A multifunctional technology platform for sorbent construction using polyacrylonitrile scaffolds

Riley, Brian J.

doi:10.1021/acs.iecr.4c00100

A multifunctional technology platform for sorbent construction using polyacrylonitrile scaffolds

Journal Article · 03 May 2024 · Industrial and Engineering Chemistry Research

DOI:https://doi.org/10.1021/acs.iecr.4c00100· OSTI ID:2396654

^[1]

BATTELLE (PACIFIC NW LAB)

Polyacrylonitrile (PAN) is a synthetic polymer that shows high potential for use in a wide range of environmental remediation applications. PAN can be implemented in various ways within a batch or continuous process stream for use as a passive scaffold holding active gettering materials in place or where the PAN scaffold (e.g., beads, fiber mats, membranes) is functionalized with active chelating groups (e.g., amine, hydrazide, amidoximes, carboxyl). Application spaces covered in this review include remediation of heavy metals (e.g., Ag, As, Cd, Cr6+, Cu, Pb, Sb, and Se), high-dose fission products (e.g., 90Sr, 137Cs), radioiodine (i.e., 129I), noble gases (i.e., Xe, 85Kr), rare earths (e.g., Ce, Y), and actinides (e.g., Am, Pu, U). Methods for producing PAN composite sorbents are discussed. Options are also discussed for removing the PAN matrix following chemisorption of an active contaminant to minimize waste volumes requiring disposal.

Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC05-76RL01830

OSTI ID:: 2396654

Report Number(s):: PNNL-SA-193801

Journal Information:: Industrial and Engineering Chemistry Research, Journal Name: Industrial and Engineering Chemistry Research Journal Issue: 19 Vol. 63

Country of Publication:: United States

Language:: English

References (79)

The free radical species in polyacrylonitrile fibers induced by γ-radiation and their decay behaviors Liu, Weihua; Wang, Mouhua; Xing, Zhe Radiation Physics and Chemistry, Vol. 81, Issue 7 https://doi.org/10.1016/j.radphyschem.2012.03.017	journal	July 2012
Improvement of Ultrafiltration for Treatment of Phosphorus-Containing Water by a Lanthanum-Modified Aminated Polyacrylonitrile Membrane Koh, Kok Yuen; Zhang, Sui; Chen, J. Paul ACS Omega, Vol. 5, Issue 13 https://doi.org/10.1021/acsomega.9b03573	journal	March 2020
Micellar enhanced ultrafiltration (MEUF) of mercury-contaminated wastewater: Experimental and artificial neural network modeling Yaqub, Muhammad; Lee, Seung Hwan Journal of Water Process Engineering, Vol. 33 https://doi.org/10.1016/j.jwpe.2019.101046	journal	February 2020
Hydrogel/mineral-integrated interface for synergistic antifouling membrane Wen, Yajie; Yang, Xiaobin; Li, Yangxue Separation and Purification Technology, Vol. 340 https://doi.org/10.1016/j.seppur.2024.126775	journal	July 2024
Silver-Loaded Aluminosilicate Aerogels As Iodine Sorbents Riley, Brian J.; Kroll, Jared O.; Peterson, Jacob A. ACS Applied Materials & Interfaces, Vol. 9, Issue 38 https://doi.org/10.1021/acsami.7b10290	journal	September 2017
Study on the adsorption performance and competitive mechanism for heavy metal contaminants removal using novel multi-pore activated carbons derived from recyclable long-root Eichhornia crassipes Cao, Fangjun; Lian, Cheng; Yu, Jianguo Bioresource Technology, Vol. 276 https://doi.org/10.1016/j.biortech.2019.01.007	journal	March 2019
Demonstrate the removal efficiency and capacity of MOF materials for krypton recovery Thallapally, Praveen K.; Liu, Jian; Strachan, Denis M. https://doi.org/10.2172/1111231	report	August 2013
A Novel Process for the Preparation of Binder‐Free Zeolite Beads (Lta‐5a) via Photopolymerization Applied in Co₂ Adsorption Field Zhang, Yijun; Josien, Ludovic; Vaulot, Cyril Advanced Materials Technologies, Vol. 8, Issue 19 https://doi.org/10.1002/admt.202300699	journal	June 2023
Removing Selenium(IV) and Arsenic(V) Oxyanions with Tailored Chelating Polymers Ramana, Anuradha; Sengupta, Arup K. Journal of Environmental Engineering, Vol. 118, Issue 5 https://doi.org/10.1061/(ASCE)0733-9372(1992)118:5(755)	journal	September 1992
Distributions of 14 elements on 63 absorbers from three simulant solutions (acid-dissolved sludge, acidified supernate, and alkaline supernate) for Hanford HLW Tank 102-SY Marsh, S. F.; Svitra, Z. V.; Bowen, S. M. https://doi.org/10.2172/10177119	report	August 1994
Sustainable Preparation of MIL-100(Fe) and Its Photocatalytic Behavior in the Degradation of Methyl Orange in Water Guesh, Kiros; Caiuby, Clarice A. D.; Mayoral, Álvaro Crystal Growth & Design, Vol. 17, Issue 4 https://doi.org/10.1021/acs.cgd.6b01776	journal	March 2017
Adsorption of cesium on copper hexacyanoferrate–PAN composite ion exchanger from aqueous solution Nilchi, A.; Saberi, R.; Moradi, M. Chemical Engineering Journal, Vol. 172, Issue 1 https://doi.org/10.1016/j.cej.2011.06.011	journal	August 2011
Synthesis of Fe₃O₄/Polyacrylonitrile Composite Electrospun Nanofiber Mat for Effective Adsorption of Tetracycline Liu, Qing; Zhong, Lu-Bin; Zhao, Quan-Bao ACS Applied Materials & Interfaces, Vol. 7, Issue 27 https://doi.org/10.1021/acsami.5b04598	journal	June 2015
The effects of γ-radiation on polyacrylonitrile Hill, D. J. T.; Lang, A. P.; O'Donnell, J. H. Polymer Degradation and Stability, Vol. 38, Issue 3 https://doi.org/10.1016/0141-3910(92)90114-K	journal	January 1992
Metal–Organic Framework–Polyacrylonitrile Composite Beads for Xenon Capture Riley, Brian J.; Chong, Saehwa; Kuang, Wenbin ACS Applied Materials & Interfaces, Vol. 12, Issue 40 https://doi.org/10.1021/acsami.0c13717	journal	September 2020
Synthesis of and iodine capture with MS_x (Ag₂S, Bi₂S₃, Cu₂S)–polyacrylonitrile composites Riley, Brian J.; Chong, Saehwa; Canfield, Nathan L. New Journal of Chemistry, Vol. 48, Issue 8 https://doi.org/10.1039/D3NJ05961H	journal	January 2024
Metal–Organic Framework–Polymer Composite as a Highly Efficient Sorbent for Sulfonamide Adsorption and Desorption: Effect of Coordinatively Unsaturated Metal Site and Topology Shih, Yung-Han; Wang, Kuen-Yun; Singco, Brenda Langmuir, Vol. 32, Issue 44 https://doi.org/10.1021/acs.langmuir.6b03067	journal	October 2016
Radiation damage in polyacrylonitrile Murthy, M. Ramakrishna; Radhakrishna, S. Pramana, Vol. 20, Issue 1 https://doi.org/10.1007/BF02846184	journal	January 1983
Zeolites in Adsorption Processes: State of the Art and Future Prospects Pérez-Botella, Eduardo; Valencia, Susana; Rey, Fernando Chemical Reviews, Vol. 122, Issue 24 https://doi.org/10.1021/acs.chemrev.2c00140	journal	October 2022
Chelating polyacrylonitrile beads for removal of lead and cadmium from wastewater Bhunia, Prasenjit; Chatterjee, Somak; Rudra, Pritam Separation and Purification Technology, Vol. 193 https://doi.org/10.1016/j.seppur.2017.11.001	journal	March 2018
Crystallographic study of the ammonium/potassium 12-molybdophosphate ion-exchange system Boeyens, J. C. A.; McDougal, Gloria J.; Van R. Smit, J. Journal of Solid State Chemistry, Vol. 18, Issue 2 https://doi.org/10.1016/0022-4596(76)90095-5	journal	June 1976
Modification of polyacrylonitrile membranes via plasma treatment followed by polydimethylsiloxane coating for recovery of ethyl acetate from aqueous solution through vacuum membrane distillation Wu, Huanhuan; Shen, Fei; Su, Yi Separation and Purification Technology, Vol. 197 https://doi.org/10.1016/j.seppur.2018.01.011	journal	May 2018
State-of-the-Art Materials and Spinning Technology for Hemodialyzer Membranes Roy, Anirban; De, Sirshendu Separation & Purification Reviews, Vol. 46, Issue 3 https://doi.org/10.1080/15422119.2016.1256323	journal	November 2016
The Methods and Stands for Testing Fixed Sorbent and Sorbent Polymer Composite Materials for the Removal of Mercury from Flue Gases Gorecki, Jerzy; Macherzynski, Mariusz; Chmielowiec, Jacek Energies, Vol. 15, Issue 23 https://doi.org/10.3390/en15238891	journal	November 2022
Brushite-infused polyacrylonitrile nanofiber adsorbent for strontium removal from water Vivas, Eleazer L.; Lee, Sumin; Cho, Kuk Journal of Environmental Management, Vol. 270 https://doi.org/10.1016/j.jenvman.2020.110837	journal	September 2020
The flammability of polyacrylonitrile and its copolymers Hall, Michael E.; Horrocks, A. Richard; Zhang, Jun Polymer Degradation and Stability, Vol. 44, Issue 3 https://doi.org/10.1016/0141-3910(94)90097-3	journal	January 1994
Biofouling alleviation and flux enhancement of electrospun PAN microfiltration membranes by embedding of para‐aminobenzoate alumoxane nanoparticles Moradi, G.; Rajabi, L.; Dabirian, F. Journal of Applied Polymer Science, Vol. 135, Issue 7 https://doi.org/10.1002/app.45738	journal	October 2017
Adsorption of lead and copper on modified polyacrylonitrile bead Godjevargova, T.; Simeonova, A.; Dimov, A. Journal of Applied Polymer Science, Vol. 79, Issue 2 https://doi.org/10.1002/1097-4628(20010110)79:2<283::AID-APP90>3.0.CO;2-2	journal	January 2000
New applications of KNiFC-PAN resin for broad scale monitoring of radiocesium following the Fukushima Dai-ichi nuclear disaster Breier, C. F.; Pike, S. M.; Sebesta, F. Journal of Radioanalytical and Nuclear Chemistry, Vol. 307, Issue 3 https://doi.org/10.1007/s10967-015-4421-x	journal	November 2015
Ammonium Salts of the Heteropolyacids as Cation Exchangers Smit, J. Van R. Nature, Vol. 181, Issue 4622 https://doi.org/10.1038/1811530a0	journal	May 1958
AMP-PAN column tests for the removal of 137Cs from actual and simulated INEEL high-activity wastes Brewer, K. N.; Todd, T. A.; Wood, D. J. Czechoslovak Journal of Physics, Vol. 49, Issue S1 https://doi.org/10.1007/s10582-999-1024-1	journal	January 1999
Experimental and numerical investigation of mercury removal from flue gas by sorbent polymer composite Ryfa, Arkadiusz; Żmuda, Robert; Mandrela, Sergiusz Fuel, Vol. 333 https://doi.org/10.1016/j.fuel.2022.126470	journal	February 2023
Composite sorbents of inorganic ion-exchangers and polyacrylonitrile binding matrix: I. Methods of modification of properties of inorganic ion-exchangers for application in column packed beds Šebesta, F. Journal of Radioanalytical and Nuclear Chemistry, Vol. 220, Issue 1 https://doi.org/10.1007/BF02035352	journal	June 1997
Oxidation of arsenate(III) with manganese oxides in water treatment Driehaus, Wolfgang; Seith, Reiner; Jekel, Martin Water Research, Vol. 29, Issue 1 https://doi.org/10.1016/0043-1354(94)E0089-O	journal	January 1995
Comparison of some commercial and laboratory prepared caesium ion-exchangers Kameník, J.; Ŝebesta, F. Czechoslovak Journal of Physics, Vol. 53, Issue S1 https://doi.org/10.1007/s10582-003-0074-z	journal	January 2003
Some cation exchange properties of ammonium 12-molybdophosphate Buchwald, H.; Thistlethwaite, W. P. Journal of Inorganic and Nuclear Chemistry, Vol. 5, Issue 4 https://doi.org/10.1016/0022-1902(58)80013-5	journal	January 1958
Radioactive Iodine and Krypton Control for Nuclear Fuel Reprocessing Facilities Soelberg, Nick R.; Garn, Troy G.; Greenhalgh, Mitchell R. Science and Technology of Nuclear Installations, Vol. 2013 https://doi.org/10.1155/2013/702496	journal	January 2013
Degradation of polyacrylonitrile by X-ray radiation Cardoso dos Santos, Luis Geraldo; Kawano, Yoshio Polymer Degradation and Stability, Vol. 44, Issue 1 https://doi.org/10.1016/0141-3910(94)90028-0	journal	January 1994
Application of polyantimonic acid–polyacrylonitrile for removal of strontium(II) from simulated high-level liquid waste Ma, Fuyin; Li, Zheng; Zhou, Wei Journal of Radioanalytical and Nuclear Chemistry, Vol. 311, Issue 3 https://doi.org/10.1007/s10967-016-5150-5	journal	December 2016
Gaseous Iodine Sorbents: A Comparison between Ag-Loaded Aerogel and Xerogel Scaffolds Chong, Saehwa; Riley, Brian J.; Peterson, Jacob A. ACS Applied Materials & Interfaces, Vol. 12, Issue 23 https://doi.org/10.1021/acsami.0c02396	journal	May 2020
Stable and high-flux polyacrylonitrile/hafnium phosphonate nanofibrous membranes for efficient removal of actinides from strong acidic solutions Xiong, Liangping; Lyu, Kai; Zeng, Yiyang Journal of Environmental Chemical Engineering, Vol. 11, Issue 2 https://doi.org/10.1016/j.jece.2023.109619	journal	April 2023
Scaleup of wet granulation processes: science not art Litster, J. D. Powder Technology, Vol. 130, Issue 1-3 https://doi.org/10.1016/S0032-5910(02)00222-X	journal	February 2003
Efficient Removal of Cs⁺ and Sr²⁺ Ions by Granulous (Me₂NH₂)_4/3(Me₃NH)_2/3Sn₃S₇·1.25H₂O/Polyacrylonitrile Composite Li, Jilong; Jin, Jiance; Zou, Yanmin ACS Applied Materials & Interfaces, Vol. 13, Issue 11 https://doi.org/10.1021/acsami.1c01983	journal	March 2021
Silver-Loaded Xerogel Nanostructures for Iodine Capture: A Comparison of Thiolated versus Unthiolated Sorbents Riley, Brian J.; Chong, Saehwa; Marcial, José ACS Applied Nano Materials, Vol. 5, Issue 7 https://doi.org/10.1021/acsanm.2c01741	journal	June 2022
Millimeter-sized Bi₂S₃@polyacrylonitrile hybrid beads for highly efficient iodine capture Yu, Qiang; Jiang, Xiaohui; Cheng, Zhengjun New Journal of Chemistry, Vol. 44, Issue 39 https://doi.org/10.1039/D0NJ03229H	journal	January 2020
Cesium Absorption from Acidic Solutions Using Ammonium Molybdophosphate on a Polyacrylonitrile Support (AMP-PAN) Miller, Carla J.; Olson, Arlin L.; Johnson, Calvin K. Separation Science and Technology, Vol. 32, Issue 1-4 https://doi.org/10.1080/01496399708003185	journal	January 1997
Preparation of phosphorylated polyacrylonitrile-based nanofiber mat and its application for heavy metal ion removal Zhao, Rui; Li, Xiang; Sun, Bolun Chemical Engineering Journal, Vol. 268 https://doi.org/10.1016/j.cej.2015.01.061	journal	May 2015
Phosphate Ion Adsorption Properties of Polyacrylonitrile (PAN) Activated Carbon Fiber Sakamoto, Tomoyoshi; Amano, Yoshimasa; Machida, Motoi Journal of Fiber Science and Technology, Vol. 73, Issue 9 https://doi.org/10.2115/fiberst.2017-0032	journal	January 2017
A novel carboxylated polyacrylonitrile nanofibrous membrane with high adsorption capacity for fluoride removal from water Chen, Xin; Wan, Caixia; Yu, Rui Journal of Hazardous Materials, Vol. 411 https://doi.org/10.1016/j.jhazmat.2021.125113	journal	June 2021
Adsorption of inorganic arsenic and organoarsenicals on hydrous oxides Ghosh, Mriganka M.; Yuan, Jill R. Environmental Progress, Vol. 6, Issue 3 https://doi.org/10.1002/ep.670060325	journal	August 1987
Removal of chromium ions (VI) from underground water in the hybrid complexation-ultrafiltration process Bohdziewicz, Jolanta Desalination, Vol. 129, Issue 3 https://doi.org/10.1016/S0011-9164(00)00063-1	journal	August 2000
Evaluation of ammonium molybdophosphate-polyacrylonitrile (AMP-PAN) as a cesium selective sorbent for the removal of 137Cs from acidic nuclear waste solutions Tranter, T. J.; Herbst, R. S.; Todd, T. A. Advances in Environmental Research, Vol. 6, Issue 2 https://doi.org/10.1016/S1093-0191(00)00073-3	journal	March 2002
Chitosan-poly (vinyl alcohol)/poly (acrylonitrile) (CS–PVA/PAN) composite pervaporation membranes for the separation of ethanol–water solutions Li, Bing-Bing; Xu, Zhen-Liang; Alsalhy Qusay, F. Desalination, Vol. 193, Issue 1-3 https://doi.org/10.1016/j.desal.2005.08.021	journal	May 2006
UV stabilization route for melt-processible PAN-based carbon fibers Paiva, M. C.; Kotasthane, P.; Edie, D. D. Carbon, Vol. 41, Issue 7 https://doi.org/10.1016/S0008-6223(03)00041-1	journal	January 2003
Granular ferric hydroxide—a new adsorbent for the removal of arsenic from natural water Driehaus, W.; Jekel, M.; Hildebrandt, U. Journal of Water Supply: Research and Technology—AQUA, Vol. 47, Issue 1 https://doi.org/10.2166/aqua.1998.0005	journal	February 1998
Binderless Faujasite Beads with Hierarchical Porosity for Selective CO2 Adsorption for Biogas Upgrading Boer, Dina G.; Asgar Pour, Zahra; Langerak, Jort Molecules, Vol. 28, Issue 5 https://doi.org/10.3390/molecules28052198	journal	February 2023
Environmental Remediation with Functional Aerogels and Xerogels Riley, Brian J.; Chong, Saehwa Global Challenges, Vol. 4, Issue 10 https://doi.org/10.1002/gch2.202000013	journal	June 2020
Preconcentration of Cu(II), Fe(III) and Pb(II) with 2-((2-aminoethylamino)methyl)phenol-functionalized activated carbon followed by ICP-OES determination He, Qun; Hu, Zheng; Jiang, Yin Journal of Hazardous Materials, Vol. 175, Issue 1-3 https://doi.org/10.1016/j.jhazmat.2009.10.067	journal	March 2010
Iodine Capture with Metal-Functionalized Polyacrylonitrile Composite Beads Containing Ag⁰, Bi⁰, Cu⁰, or Sn⁰ Particles Chong, Saehwa; Riley, Brian J.; Asmussen, R. Matthew ACS Applied Polymer Materials, Vol. 4, Issue 12 https://doi.org/10.1021/acsapm.2c01407	journal	November 2022
Composite ion exchanger with ammonium molybdophosphate and its properties Šebesta, F.; Štefula, V. Journal of Radioanalytical and Nuclear Chemistry Articles, Vol. 140, Issue 1 https://doi.org/10.1007/BF02037360	journal	May 1990
A review of heat treatment on polyacrylonitrile fiber Rahaman, M. S. A.; Ismail, A. F.; Mustafa, A. Polymer Degradation and Stability, Vol. 92, Issue 8 https://doi.org/10.1016/j.polymdegradstab.2007.03.023	journal	August 2007
Composite absorbers of inorganic ion-exchangers and polyacrylonitrile binding matrix: V. Influence of ionising radiation on the leachability of137Cs from cemented composite NiFC-PAN absorber Motl, A.; John, J.; Sebesta, F. Journal of Radioanalytical and Nuclear Chemistry, Vol. 222, Issue 1-2 https://doi.org/10.1007/BF02034270	journal	August 1997
Granulation techniques and technologies: recent progresses Shanmugam, Srinivasan BioImpacts, Vol. 5, Issue 1 https://doi.org/10.15171/bi.2015.04	journal	August 2017
Iodine Vapor Reactions with Pure Metal Wires at Temperatures of 100–139 °C in Air Riley, Brian J.; Chong, Saehwa; Beck, Chelsie L. Industrial & Engineering Chemistry Research, Vol. 60, Issue 47 https://doi.org/10.1021/acs.iecr.1c03902	journal	November 2021
In vitro cytocompatibility and blood compatibility of polysulfone blend, surface-modified polysulfone and polyacrylonitrile membranes for hemodialysis Roy, Anirban; Dadhich, Prabhash; Dhara, Santanu RSC Advances, Vol. 5, Issue 10 https://doi.org/10.1039/C4RA13460E	journal	January 2015
Noble gas management with radiation-tolerant MOF for molten salt reactors Robinson, Alexander J.; Johnson, Hannah M.; Chong, Saehwa Cell Reports Physical Science, Vol. 5, Issue 2 https://doi.org/10.1016/j.xcrp.2024.101829	journal	February 2024
Supporting of some ferrocyanides on polyacrylonitrile (PAN) binding polymer and their application for cesium treatment Someda, H. H.; ElZahhar, A. A.; Shehata, M. K. Separation and Purification Technology, Vol. 29, Issue 1 https://doi.org/10.1016/S1383-5866(02)00018-7	journal	October 2002
Polyacrylonitrile in the Preparation of Separation Membranes: A Review Vatanpour, Vahid; Pasaoglu, Mehmet Emin; Kose-Mutlu, Borte Industrial & Engineering Chemistry Research, Vol. 62, Issue 17 https://doi.org/10.1021/acs.iecr.3c00057	journal	April 2023
The Study of Competitive Adsorption of Heavy Metal Ions from Aqueous Solution by Aminated Polyacrylonitrile Nanofiber Mats Kampalanonwat, Pimolpun; Supaphol, Pitt Energy Procedia, Vol. 56 https://doi.org/10.1016/j.egypro.2014.07.142	journal	January 2014
Polyacrylonitrile Composites of Ag–Al–Si–O Aerogels and Xerogels as Iodine and Iodide Sorbents Riley, Brian J.; Chong, Saehwa; Asmussen, R. Matthew ACS Applied Polymer Materials, Vol. 3, Issue 7 https://doi.org/10.1021/acsapm.1c00237	journal	June 2021
Polyacrylonitrile-Chalcogel Hybrid Sorbents for Radioiodine Capture Riley, Brian J.; Pierce, David A.; Chun, Jaehun Environmental Science & Technology, Vol. 48, Issue 10 https://doi.org/10.1021/es405807w	journal	April 2014
Development of a hydrogen mordenite sorbent for the capture of krypton from used nuclear fuel reprocessing off-gas streams Greenhalgh, Mitchell; Garn, Troy G.; Law, Jack D. Journal of Nuclear Science and Technology, Vol. 51, Issue 4 https://doi.org/10.1080/00223131.2014.877404	journal	January 2014
Heparinized thin-film composite membranes with sub-micron ridge structure for efficient hemodialysis Yu, Xufeng; Zhu, Yadong; Zhang, Tonghui Journal of Membrane Science, Vol. 599 https://doi.org/10.1016/j.memsci.2019.117706	journal	April 2020
Fabrication of electrospun polyacrylonitrile ion-exchange membranes for application in lysozyme adsorption Chiu, H. T.; Lin, J. M.; Cheng, T. H. Express Polymer Letters, Vol. 5, Issue 4 https://doi.org/10.3144/expresspolymlett.2011.31	journal	January 2011
Hybrid Sorbents for ¹²⁹ I Capture from Contaminated Groundwater Cordova, Elsa A.; Garayburu-Caruso, Vanessa; Pearce, Carolyn I. ACS Applied Materials & Interfaces, Vol. 12, Issue 23 https://doi.org/10.1021/acsami.0c01527	journal	May 2020
Degradation of polyacrylonitrile by low energy ion beam and UV radiation Aggour, Y. A.; Aziz, M. S. Polymer Testing, Vol. 19, Issue 3 https://doi.org/10.1016/S0142-9418(98)00087-7	journal	May 2000
Removal of phosphate with a polyacrylonitrile composite functionalized by a metal organic framework-enhanced layered double hydroxide Song, Jianzhi; Cha, Ligen; Sillanpää, Mika Water Science and Technology, Vol. 87, Issue 7 https://doi.org/10.2166/wst.2023.083	journal	March 2023
Inorganic Arsenic Removal by Zero-Valent Iron Lackovic, Jeffrey A.; Nikolaidis, Nikolaos P.; Dobbs, Gregory M. Environmental Engineering Science, Vol. 17, Issue 1 https://doi.org/10.1089/ees.2000.17.29	journal	January 2000
Development and evaluation of a silver mordenite composite sorbent for the partitioning of xenon from krypton in gas compositions Garn, Troy G.; Greenhalgh, Mitchell; Law, Jack D. Journal of Nuclear Science and Technology, Vol. 53, Issue 10 https://doi.org/10.1080/00223131.2015.1126205	journal	December 2015

Similar Records

Related Subjects

polyacrylonitrile
composite sorbents
sulfides
actinides
rare earths
137Cs
90Sr
radioiodine

A multifunctional technology platform for sorbent construction using polyacrylonitrile scaffolds

Citation Formats

References (79)

Similar Records

Related Subjects