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Gel electrolyte composite including ionic liquid and zwitterionic polymer scaffold

Patent ·
OSTI ID:2293891

A gel electrolyte composite containing a nonvolatile electrolyte and a zwitterionic polymer scaffold in which the non-volatile electrolyte is a non-lithium-containing ionic liquid, a sodium-containing ionic liquid, or a lithium-containing ionic liquid and the zwitterionic polymer scaffold is formed from one or more zwitterionic monomers only or both one or more zwitterionic monomers and one or more non-zwitterionic monomers. The zwitterionic polymer scaffold contains 8 mol % or higher of zwitterions relative to the total content of the gel electrolyte composite when the nonvolatile electrolyte is a non-lithium-containing ionic liquid, and contains 1 mol % or higher of zwitterions relative to the total content of the gel electrolyte composite when the nonvolatile electrolyte is a sodium-containing ionic liquid or a lithium-containing ionic liquid. Also disclosed are a method of preparing the above-described gel electrolyte composite and an electrochemical energy storage device containing same.

Research Organization:
Tufts Univ., Medford, MA (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
SC0016423
Assignee:
Trustees of Tufts College (Medford, MA)
Patent Number(s):
11,824,158
Application Number:
16/754,046
OSTI ID:
2293891
Country of Publication:
United States
Language:
English

References (6)

Mechanically strong ionogels formed by immobilizing ionic liquid in polyzwitterion networks journal December 2017
Lithium-Containing Zwitterionic Poly(Ionic Liquid)s as Polymer Electrolytes for Lithium-Ion Batteries journal August 2017
Synthesis and Evaluation of Polybetaine-Type Ion Gel Electrolytes journal January 2017
Zwitterion-Containing Ionogel Electrolytes journal November 2016
Ion conduction in zwitterionic-type molten salts and their polymers journal January 2001
Effect of Ionic Liquid on Mechanical Properties and Morphology of Zwitterionic Copolymer Membranes journal December 2009

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