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Title: Production of complex rubidium and cesium hydrogen sulfate‒phosphates

Abstract

The solubility in the CsH{sub 2}PO{sub 4}‒CsHSO{sub 4}‒H{sub 2}O system at different temperatures (25, 50, and 75°C) is studied and the phase equilibria in the Rb{sub 3}H(SO{sub 4}){sub 2}‒RbH{sub 2}PO{sub 4}‒H{sub 2}O system under isothermal conditions (at 25°C) are analyzed. The temperature and concentration conditions for forming Rb{sub 2}(HSO{sub 4})(H{sub 2}PO{sub 4}), Rb{sub 4}(HSO{sub 4}){sub 3}(H{sub 2}PO{sub 4}), Cs{sub 4}(HSO{sub 4}){sub 3}(H{sub 2}PO{sub 4}), Cs{sub 3}(HSO{sub 4}){sub 2}(H{sub 2}PO{sub 4}), Cs{sub 2}(HSO{sub 4})(H{sub 2}PO{sub 4}), and Cs{sub 6}H(HSO{sub 4}){sub 3}(H{sub 2}PO{sub 4}){sub 4} compounds (the latter has been obtained for the first time) are determined. The conditions for growing large single crystals of complex acid rubidium and cesium salts are found.

Authors:
; ; ;  [1];  [2]
  1. Russian Academy of Sciences, Shubnikov Institute of Crystallography (Russian Federation)
  2. Lobachevsky State University of Nizhny Novgorod (Russian Federation)
Publication Date:
OSTI Identifier:
22645431
Resource Type:
Journal Article
Resource Relation:
Journal Name: Crystallography Reports; Journal Volume: 61; Journal Issue: 4; Other Information: Copyright (c) 2016 Pleiades Publishing, Inc.; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; CARBON SULFIDES; CESIUM PHOSPHATES; CRYSTAL GROWTH; HYDROGEN PHOSPHATES; HYDROGEN SULFATES; MONOCRYSTALS; RUBIDIUM PHOSPHATES; RUBIDIUM SULFATES

Citation Formats

Komornikov, V. A., E-mail: v.a.kom@mail.ru, Grebenev, V. V., Makarova, I. P., Selezneva, E. V., and Andreev, P. V. Production of complex rubidium and cesium hydrogen sulfate‒phosphates. United States: N. p., 2016. Web. doi:10.1134/S1063774516040106.
Komornikov, V. A., E-mail: v.a.kom@mail.ru, Grebenev, V. V., Makarova, I. P., Selezneva, E. V., & Andreev, P. V. Production of complex rubidium and cesium hydrogen sulfate‒phosphates. United States. doi:10.1134/S1063774516040106.
Komornikov, V. A., E-mail: v.a.kom@mail.ru, Grebenev, V. V., Makarova, I. P., Selezneva, E. V., and Andreev, P. V. Fri . "Production of complex rubidium and cesium hydrogen sulfate‒phosphates". United States. doi:10.1134/S1063774516040106.
@article{osti_22645431,
title = {Production of complex rubidium and cesium hydrogen sulfate‒phosphates},
author = {Komornikov, V. A., E-mail: v.a.kom@mail.ru and Grebenev, V. V. and Makarova, I. P. and Selezneva, E. V. and Andreev, P. V.},
abstractNote = {The solubility in the CsH{sub 2}PO{sub 4}‒CsHSO{sub 4}‒H{sub 2}O system at different temperatures (25, 50, and 75°C) is studied and the phase equilibria in the Rb{sub 3}H(SO{sub 4}){sub 2}‒RbH{sub 2}PO{sub 4}‒H{sub 2}O system under isothermal conditions (at 25°C) are analyzed. The temperature and concentration conditions for forming Rb{sub 2}(HSO{sub 4})(H{sub 2}PO{sub 4}), Rb{sub 4}(HSO{sub 4}){sub 3}(H{sub 2}PO{sub 4}), Cs{sub 4}(HSO{sub 4}){sub 3}(H{sub 2}PO{sub 4}), Cs{sub 3}(HSO{sub 4}){sub 2}(H{sub 2}PO{sub 4}), Cs{sub 2}(HSO{sub 4})(H{sub 2}PO{sub 4}), and Cs{sub 6}H(HSO{sub 4}){sub 3}(H{sub 2}PO{sub 4}){sub 4} compounds (the latter has been obtained for the first time) are determined. The conditions for growing large single crystals of complex acid rubidium and cesium salts are found.},
doi = {10.1134/S1063774516040106},
journal = {Crystallography Reports},
number = 4,
volume = 61,
place = {United States},
year = {Fri Jul 15 00:00:00 EDT 2016},
month = {Fri Jul 15 00:00:00 EDT 2016}
}