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Title: Synthesis and Crystal Structure of Dibromido{2-[(4-tert-butylmethylphenyl) iminomethyl]pyridine-κ"2N,N'}Zinc

Abstract

The title compound [Zn(dip)Br{sub 2}] was synthesized using the Schiff base bidentate ligand (E)-4-tert-butyl-N-(pyridine-2-ylmethylene)benzeneamine (dip) and zinc(II) bromide salts. It has been characterized by elemental analysis, X-ray diffraction, and optical spectroscopy. The X-ray diffraction analysis demonstrates that in this structure, the zinc(II) ion is located on an inversion center and exhibits a ZnN{sub 2}Br{sub 2} tetrahedral geometry. In this structure the dip ligand is coordinated with zinc(II) ion in a cyclic-bidentate fashion forming a five-membered metallocyclic ring. The compound crystallizes in the monoclinic sp. gr. P2{sub 1}/m with a = 9.2700(13) Å, b = 7.6128(11) Å, c = 12.3880(17) Å, and β = 97.021(3)°.

Authors:
; ; ;  [1]
  1. Islamic Azad University, Young Researchers and Elite Club, Buinzahra Branch (Iran, Islamic Republic of)
Publication Date:
OSTI Identifier:
22758306
Resource Type:
Journal Article
Journal Name:
Crystallography Reports
Additional Journal Information:
Journal Volume: 62; Journal Issue: 7; Other Information: Copyright (c) 2017 Pleiades Publishing, Inc.; Country of input: International Atomic Energy Agency (IAEA); Journal ID: ISSN 1063-7745
Country of Publication:
United States
Language:
English
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; CRYSTAL STRUCTURE; GEOMETRY; LIGANDS; MONOCLINIC LATTICES; RINGS; SALTS; SCHIFF BASES; SPECTROSCOPY; SYNTHESIS; X-RAY DIFFRACTION; ZINC BROMIDES; ZINC IONS

Citation Formats

Khalaj, M., E-mail: khalaj-mehdi@yahoo.com, Ghazanfarpour-Darjani, M., Seftejani, F. B., and Lalegani, A. Synthesis and Crystal Structure of Dibromido{2-[(4-tert-butylmethylphenyl) iminomethyl]pyridine-κ"2N,N'}Zinc. United States: N. p., 2017. Web. doi:10.1134/S1063774517070112.
Khalaj, M., E-mail: khalaj-mehdi@yahoo.com, Ghazanfarpour-Darjani, M., Seftejani, F. B., & Lalegani, A. Synthesis and Crystal Structure of Dibromido{2-[(4-tert-butylmethylphenyl) iminomethyl]pyridine-κ"2N,N'}Zinc. United States. doi:10.1134/S1063774517070112.
Khalaj, M., E-mail: khalaj-mehdi@yahoo.com, Ghazanfarpour-Darjani, M., Seftejani, F. B., and Lalegani, A. Fri . "Synthesis and Crystal Structure of Dibromido{2-[(4-tert-butylmethylphenyl) iminomethyl]pyridine-κ"2N,N'}Zinc". United States. doi:10.1134/S1063774517070112.
@article{osti_22758306,
title = {Synthesis and Crystal Structure of Dibromido{2-[(4-tert-butylmethylphenyl) iminomethyl]pyridine-κ"2N,N'}Zinc},
author = {Khalaj, M., E-mail: khalaj-mehdi@yahoo.com and Ghazanfarpour-Darjani, M. and Seftejani, F. B. and Lalegani, A.},
abstractNote = {The title compound [Zn(dip)Br{sub 2}] was synthesized using the Schiff base bidentate ligand (E)-4-tert-butyl-N-(pyridine-2-ylmethylene)benzeneamine (dip) and zinc(II) bromide salts. It has been characterized by elemental analysis, X-ray diffraction, and optical spectroscopy. The X-ray diffraction analysis demonstrates that in this structure, the zinc(II) ion is located on an inversion center and exhibits a ZnN{sub 2}Br{sub 2} tetrahedral geometry. In this structure the dip ligand is coordinated with zinc(II) ion in a cyclic-bidentate fashion forming a five-membered metallocyclic ring. The compound crystallizes in the monoclinic sp. gr. P2{sub 1}/m with a = 9.2700(13) Å, b = 7.6128(11) Å, c = 12.3880(17) Å, and β = 97.021(3)°.},
doi = {10.1134/S1063774517070112},
journal = {Crystallography Reports},
issn = {1063-7745},
number = 7,
volume = 62,
place = {United States},
year = {2017},
month = {12}
}