Synthesis and structural characterization of a Cu(I) complex with 4-(1H-imidazol-1-yl)phenyl)methanone ligands

Journal Article · Wed Nov 15 00:00:00 EST 2017 · Crystallography Reports

DOI:https://doi.org/10.1134/S1063774517060268· OSTI ID:22758327

Wang, Gao-Feng ^[1]; Zhang, Xiao ^[2]; Sun, Shu-Wen; Sun, Hong; Zhang, Wen-Chan; Yang, Xia; Qin, Ying-Lian; Ma, Hui-Xuan ^[1]

---

1. Yuncheng University, Department of Applied Chemistry (China)
2. Harbin Institute of Technology, MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage, School of Chemistry and Chemical Engineering (China)

A copper complex with V-shaped ligands, [(L{sup 1})Cu{sub 2}Cl{sub 2}]{sub n} (1), (L1 = 4-(1H-imidazol-1-yl)phenyl) methanone) has been synthesized and characterized by IR spectroscopy, elemental analyses and singlecrystal X-ray diffraction. The crystal of 1 is monoclinic, sp. gr. C2/{sub c} with the unit cell parameters a = 17.9496(13), b = 15.3440(13), c = 7.2983(7) Å, and β = 112.875(6)°, Z = 4, R{sub 1} = 0.0681, and wR{sub 2} = 0.1736 (I > 2 σ). The solid state structure of 1 consists of 2D metal aromatic chloride layers, which are propagating along the bc plane to form a 3D network through hydrogen bonds.

• OSTI ID: 22758327
• Journal Information: Crystallography Reports, Vol. 62, Issue 6; Other Information: Copyright (c) 2017 Pleiades Publishing, Inc.; Country of input: International Atomic Energy Agency (IAEA); ISSN 1063-7745
• Country of Publication: United States
• Language: English

Related Subjects

75 CONDENSED MATTER PHYSICS
SUPERCONDUCTIVITY AND SUPERFLUIDITY
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
AROMATICS
CHLORIDES
COPPER COMPLEXES
CRYSTALS
HYDROGEN
INFRARED SPECTRA
LAYERS
LIGANDS
MONOCLINIC LATTICES
SYNTHESIS
X-RAY DIFFRACTION