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Title: A Novel Coordination Polymer Based on Trinuclear Cobalt Building Blocks Cluster: Synthesis, Crystal Structure, and Properties

Abstract

The title compound {[Co_3(μ_3-OH)(μ_2-H_2O)2(H_2O)_5(BTC)_2] · 6H_2O}{sub n} (H{sub 3}BTC is a 1,3,5-benzenetricarboxylic acid) was prepared and characterized by single crystal and powder X-ray diffraction, Fourier transform infrared spectroscopy, thermogravimetric and elemental analyses. The single crystal X-ray diffraction reveals that the title compound consists of 1D infinite zigzag chains which were constructed by trinuclear cobalt cluster and BTC{sup 3–} ligand. Neighbouring above-mentioned 1D infinite zigzag chains are further linked by intermolecular hydrogen bonding to form a 3D supermolecular structure. In addition, the luminescent properties of the title compound were investigated.

Authors:
; ; ; ; ; ;  [1]
  1. Shaanxi University of Technology, Shaanxi Province Key Laboratory of Catalytic Foundation and Application, College of Chemical and Environment Science (China)
Publication Date:
OSTI Identifier:
22758310
Resource Type:
Journal Article
Journal Name:
Crystallography Reports
Additional Journal Information:
Journal Volume: 62; Journal Issue: 7; Other Information: Copyright (c) 2017 Pleiades Publishing, Inc.; Country of input: International Atomic Energy Agency (IAEA); Journal ID: ISSN 1063-7745
Country of Publication:
United States
Language:
English
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; BONDING; CARBONATES; COBALT; FOURIER TRANSFORM SPECTROMETERS; HYDROGEN; LIGANDS; LUMINESCENCE; MONOCRYSTALS; POLYMERS; POWDERS; SYNTHESIS; THERMAL GRAVIMETRIC ANALYSIS; THREE-DIMENSIONAL LATTICES; WATER; X-RAY DIFFRACTION

Citation Formats

Lu, J. F., E-mail: jiufulu@163.com, Tang, Z. H., Shi, J., Ge, H. G., Jiang, M., Song, J., and Jin, L. X. A Novel Coordination Polymer Based on Trinuclear Cobalt Building Blocks Cluster: Synthesis, Crystal Structure, and Properties. United States: N. p., 2017. Web. doi:10.1134/S1063774517070161.
Lu, J. F., E-mail: jiufulu@163.com, Tang, Z. H., Shi, J., Ge, H. G., Jiang, M., Song, J., & Jin, L. X. A Novel Coordination Polymer Based on Trinuclear Cobalt Building Blocks Cluster: Synthesis, Crystal Structure, and Properties. United States. doi:10.1134/S1063774517070161.
Lu, J. F., E-mail: jiufulu@163.com, Tang, Z. H., Shi, J., Ge, H. G., Jiang, M., Song, J., and Jin, L. X. Fri . "A Novel Coordination Polymer Based on Trinuclear Cobalt Building Blocks Cluster: Synthesis, Crystal Structure, and Properties". United States. doi:10.1134/S1063774517070161.
@article{osti_22758310,
title = {A Novel Coordination Polymer Based on Trinuclear Cobalt Building Blocks Cluster: Synthesis, Crystal Structure, and Properties},
author = {Lu, J. F., E-mail: jiufulu@163.com and Tang, Z. H. and Shi, J. and Ge, H. G. and Jiang, M. and Song, J. and Jin, L. X.},
abstractNote = {The title compound {[Co_3(μ_3-OH)(μ_2-H_2O)2(H_2O)_5(BTC)_2] · 6H_2O}{sub n} (H{sub 3}BTC is a 1,3,5-benzenetricarboxylic acid) was prepared and characterized by single crystal and powder X-ray diffraction, Fourier transform infrared spectroscopy, thermogravimetric and elemental analyses. The single crystal X-ray diffraction reveals that the title compound consists of 1D infinite zigzag chains which were constructed by trinuclear cobalt cluster and BTC{sup 3–} ligand. Neighbouring above-mentioned 1D infinite zigzag chains are further linked by intermolecular hydrogen bonding to form a 3D supermolecular structure. In addition, the luminescent properties of the title compound were investigated.},
doi = {10.1134/S1063774517070161},
journal = {Crystallography Reports},
issn = {1063-7745},
number = 7,
volume = 62,
place = {United States},
year = {2017},
month = {12}
}