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Ammonia Hydrogen Ignition Measurements for Clean Aircraft Propulsion

Conference · · AIAA SCITECH 2022 Forum
DOI:https://doi.org/10.2514/6.2022-0817· OSTI ID:2406157
 [1];  [2];  [2];  [2]
  1. University of Central Florida College of Engineering and Computer Science; University of Central Florida
  2. University of Central Florida College of Engineering and Computer Science

In the current study, the oxidation of ammonia with hydrogen as well as ammonia with Natural Gas was carried out in order to study the ignition delay times behind reflected shock waves to refine chemical kinetic models. Experiments were carried out in the University of Central Florida’s shock tube facility by utilizing chemiluminescence to obtain OH* emission. Experimental results were then compared with the mainstay GRI 3.0 mechanism, as well as the proprietary UCF 2022 mechanism. Results indicate that for hydrogen/ammonia mixtures, GRI 3.0 overpredicts experimental values while UCF 2022 aligns well at low temperatures but shows variance at high temperature conditions. For hydrogen/Natural Gas mixtures, neither mechanism is able to accurately predict the experimental ignition delay times. The UCF 2022 mechanism is currently being adjusted based on a sensitivity study that was carried out and the experimental results so that it will be able to capture the ignition behavior of hydrogen-carrying compounds during combustion. Experiments are currently being planned in order to extend the pressure and temperature range.

Research Organization:
University of Central Florida
Sponsoring Organization:
USDOE; USDOE Office of Fossil Energy (FE), Office of Clean Energy Systems (FE-22)
DOE Contract Number:
FE0032072
OSTI ID:
2406157
Journal Information:
AIAA SCITECH 2022 Forum, Journal Name: AIAA SCITECH 2022 Forum
Country of Publication:
United States
Language:
English

References (13)

Interpreting shock tube ignition data journal January 2004
Measurements of Propanal Ignition Delay Times and Species Time Histories Using Shock Tube and Laser Absorption: MEASUREMENTS OF PROPANAL IGNITION DELAY TIMES AND SPECIES TIME HISTORIES journal July 2016
Experimental and modeling study on the high-temperature oxidation of Ammonia and related NOx chemistry journal March 2015
Shock tube ignition delay times and methane time-histories measurements during excess CO2 diluted oxy-methane combustion journal February 2016
Measurements and interpretation of shock tube ignition delay times in highly CO2 diluted mixtures using multiple diagnostics journal June 2017
Auto-ignition kinetics of ammonia and ammonia/hydrogen mixtures at intermediate temperatures and high pressures journal August 2019
Effect of hydrogen blending on the high temperature auto-ignition of ammonia at elevated pressure journal March 2021
Natural gas–ammonia dual-fuel combustion in spark-ignited engine with various air–fuel ratios and split ratios of ammonia under part load condition journal April 2021
A comprehensive study on using new hydrogen-natural gas and ammonia-natural gas blends for better performance journal September 2020
High temperature infrared absorption cross sections of methane near 3.4 µm in Ar and CO2 mixtures journal February 2018
Ammonia–methane interaction in jet-stirred and flow reactors: An experimental and kinetic modeling study journal January 2021
Measuring the effectiveness of high-performance Co-Optima biofuels on suppressing soot formation at high temperature journal February 2020
Probing the Effects of NOx and SOx Impurities on Oxy-Fuel Combustion in Supercritical CO2: Shock Tube Experiments and Chemical Kinetic Modeling journal June 2020

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