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Title: Crystal structure of (E)-3-fluoro-N-((5-nitrothiophen-2-yl)methylene)aniline

Abstract

The structure of the title compound C{sub 11}H{sub 7}FN{sub 2}O{sub 2}S was characterized by single crystal X-ray diffraction. The compound crystallizes in the monoclinic space group P2{sub 1}/n with Z = 12, i.e. with three molecules in asymmetric unit. The molecules are not planar: the dihedral angles between the planes of thiophene and the benzene rings are 42.3(3)°, 42.0(3)°, and 48.9(2)°. In the crystal, intermolecular C–H···F interactions link the molecules through R{sub 2}{sup 2} (14) ring motif. The crystal packing is also stabilized by π···π interactions.

Authors:
;  [1];  [2]
  1. Amasya University, Department of Physics, Faculty of Arts and Sciences (Turkey)
  2. Ondokuz Mayıs University, Department of Chemistry, Faculty of Arts and Sciences (Turkey)
Publication Date:
OSTI Identifier:
22645522
Resource Type:
Journal Article
Resource Relation:
Journal Name: Crystallography Reports; Journal Volume: 61; Journal Issue: 3; Other Information: Copyright (c) 2016 Pleiades Publishing, Inc.; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; ANILINE; BENZENE; CRYSTAL STRUCTURE; MONOCLINIC LATTICES; MONOCRYSTALS; POLYCYCLIC SULFUR HETEROCYCLES; SPACE GROUPS; THIOPHENE; X-RAY DIFFRACTION

Citation Formats

Karataş, Şadiye, Tanak, Hasan, E-mail: hasantanak@gmail.com, and Ağar, Ayşen Alaman. Crystal structure of (E)-3-fluoro-N-((5-nitrothiophen-2-yl)methylene)aniline. United States: N. p., 2016. Web. doi:10.1134/S1063774516030147.
Karataş, Şadiye, Tanak, Hasan, E-mail: hasantanak@gmail.com, & Ağar, Ayşen Alaman. Crystal structure of (E)-3-fluoro-N-((5-nitrothiophen-2-yl)methylene)aniline. United States. doi:10.1134/S1063774516030147.
Karataş, Şadiye, Tanak, Hasan, E-mail: hasantanak@gmail.com, and Ağar, Ayşen Alaman. Sun . "Crystal structure of (E)-3-fluoro-N-((5-nitrothiophen-2-yl)methylene)aniline". United States. doi:10.1134/S1063774516030147.
@article{osti_22645522,
title = {Crystal structure of (E)-3-fluoro-N-((5-nitrothiophen-2-yl)methylene)aniline},
author = {Karataş, Şadiye and Tanak, Hasan, E-mail: hasantanak@gmail.com and Ağar, Ayşen Alaman},
abstractNote = {The structure of the title compound C{sub 11}H{sub 7}FN{sub 2}O{sub 2}S was characterized by single crystal X-ray diffraction. The compound crystallizes in the monoclinic space group P2{sub 1}/n with Z = 12, i.e. with three molecules in asymmetric unit. The molecules are not planar: the dihedral angles between the planes of thiophene and the benzene rings are 42.3(3)°, 42.0(3)°, and 48.9(2)°. In the crystal, intermolecular C–H···F interactions link the molecules through R{sub 2}{sup 2} (14) ring motif. The crystal packing is also stabilized by π···π interactions.},
doi = {10.1134/S1063774516030147},
journal = {Crystallography Reports},
number = 3,
volume = 61,
place = {United States},
year = {Sun May 15 00:00:00 EDT 2016},
month = {Sun May 15 00:00:00 EDT 2016}
}