Recommendations for Improving Rigor and Reproducibility in Site Specific Characterization

Wrasman, Cody J.; Bell, Alexis T.; Chandler, Bert D.; Harris, James W.; Kwon, Stephanie; Ball, Madelyn R.; Krishna, Siddarth H.; Khatib, Sheima J.; Bollini, Praveen; Roman-Leshkov, Yuriy; Getsoian, Andrew; Weber, Robert S.; Lercher, Johannes A.; Liu, Dongxia; Resasco, Daniel E.; Bates, Jason S.; Hall, Jacklyn N.; Lebron-Rodriguez, Edgard A.; Paz Herrera, Laura; Notestein, Justin M.; Schaidle, Josh

doi:10.1016/j.jcat.2024.115451

Recommendations for Improving Rigor and Reproducibility in Site Specific Characterization

Journal Article · 19 March 2024 · Journal of Catalysis

DOI:https://doi.org/10.1016/j.jcat.2024.115451· OSTI ID:2341271

Wrasman, Cody J.; Bell, Alexis T.; Chandler, Bert D.; Harris, James W.; Kwon, Stephanie; Ball, Madelyn R.; Krishna, Siddarth H.; Khatib, Sheima J.; Bollini, Praveen; Roman-Leshkov, Yuriy; Getsoian, Andrew "Bean"; Weber, Robert S.; Lercher, Johannes A.; Liu, Dongxia; Resasco, Daniel E.; Bates, Jason S.; Hall, Jacklyn N.; Lebron-Rodriguez, Edgard A.; Paz Herrera, Laura; Notestein, Justin M. more »

Heterogeneous catalysis is driven by the interaction of reactant molecules and the catalyst surface. The locus of this interaction as well as the surrounding ensemble of atoms is referred to as the catalyst active site. Active site characterization attempts to distinguish active catalytic sites from inactive surface sites, to elucidate the structural and chemical nature of active sites, and to quantify active site concentration. Numerous techniques have been demonstrated to provide compositional and structural information about the active sites within a catalyst. However, each technique has its own limitations and experimental pitfalls that can lead to data misinterpretation or irreproducible results. This work aims to provide an overview of the types of data that can be collected, to outline common experimental challenges and how to avoid them, and to assemble relevant references for the most used active site characterization techniques. More broadly, we aim to outline best practices for researchers to collect, interpret, and report active site characterization data in a way that provides the most benefit to the broader catalysis community. Increasing the rigor and reproducibility of active site characterization offers a strategy to better link properties with catalytic performance and to enable the community to develop consensus concerning these relationships.

Research Organization:: National Renewable Energy Laboratory (NREL), Golden, CO (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Transportation Office. Bioenergy Technologies Office

DOE Contract Number:: AC36-08GO28308

OSTI ID:: 2341271

Report Number(s):: NREL/JA-5100-88017; MainId:88792; UUID:4bf7d0ab-0134-4f0d-a1d4-1ec43346d027; MainAdminId:72466

Journal Information:: Journal of Catalysis, Journal Name: Journal of Catalysis Vol. 433

Country of Publication:: United States

Language:: English

References (85)

Influence of adsorption and mass transfer effects on temperature-programmed desorption from porous catalysts Rieck, J. Journal of Catalysis, Vol. 85, Issue 1 https://doi.org/10.1016/0021-9517(84)90118-0	journal	January 1984
Developing a Raman Spectrokinetic Approach To Gain Insights into the Structure–Reactivity Relationship of Supported Metal Oxide Catalysts Moncada, Jorge; Adams, William R.; Thakur, Raj ACS Catalysis, Vol. 8, Issue 10 https://doi.org/10.1021/acscatal.8b02041	journal	August 2018
Isotopic and Chemical Titration of Acid Sites in Tungsten Oxide Domains Supported on Zirconia Baertsch, Chelsey D.; Soled, Stuart L.; Iglesia, Enrique The Journal of Physical Chemistry B, Vol. 105, Issue 7 https://doi.org/10.1021/jp003073d	journal	February 2001
Size and Support Effects for the Water–Gas Shift Catalysis over Gold Nanoparticles Supported on Model Al ₂ O ₃ and TiO ₂ Shekhar, Mayank; Wang, Jun; Lee, Wen-Sheng Journal of the American Chemical Society, Vol. 134, Issue 10 https://doi.org/10.1021/ja210083d	journal	February 2012
On the contamination with nickel and nickel tetracarbonyl during FT-IR investigation of catalysts under CO-containing gases Meunier, Frederic C. Journal of Catalysis, Vol. 372 https://doi.org/10.1016/j.jcat.2019.03.006	journal	April 2019
In situ IR spectroscopic studies of Ni surface segregation induced by CO adsorption on Cu–Ni/SiO2 bimetallic catalysts Yao, Yunxi; Goodman, D. Wayne Physical Chemistry Chemical Physics, Vol. 16, Issue 8 https://doi.org/10.1039/c3cp54997f	journal	January 2014
The active site of acidic aluminosilicate catalysts Haag, W. O.; Lago, R. M.; Weisz, P. B. Nature, Vol. 309, Issue 5969 https://doi.org/10.1038/309589a0	journal	June 1984
Transition state and product diffusion control by polymer–nanocrystal hybrid catalysts Riscoe, Andrew R.; Wrasman, Cody J.; Herzing, Andrew A. Nature Catalysis, Vol. 2, Issue 10 https://doi.org/10.1038/s41929-019-0322-7	journal	August 2019
Acid Sites of Phosphorus-Modified Zeosils Kumar, Gaurav; Ren, Limin; Pang, Yutong ACS Catalysis, Vol. 11, Issue 15 https://doi.org/10.1021/acscatal.1c01588	journal	July 2021
In situ spectroscopic detection ofSMSI effect in a Ni/CeO ₂ system: hydrogen-induced burial and dig out of metallic nickel Caballero, Alfonso; Holgado, Juan P.; Gonzalez-delaCruz, Victor M. Chem. Commun., Vol. 46, Issue 7 https://doi.org/10.1039/B920803H	journal	January 2010
Unifying views on catalyst deactivation Martín, Antonio J.; Mitchell, Sharon; Mondelli, Cecilia Nature Catalysis, Vol. 5, Issue 10 https://doi.org/10.1038/s41929-022-00842-y	journal	September 2022
Normalization by oxygen uptake of the rates of oxidative dehydrogenation of methanol and ethanol Tanabe, S.; Davis, H. E.; Wei, D. 11th International Congress On Catalysis - 40th Anniversary, Proceedings of the 11th ICC https://doi.org/10.1016/S0167-2991(96)80244-8	book	January 1996
Genesis of Brønsted Acid Sites during Dehydration of 2-Butanol on Tungsten Oxide Catalysts Baertsch, Chelsey D.; Komala, Kenny T.; Chua, Yong-Hwee Journal of Catalysis, Vol. 205, Issue 1 https://doi.org/10.1006/jcat.2001.3426	journal	January 2002
In situ FT-IR spectroscopy investigations of dimethyl carbonate synthesis: on the contribution of gas-phase species Meunier, F. C. RSC Advances, Vol. 6, Issue 21 https://doi.org/10.1039/C4RA15157G	journal	January 2016
Elementary steps in acetone condensation reactions catalyzed by aluminosilicates with diverse void structures Herrmann, Stanley; Iglesia, Enrique Journal of Catalysis, Vol. 346 https://doi.org/10.1016/j.jcat.2016.12.011	journal	February 2017
Design parameters for temperature programmed desorption from porous catalysts*1 Gorte, R. Journal of Catalysis, Vol. 75, Issue 1 https://doi.org/10.1016/0021-9517(82)90131-2	journal	May 1982
Spectroscopic Observation of Dual Catalytic Sites During Oxidation of CO on a Au/TiO2 Catalyst Green, I. X.; Tang, W.; Neurock, M. Science, Vol. 333, Issue 6043 https://doi.org/10.1126/science.1207272	journal	August 2011
New advances in using Raman spectroscopy for the characterization of catalysts and catalytic reactions Hess, Christian Chemical Society Reviews, Vol. 50, Issue 5 https://doi.org/10.1039/D0CS01059F	journal	January 2021
Lies, damned lies, and turnover rates Weber, Robert S. Journal of Catalysis, Vol. 404 https://doi.org/10.1016/j.jcat.2021.06.024	journal	December 2021
XAFS Techniques for Catalysts, Nanomaterials, and Surfaces Iwasawa, Yasuhiro; Asakura, Kiyotaka; Tada, Mizuki https://doi.org/10.1007/978-3-319-43866-5	book	January 2017
Identification and quantification of distinct active sites in Hf-Beta zeolites for transfer hydrogenation catalysis Johnson, Blake A.; Di Iorio, John R.; Román-Leshkov, Yuriy Journal of Catalysis, Vol. 404 https://doi.org/10.1016/j.jcat.2021.10.026	journal	December 2021
Consequences of product inhibition in the quantification of kinetic parameters Harris, James W.; Verma, Anuj A.; Arvay, Jeremy W. Journal of Catalysis, Vol. 389 https://doi.org/10.1016/j.jcat.2020.06.014	journal	September 2020
Infrared studies of the surface acidity of oxides and zeolites using adsorbed probe molecules Lercher, Johannes A.; Gründling, Christian; Eder-Mirth, Gabriele Catalysis Today, Vol. 27, Issue 3-4 https://doi.org/10.1016/0920-5861(95)00248-0	journal	February 1996
Structure, Dynamics, and Reactivity for Light Alkane Oxidation of Fe(II) Sites Situated in the Nodes of a Metal–Organic Framework Simons, Matthew C.; Vitillo, Jenny G.; Babucci, Melike Journal of the American Chemical Society, Vol. 141, Issue 45 https://doi.org/10.1021/jacs.9b08686	journal	October 2019
Isolated Metal Active Site Concentration and Stability Control Catalytic CO ₂ Reduction Selectivity Matsubu, John C.; Yang, Vanessa N.; Christopher, Phillip Journal of the American Chemical Society, Vol. 137, Issue 8 https://doi.org/10.1021/ja5128133	journal	February 2015
Turnover Rates in Heterogeneous Catalysis Boudart, M. Chemical Reviews, Vol. 95, Issue 3 https://doi.org/10.1021/cr00035a009	journal	May 1995
Dealing with a local heating effect when measuring catalytic solids in a reactor with Raman spectroscopy Tinnemans, Stan J.; Kox, Marianne H. F.; Sletering, Marco W. Physical Chemistry Chemical Physics, Vol. 8, Issue 20 https://doi.org/10.1039/b602311h	journal	January 2006
Distinct Catalytic Reactivity of Sn Substituted in Framework Locations and at Defect Grain Boundaries in Sn-Zeolites Bates, Jason S.; Bukowski, Brandon C.; Harris, James W. ACS Catalysis, Vol. 9, Issue 7 https://doi.org/10.1021/acscatal.9b01123	journal	May 2019
Resonance Raman and surface- and tip-enhanced Raman spectroscopy methods to study solid catalysts and heterogeneous catalytic reactions Kim, Hacksung; Kosuda, Kathryn M.; Van Duyne, Richard P. Chemical Society Reviews, Vol. 39, Issue 12 https://doi.org/10.1039/c0cs00044b	journal	January 2010
The Burden of Dis proof Scott, Susannah L. ACS Catalysis, Vol. 9, Issue 5 https://doi.org/10.1021/acscatal.9b01623	journal	April 2019
Operando chemistry of catalyst surfaces during catalysis Dou, Jian; Sun, Zaicheng; Opalade, Adedamola A. Chemical Society Reviews, Vol. 46, Issue 7 https://doi.org/10.1039/C6CS00931J	journal	January 2017
Titration and quantification of open and closed Lewis acid sites in Sn-Beta zeolites that catalyze glucose isomerization Harris, James W.; Cordon, Michael J.; Di Iorio, John R. Journal of Catalysis, Vol. 335 https://doi.org/10.1016/j.jcat.2015.12.024	journal	March 2016
Best Practices for the Reporting of Colloidal Inorganic Nanomaterials Murphy, Catherine J.; Buriak, Jillian M. Chemistry of Materials, Vol. 27, Issue 14 https://doi.org/10.1021/acs.chemmater.5b02323	journal	July 2015
IR spectroscopy in catalysis Ryczkowski, Janusz Catalysis Today, Vol. 68, Issue 4 https://doi.org/10.1016/S0920-5861(01)00334-0	journal	July 2001
Probing the acid sites of zeolites with pyridine: Quantitative AGIR measurements of the molar absorption coefficients Zholobenko, Vladimir; Freitas, Cátia; Jendrlin, Martin Journal of Catalysis, Vol. 385, p. 52-60 https://doi.org/10.1016/j.jcat.2020.03.003	journal	May 2020
Effects of degree of mixing on quantitative interpretation of TPD spectra Ioannides, T. Journal of Catalysis, Vol. 120, Issue 1 https://doi.org/10.1016/0021-9517(89)90257-1	journal	November 1989
The Active Site of Methanol Synthesis over Cu/ZnO/Al₂O₃ Industrial Catalysts Behrens, M.; Studt, F.; Kasatkin, I. Science, Vol. 336, Issue 6083, p. 893-897 https://doi.org/10.1126/science.1219831	journal	April 2012
Functional assessment of the strength of solid acid catalysts Macht, Josef; Carr, Robert T.; Iglesia, Enrique Journal of Catalysis, Vol. 264, Issue 1 https://doi.org/10.1016/j.jcat.2009.03.005	journal	May 2009
CO Oxidation as a Prototypical Reaction for Heterogeneous Processes Freund, Hans-Joachim; Meijer, Gerard; Scheffler, Matthias Angewandte Chemie International Edition, Vol. 50, Issue 43 https://doi.org/10.1002/anie.201101378	journal	September 2011
The concept of active site in heterogeneous catalysis Vogt, Charlotte; Weckhuysen, Bert M. Nature Reviews Chemistry, Vol. 6, Issue 2 https://doi.org/10.1038/s41570-021-00340-y	journal	January 2022
Metal Active Sites and Their Catalytic Functions in Zeolites: Insights from Solid-State NMR Spectroscopy Xu, Jun; Wang, Qiang; Deng, Feng Accounts of Chemical Research, Vol. 52, Issue 8 https://doi.org/10.1021/acs.accounts.9b00125	journal	May 2019
An infrared study of pyridine adsorbed on acidic solids. Characterization of surface acidity Parry, E. Journal of Catalysis, Vol. 2, Issue 5 https://doi.org/10.1016/0021-9517(63)90102-7	journal	October 1963
Combining In-Situ Transmission Electron Microscopy and Infrared Spectroscopy for Understanding Dynamic and Atomic-Scale Features of Supported Metal Catalysts Resasco, Joaquin; Dai, Sheng; Graham, George The Journal of Physical Chemistry C, Vol. 122, Issue 44 https://doi.org/10.1021/acs.jpcc.8b03959	journal	June 2018
Determining the active site in a catalytic process: Operando spectroscopy is more than a buzzword Weckhuysen, Bert M. Physical Chemistry Chemical Physics, Vol. 5, Issue 20 https://doi.org/10.1039/b309650p	journal	January 2003
Control of Metal Nanocrystal Size Reveals Metal-Support Interface Role for Ceria Catalysts Cargnello, M.; Doan-Nguyen, V. V. T.; Gordon, T. R. Science, Vol. 341, Issue 6147 https://doi.org/10.1126/science.1240148	journal	July 2013
Methods for Characterizing Zeolite Acidity Farneth, W. E.; Gorte, R. J. Chemical Reviews, Vol. 95, Issue 3 https://doi.org/10.1021/cr00035a007	journal	May 1995
Isomerization and β-scission reactions of alkanes on bifunctional metal-acid catalysts: Consequences of confinement and diffusional constraints on reactivity and selectivity Noh, Gina; Shi, Zhichen; Zones, Stacey I. Journal of Catalysis, Vol. 368 https://doi.org/10.1016/j.jcat.2018.03.033	journal	December 2018
Dilute Pd/Au Alloys Replace Au/TiO ₂ Interface for Selective Oxidation Reactions Wrasman, Cody J.; Riscoe, Andrew R.; Lee, Hyosun ACS Catalysis, Vol. 10, Issue 3 https://doi.org/10.1021/acscatal.9b05227	journal	January 2020
Developments and advances in in situ transmission electron microscopy for catalysis research van der Wal, Lars I.; Turner, Savannah J.; Zečević, Jovana Catalysis Science & Technology, Vol. 11, Issue 11 https://doi.org/10.1039/D1CY00258A	journal	January 2021
Structure and site evolution of molybdenum carbide catalysts upon exposure to oxygen Sullivan, Mark M.; Held, Jacob T.; Bhan, Aditya Journal of Catalysis, Vol. 326 https://doi.org/10.1016/j.jcat.2015.03.011	journal	June 2015
In Situ Analysis of Surface Catalytic Reactions Using Shell-Isolated Nanoparticle-Enhanced Raman Spectroscopy Wang, Yao-Hui; Wei, Jie; Radjenovic, Petar Analytical Chemistry, Vol. 91, Issue 3 https://doi.org/10.1021/acs.analchem.8b05499	journal	January 2019
The Experimental Section: The Key to Longevity of Your Research Buriak, Jillian M.; Korgel, Brian Chemistry of Materials, Vol. 26, Issue 5 https://doi.org/10.1021/cm500632c	journal	March 2014
What Is Being Measured with P-Bearing NMR Probe Molecules Adsorbed on Zeolites? Bornes, Carlos; Fischer, Michael; Amelse, Jeffrey A. Journal of the American Chemical Society, Vol. 143, Issue 34 https://doi.org/10.1021/jacs.1c05014	journal	August 2021
Temperature-Programmed Desorption and Reaction: Applications to Supported Catalysts Falconer, John L.; Schwarz, James A. Catalysis Reviews, Vol. 25, Issue 2 https://doi.org/10.1080/01614948308079666	journal	June 1983
A modified commercial DRIFTS cell for kinetically relevant operando studies of heterogeneous catalytic reactions Meunier, F. C.; Goguet, A.; Shekhtman, S. Applied Catalysis A: General, Vol. 340, Issue 2 https://doi.org/10.1016/j.apcata.2008.02.034	journal	June 2008
Acid properties of solid acid catalysts characterized by solid-state 31P NMR of adsorbed phosphorous probe molecules Zheng, Anmin; Huang, Shing-Jong; Liu, Shang-Bin Physical Chemistry Chemical Physics, Vol. 13, Issue 33 https://doi.org/10.1039/c1cp20417c	journal	January 2011
Mechanistic interpretation of the effects of acid strength on alkane isomerization turnover rates and selectivity Knaeble, William; Carr, Robert T.; Iglesia, Enrique Journal of Catalysis, Vol. 319 https://doi.org/10.1016/j.jcat.2014.09.005	journal	November 2014
Substrate Size-Selective Catalysis with Zeolite-Encapsulated Gold Nanoparticles Laursen, Anders B.; Højholt, Karen T.; Lundegaard, Lars F. Angewandte Chemie, Vol. 122, Issue 20 https://doi.org/10.1002/ange.200906977	journal	April 2010
Applications of Modulation Excitation Spectroscopy in Heterogeneous Catalysis Müller, Philipp; Hermans, Ive Industrial & Engineering Chemistry Research, Vol. 56, Issue 5 https://doi.org/10.1021/acs.iecr.6b04855	journal	January 2017
Hydrogen Adsorption at the Au/TiO₂ Interface: Quantitative Determination and Spectroscopic Signature of the Reactive Interface Hydroxyl Groups at the Active Site Mahdavi-Shakib, Akbar; Rich, Lauren C.; Whittaker, Todd N. ACS Catalysis, Vol. 11, Issue 24 https://doi.org/10.1021/acscatal.1c04419	journal	December 2021
Uniform Pt/Pd Bimetallic Nanocrystals Demonstrate Platinum Effect on Palladium Methane Combustion Activity and Stability Goodman, Emmett D.; Dai, Sheng; Yang, An-Chih ACS Catalysis, Vol. 7, Issue 7 https://doi.org/10.1021/acscatal.7b00393	journal	May 2017
Temperature-programmed desorption for the characterization of oxide catalysts Gorte, R. J. Catalysis Today, Vol. 28, Issue 4 https://doi.org/10.1016/S0920-5861(96)00249-0	journal	September 1996
Open Data in Catalysis: From Today's Big Picture to the Future of Small Data Mendes, Pedro S. F.; Siradze, Sébastien; Pirro, Laura ChemCatChem, Vol. 13, Issue 3 https://doi.org/10.1002/cctc.202001132	journal	December 2020
Reactivity of Pd–MO₂ encapsulated catalytic systems for CO oxidation Paz Herrera, Laura; Freitas de Lima e. Freitas, Lucas; Hong, Jiyun Catalysis Science & Technology, Vol. 12, Issue 5 https://doi.org/10.1039/D1CY01916C	journal	January 2022
Raman and IR studies of surface metal oxide species on oxide supports: Supported metal oxide catalysts Wachs, Israel E. Catalysis Today, Vol. 27, Issue 3-4 https://doi.org/10.1016/0920-5861(95)00203-0	journal	February 1996
Reverse Water–Gas Shift on Interfacial Sites Formed by Deposition of Oxidized Molybdenum Moieties onto Gold Nanoparticles Carrasquillo-Flores, Ronald; Ro, Insoo; Kumbhalkar, Mrunmayi D. Journal of the American Chemical Society, Vol. 137, Issue 32 https://doi.org/10.1021/jacs.5b05945	journal	August 2015
Methanol oxidation as a catalytic surface probe Tatibouët, J. M. Applied Catalysis A: General, Vol. 148, Issue 2 https://doi.org/10.1016/S0926-860X(96)00236-0	journal	January 1997
The effect of metal particle size on the stoichiometry of adsorption Ladas, S. Surface Science, Vol. 175, Issue 1 https://doi.org/10.1016/0039-6028(86)90074-9	journal	September 1986
Condensation and esterification reactions of alkanals, alkanones, and alkanols on TiO2: Elementary steps, site requirements, and synergistic effects of bifunctional strategies Wang, Shuai; Goulas, Konstantinos; Iglesia, Enrique Journal of Catalysis, Vol. 340 https://doi.org/10.1016/j.jcat.2016.05.026	journal	August 2016
Redefining the Experimental and Methods Sections Millstone, Jill E.; Chan, Warren C. W.; Kagan, Cherie R. ACS Nano, Vol. 13, Issue 5 https://doi.org/10.1021/acsnano.9b03753	journal	May 2019
Catalysis by crystalline aluminosilicates: Characterization of intermediate pore-size zeolites by the ?Constraint Index? Frillette, V. Journal of Catalysis, Vol. 67, Issue 1 https://doi.org/10.1016/0021-9517(81)90273-6	journal	January 1981
Characterization of H,Na-Y Using Amine Desorption Biaglow, A. I.; Parrillo, D. J.; Gorte, R. J. Journal of Catalysis, Vol. 144, Issue 1 https://doi.org/10.1006/jcat.1993.1323	journal	November 1993
Developing quantitative synthesis-structure-function relations for framework aluminum arrangement effects in zeolite acid catalysis Bickel, Elizabeth E.; Nimlos, Claire T.; Gounder, Rajamani Journal of Catalysis, Vol. 399 https://doi.org/10.1016/j.jcat.2021.04.027	journal	July 2021
Ammonia Synthesis from First-Principles Calculations Honkala, K. Science, Vol. 307, Issue 5709 https://doi.org/10.1126/science.1106435	journal	January 2005
Prerequisites for kinetic modeling of TPD data of porous catalysts—Exemplified by toluene/H-ZSM-5 system Kanervo, J. M.; Kouva, S.; Kanervo, K. J. Chemical Engineering Science, Vol. 137 https://doi.org/10.1016/j.ces.2015.07.032	journal	December 2015
Extracting Knowledge from Data through Catalysis Informatics Medford, Andrew J.; Kunz, M. Ross; Ewing, Sarah M. ACS Catalysis, Vol. 8, Issue 8 https://doi.org/10.1021/acscatal.8b01708	journal	June 2018
Electron microscopy of catalysts: recent achievements and future prospects Datye, Abhaya K. Journal of Catalysis, Vol. 216, Issue 1-2 https://doi.org/10.1016/S0021-9517(02)00113-6	journal	May 2003
Relevance of IR Spectroscopy of Adsorbed CO for the Characterization of Heterogeneous Catalysts Containing Isolated Atoms Meunier, Frederic C. The Journal of Physical Chemistry C, Vol. 125, Issue 40 https://doi.org/10.1021/acs.jpcc.1c06784	journal	September 2021
Effective bulk and surface temperatures of the catalyst bed of FT-IR cells used for in situ and operando studies Li, Haoguang; Rivallan, Mickael; Thibault-Starzyk, Frederic Physical Chemistry Chemical Physics, Vol. 15, Issue 19 https://doi.org/10.1039/c3cp50442e	journal	January 2013
Quantitative Analysis of Adsorbate Concentrations by Diffuse Reflectance FT-IR Sirita, Jinda; Phanichphant, Sukon; Meunier, Frederic C. Analytical Chemistry, Vol. 79, Issue 10 https://doi.org/10.1021/ac0702802	journal	May 2007
Molecular Structure and Confining Environment of Sn Sites in Single-Site Chabazite Zeolites Harris, James W.; Liao, Wei-Chih; Di Iorio, John R. Chemistry of Materials, Vol. 29, Issue 20 https://doi.org/10.1021/acs.chemmater.7b03209	journal	October 2017
A Theory of the Catalytic Surface Taylor, H. S. Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 108, Issue 745 https://doi.org/10.1098/rspa.1925.0061	journal	May 1925
Pitfalls and benefits of in situ and operando diffuse reflectance FT-IR spectroscopy (DRIFTS) applied to catalytic reactions Meunier, F. C. Reaction Chemistry & Engineering, Vol. 1, Issue 2 https://doi.org/10.1039/C5RE00018A	journal	January 2016
Decomposition of formic acid on copper, nickel, and copper-nickel alloys I. Preparation and characterization of catalysts Iglesia, E. Journal of Catalysis, Vol. 81, Issue 1 https://doi.org/10.1016/0021-9517(83)90158-6	journal	May 1983
Acidity characterization of heterogeneous catalysts by solid-state NMR spectroscopy using probe molecules Zheng, Anmin; Liu, Shang-Bin; Deng, Feng Solid State Nuclear Magnetic Resonance, Vol. 55-56 https://doi.org/10.1016/j.ssnmr.2013.09.001	journal	October 2013

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