtZn4] Intermetallic Catalysts journal February 2021
Coking-Resistant Sub-Nano Dehydrogenation Catalysts: Pt n Sn x /SiO 2 ( n = 4, 7) journal March 2020
Role of acid solvent to prepare highly active PtSn/θ-Al 2 O 3 catalysts in dehydrogenation of propane to propylene journal September 2017
A Python Multiscale Thermochemistry Toolbox (pMuTT) for thermochemical and kinetic parameter estimation journal February 2020
Use of DFT to achieve a rational understanding of acid?basic properties of ?-alumina surfaces journal August 2004
Higher-accuracy van der Waals density functional journal August 2010
Chemical Potential of Metal Atoms in Supported Nanoparticles: Dependence upon Particle Size and Support journal November 2017
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set journal October 1996
DFT study of propane dehydrogenation on Pt catalyst: effects of step sites journal January 2011
Apparent Activation Energies in Complex Reaction Mechanisms: A Simple Relationship via Degrees of Rate Control journal August 2019
Multiscale modeling of hydrogenolysis of ethane and propane on Ru(0001): Implications for plastics recycling journal November 2022
Selective dehydrogenation of isobutane over supported Pt/Sn catalysts journal January 2000
Review of Pt-Based Bimetallic Catalysis: From Model Surfaces to Supported Catalysts journal August 2012
Confining isolated atoms and clusters in crystalline porous materials for catalysis journal October 2020
First principles study on the adsorption of Ptn (n=1–4) on γ-Al2O3(110) surface journal September 2014
Effect of reduction method on the activity of Pt–Sn/SiO2 for dehydrogenation of propane journal September 2014
Few-Atom Pt Ensembles Enable Efficient Catalytic Cyclohexane Dehydrogenation for Hydrogen Production journal February 2022
The Positive Role of Hydrogen on the Dehydrogenation of Propane on Pt(111) journal October 2017
Beyond the Reverse Horiuti–Polanyi Mechanism in Propane Dehydrogenation over Pt Catalysts journal December 2020
Enthalpy of formation of the (Pt–Sn) system journal October 1998
Platinum Nanoclusters Stabilized on γ-Alumina by Chlorine Used As a Capping Surface Ligand: A Density Functional Theory Study journal May 2012
Size Dependence of Pt Catalysts for Propane Dehydrogenation: from Atomically Dispersed to Nanoparticles journal October 2020
Stable and selective catalysts for propane dehydrogenation operating at thermodynamic limit journal July 2021
Density Functional Theory Study on Propane and Propene Adsorption on Pt(111) and PtSn Alloy Surfaces journal April 2011
Structural modulation and direct measurement of subnanometric bimetallic PtSn clusters confined in zeolites journal June 2020
Sn-modification of Pt 7 /alumina model catalysts: Suppression of carbon deposition and enhanced thermal stability journal January 2020
Alloying with Sn Suppresses Sintering of Size-Selected Subnano Pt Clusters on SiO 2 with and without Adsorbates journal September 2020

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