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Activation of Hydrogen Under Ambient Conditions by Main Group Molecules

Technical Report ·
DOI:https://doi.org/10.2172/2283951· OSTI ID:2283951
 [1];  [2];  [2];  [2];  [2];  [2];  [2];  [2];  [2];  [2];  [2];  [2]
  1. Univ. of California (United States); University of California
  2. Univ. of California (United States)
+ Show Author Affiliations

The major goals as indicated by the title are the detailed understanding of the interactions of main group compounds with small molecules such as H2, NH3, CO, C2H4 and related species as well as the development of catalysts based on inexpensive main group (13 or 14) elements such as aluminum or silicon. A key feature of the compounds studied is the existence of Lewis acidic and basic sites at the main group element such that the small molecules become activated in a synergistic manner under relatively mild conditions.

Research Organization:
Univ. of California (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
DOE Contract Number:
FG02-07ER46475
OSTI ID:
2283951
Report Number(s):
DOE-UCDAVIS--202EPPP
Country of Publication:
United States
Language:
English

References (8)

Insertion Reactions of NH3 and H2O with the Ferriogermylenes ArGeFeCp(CO)2 (Ar = ArMe6 (−C6H3-(C6H2-2,4,6-Me3)2) or AriPr4 (−C6H3-(C6H3-2,6-iPr2)2); Cp = η5-C5H5): Structural Isomerism and Polymorphism in a Metallogermylene journal October 2021
Hydrostannylation of Olefins by a Hydridostannylene Tungsten Complex journal November 2022
Germanium Hydride Radical Trapped during the Photolysis/Thermolysis of Diarylgermylene journal October 2019
Metathetical Exchange between Metal–Metal Triple Bonds journal January 2020
Synthesis, Structure, and Spectroscopy of the Biscarboranyl Stannylenes (bc)Sn·THF and K2[(bc)Sn]2 (bc = 1,1′(ortho-Biscarborane)) and Dibiscarboranyl Ethene (bc)CH═CH(bc) journal June 2023
Hydrostannylation of carbon dioxide by a hydridostannylene molybdenum complex journal January 2021
The Monomeric Alanediyl :AlAriPr8 (AriPr8 = C6H-2,6-(C6H2-2,4,6-Pri3)2-3,5-Pri2): An Organoaluminum(I) Compound with a One-Coordinate Aluminum Atom journal November 2020
N–N Double-Bond Cleavage and Azobenzene Rearrangement with C–C Bond Formation Induced by a Germylene journal June 2022

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY