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Title: Synthesis and Crystal Structure of Di-μ-chlorido-bis{chlorido[4-ethyl-N-(pyridin-2-ylmethylidene-κN)aniline-κN]mercury(II)}

Abstract

The centrosymmetric dinuclear title complex [Hg{sub 2}Cl{sub 4}(dip){sub 2}] was synthesized using the Schiff base bidentate ligand (E)-4-ethyl-N-(pyridine-2-ylmethylene)benzeneamine (dip) and mercury(II) chloride salts. It has been characterized by elemental analysis, X-ray diffraction, and UV-Visible and infrared spectroscopic techniques. The X-ray analysis shows that the title compound crystallizes in the monoclinic sp. gr. P2{sub 1}/n, Z = 2 with a = 7.8233(17) Å, b = 15.178(3) Å, c = 12.559(3) Å, β = 97.021(3)°. The Hg(II) ion has a distorted trigonal–bipyramidal coordination environment formed by the bischelating N-heterocyclic ligands, two bridging Cl atoms and one terminal Cl atom.

Authors:
; ; ;  [1]
  1. Islamic Azad University, Young Researchers and Elite Club, Buinzahra Branch (Iran, Islamic Republic of)
Publication Date:
OSTI Identifier:
22758305
Resource Type:
Journal Article
Journal Name:
Crystallography Reports
Additional Journal Information:
Journal Volume: 62; Journal Issue: 7; Other Information: Copyright (c) 2017 Pleiades Publishing, Inc.; Country of input: International Atomic Energy Agency (IAEA); Journal ID: ISSN 1063-7745
Country of Publication:
United States
Language:
English
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; ANILINE; ATOMS; COMPLEXES; CRYSTAL STRUCTURE; INFRARED SPECTRA; LIGANDS; MERCURY; MERCURY CHLORIDES; MERCURY IONS; MONOCLINIC LATTICES; PYRIDINE; SALTS; SCHIFF BASES; SYNTHESIS; ULTRAVIOLET SPECTRA; VISIBLE SPECTRA; X-RAY DIFFRACTION

Citation Formats

Khalaj, M., E-mail: khalaj-mehdi@yahoo.com, Seftejani, F. B., Ghazanfarpour-Darjani, M., and Lalegani, A.. Synthesis and Crystal Structure of Di-μ-chlorido-bis{chlorido[4-ethyl-N-(pyridin-2-ylmethylidene-κN)aniline-κN]mercury(II)}. United States: N. p., 2017. Web. doi:10.1134/S1063774517070124.
Khalaj, M., E-mail: khalaj-mehdi@yahoo.com, Seftejani, F. B., Ghazanfarpour-Darjani, M., & Lalegani, A.. Synthesis and Crystal Structure of Di-μ-chlorido-bis{chlorido[4-ethyl-N-(pyridin-2-ylmethylidene-κN)aniline-κN]mercury(II)}. United States. doi:10.1134/S1063774517070124.
Khalaj, M., E-mail: khalaj-mehdi@yahoo.com, Seftejani, F. B., Ghazanfarpour-Darjani, M., and Lalegani, A.. Fri . "Synthesis and Crystal Structure of Di-μ-chlorido-bis{chlorido[4-ethyl-N-(pyridin-2-ylmethylidene-κN)aniline-κN]mercury(II)}". United States. doi:10.1134/S1063774517070124.
@article{osti_22758305,
title = {Synthesis and Crystal Structure of Di-μ-chlorido-bis{chlorido[4-ethyl-N-(pyridin-2-ylmethylidene-κN)aniline-κN]mercury(II)}},
author = {Khalaj, M., E-mail: khalaj-mehdi@yahoo.com and Seftejani, F. B. and Ghazanfarpour-Darjani, M. and Lalegani, A.},
abstractNote = {The centrosymmetric dinuclear title complex [Hg{sub 2}Cl{sub 4}(dip){sub 2}] was synthesized using the Schiff base bidentate ligand (E)-4-ethyl-N-(pyridine-2-ylmethylene)benzeneamine (dip) and mercury(II) chloride salts. It has been characterized by elemental analysis, X-ray diffraction, and UV-Visible and infrared spectroscopic techniques. The X-ray analysis shows that the title compound crystallizes in the monoclinic sp. gr. P2{sub 1}/n, Z = 2 with a = 7.8233(17) Å, b = 15.178(3) Å, c = 12.559(3) Å, β = 97.021(3)°. The Hg(II) ion has a distorted trigonal–bipyramidal coordination environment formed by the bischelating N-heterocyclic ligands, two bridging Cl atoms and one terminal Cl atom.},
doi = {10.1134/S1063774517070124},
journal = {Crystallography Reports},
issn = {1063-7745},
number = 7,
volume = 62,
place = {United States},
year = {2017},
month = {12}
}