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Title: Synthesis and structural characterization of a Cu(I) complex with 4-(1H-imidazol-1-yl)phenyl)methanone ligands

Abstract

A copper complex with V-shaped ligands, [(L{sup 1})Cu{sub 2}Cl{sub 2}]{sub n} (1), (L1 = 4-(1H-imidazol-1-yl)phenyl) methanone) has been synthesized and characterized by IR spectroscopy, elemental analyses and singlecrystal X-ray diffraction. The crystal of 1 is monoclinic, sp. gr. C2/{sub c} with the unit cell parameters a = 17.9496(13), b = 15.3440(13), c = 7.2983(7) Å, and β = 112.875(6)°, Z = 4, R{sub 1} = 0.0681, and wR{sub 2} = 0.1736 (I > 2 σ). The solid state structure of 1 consists of 2D metal aromatic chloride layers, which are propagating along the bc plane to form a 3D network through hydrogen bonds.

Authors:
 [1];  [2]; ; ; ; ; ;  [1]
  1. Yuncheng University, Department of Applied Chemistry (China)
  2. Harbin Institute of Technology, MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage, School of Chemistry and Chemical Engineering (China)
Publication Date:
OSTI Identifier:
22758327
Resource Type:
Journal Article
Journal Name:
Crystallography Reports
Additional Journal Information:
Journal Volume: 62; Journal Issue: 6; Other Information: Copyright (c) 2017 Pleiades Publishing, Inc.; Country of input: International Atomic Energy Agency (IAEA); Journal ID: ISSN 1063-7745
Country of Publication:
United States
Language:
English
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; AROMATICS; CHLORIDES; COPPER COMPLEXES; CRYSTALS; HYDROGEN; INFRARED SPECTRA; LAYERS; LIGANDS; MONOCLINIC LATTICES; SYNTHESIS; X-RAY DIFFRACTION

Citation Formats

Wang, Gao-Feng, Zhang, Xiao, Sun, Shu-Wen, Sun, Hong, Zhang, Wen-Chan, Yang, Xia, Qin, Ying-Lian, and Ma, Hui-Xuan. Synthesis and structural characterization of a Cu(I) complex with 4-(1H-imidazol-1-yl)phenyl)methanone ligands. United States: N. p., 2017. Web. doi:10.1134/S1063774517060268.
Wang, Gao-Feng, Zhang, Xiao, Sun, Shu-Wen, Sun, Hong, Zhang, Wen-Chan, Yang, Xia, Qin, Ying-Lian, & Ma, Hui-Xuan. Synthesis and structural characterization of a Cu(I) complex with 4-(1H-imidazol-1-yl)phenyl)methanone ligands. United States. doi:10.1134/S1063774517060268.
Wang, Gao-Feng, Zhang, Xiao, Sun, Shu-Wen, Sun, Hong, Zhang, Wen-Chan, Yang, Xia, Qin, Ying-Lian, and Ma, Hui-Xuan. Wed . "Synthesis and structural characterization of a Cu(I) complex with 4-(1H-imidazol-1-yl)phenyl)methanone ligands". United States. doi:10.1134/S1063774517060268.
@article{osti_22758327,
title = {Synthesis and structural characterization of a Cu(I) complex with 4-(1H-imidazol-1-yl)phenyl)methanone ligands},
author = {Wang, Gao-Feng and Zhang, Xiao and Sun, Shu-Wen and Sun, Hong and Zhang, Wen-Chan and Yang, Xia and Qin, Ying-Lian and Ma, Hui-Xuan},
abstractNote = {A copper complex with V-shaped ligands, [(L{sup 1})Cu{sub 2}Cl{sub 2}]{sub n} (1), (L1 = 4-(1H-imidazol-1-yl)phenyl) methanone) has been synthesized and characterized by IR spectroscopy, elemental analyses and singlecrystal X-ray diffraction. The crystal of 1 is monoclinic, sp. gr. C2/{sub c} with the unit cell parameters a = 17.9496(13), b = 15.3440(13), c = 7.2983(7) Å, and β = 112.875(6)°, Z = 4, R{sub 1} = 0.0681, and wR{sub 2} = 0.1736 (I > 2 σ). The solid state structure of 1 consists of 2D metal aromatic chloride layers, which are propagating along the bc plane to form a 3D network through hydrogen bonds.},
doi = {10.1134/S1063774517060268},
journal = {Crystallography Reports},
issn = {1063-7745},
number = 6,
volume = 62,
place = {United States},
year = {2017},
month = {11}
}