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Title: Effect of quenching rate on the microstructure and mechanical behavior of Ce75Al21Ga4 glassy alloy

Journal Article · · Materials Characterization
 [1];  [2];  [3];
  1. Department of Physics, Nano–Science Unit, Banaras Hindu University, Varanasi 221005 (India)
  2. Department of Physics, Panjab University, Chandigarh 160014 (India)
  3. Department of Metallurgical Engineering, Indian Institute of Technology (Banaras Hindu University), Varanasi 221005 (India)

Highlights: • Structural and microstructural changes with respect to quenching rate have been reported. • Ribbons synthesized at slow cooling rate shows higher hardness and yield strength. • Study is focused on the correlation between quenching rate and mechanical behavior. • Metallic glass synthesized at faster quenching rate contains the highest shear band density. - Abstract: The present study deals with the structural and microstructural changes with respect to the quenching rate and their correlation with mechanical behavior of melt-spun Ce{sub 75}Al{sub 21}Ga{sub 4} glassy alloys. The ribbons of the alloy have been synthesized at different quenching rates obtained through different wheel speeds (44, 36, 29, 22 and 15 m/s). The glass forming indicators and mechanical properties have been investigated at different quenching rates. The higher quenching rate obtained through high wheel speed (44, 36 and 29 m/s) has led to phase separation giving rise to nano-amorphous domains in a glassy matrix while the lower quenching rate obtained through lower wheel speed (22 and 15 m/s) produces nano-crystalline grains with size ranges from 25 ± 1 to 120 ± 1 nm. It has been found that the size of the nano-amorphous domains decreases with decrease in wheel speed. The mechanical behavior has been studied using micro-indentation technique. The indentation test indicates that with the same chemical composition, the ribbons synthesized at slow quenching rate exhibits higher hardness and yield strength than those synthesized at faster quenching rate. The ribbons synthesized at 44 m/s contains the large free volume and has the highest shear band density.

OSTI ID:
22804805
Journal Information:
Materials Characterization, Vol. 134; Other Information: Copyright (c) 2017 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA); ISSN 1044-5803
Country of Publication:
United States
Language:
English

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