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Title: Two new coordination polymers based on tartaric acid ligand: Syntheses, crystal structure and thermal stability

Abstract

Two new coordination polymers [Cd{sub 3}(D-Tar){sub 3}]{sub n} (1) and [Pb(meso-Tar)]{sub n} (2) (H{sub 2}Tar = tartaric acid) have been synthesized by hydrothermal reaction and characterized by single crystal X-ray diffraction analysis and IR spectra. 1 crystallizes in the C222{sub 1} chiral space group and shows a 3D (4,4)-connected net with the (4.6.8{sup 4}){sub 4}(4.6{sup 2}.8{sup 2}.10)(4.6{sup 2}.8{sup 3})(4.6{sup 3}.8{sup 2})(4.6{sup 3}.8{sup 2}){sub 4}(4.8{sup 5}){sub 2} topology. 2 possesses a 3D (4,4)-connected net with the (4{sup 3}.6{sup 2}.8) topology. In addition, the thermogravimetric analyses (TGA) results for polymers are discussed.

Authors:
; ; ;  [1]
  1. Zhejiang Normal University, Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces, Institute of Physical Chemistry (China)
Publication Date:
OSTI Identifier:
22645394
Resource Type:
Journal Article
Resource Relation:
Journal Name: Crystallography Reports; Journal Volume: 61; Journal Issue: 5; Other Information: Copyright (c) 2016 Pleiades Publishing, Inc.; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; CRYSTAL STRUCTURE; HYDROTHERMAL SYNTHESIS; INFRARED SPECTRA; LIGANDS; MONOCRYSTALS; POLYMERS; SPACE GROUPS; TAR; TARTARIC ACID; THERMAL GRAVIMETRIC ANALYSIS; X-RAY DIFFRACTION

Citation Formats

Chen, Fei-Yan, Lan, You-Zhao, E-mail: sky37@zjnu.cn, Han, Min-Min, and Feng, Yun-Long, E-mail: lyzhao@zjnu.cn. Two new coordination polymers based on tartaric acid ligand: Syntheses, crystal structure and thermal stability. United States: N. p., 2016. Web. doi:10.1134/S1063774516050072.
Chen, Fei-Yan, Lan, You-Zhao, E-mail: sky37@zjnu.cn, Han, Min-Min, & Feng, Yun-Long, E-mail: lyzhao@zjnu.cn. Two new coordination polymers based on tartaric acid ligand: Syntheses, crystal structure and thermal stability. United States. doi:10.1134/S1063774516050072.
Chen, Fei-Yan, Lan, You-Zhao, E-mail: sky37@zjnu.cn, Han, Min-Min, and Feng, Yun-Long, E-mail: lyzhao@zjnu.cn. Thu . "Two new coordination polymers based on tartaric acid ligand: Syntheses, crystal structure and thermal stability". United States. doi:10.1134/S1063774516050072.
@article{osti_22645394,
title = {Two new coordination polymers based on tartaric acid ligand: Syntheses, crystal structure and thermal stability},
author = {Chen, Fei-Yan and Lan, You-Zhao, E-mail: sky37@zjnu.cn and Han, Min-Min and Feng, Yun-Long, E-mail: lyzhao@zjnu.cn},
abstractNote = {Two new coordination polymers [Cd{sub 3}(D-Tar){sub 3}]{sub n} (1) and [Pb(meso-Tar)]{sub n} (2) (H{sub 2}Tar = tartaric acid) have been synthesized by hydrothermal reaction and characterized by single crystal X-ray diffraction analysis and IR spectra. 1 crystallizes in the C222{sub 1} chiral space group and shows a 3D (4,4)-connected net with the (4.6.8{sup 4}){sub 4}(4.6{sup 2}.8{sup 2}.10)(4.6{sup 2}.8{sup 3})(4.6{sup 3}.8{sup 2})(4.6{sup 3}.8{sup 2}){sub 4}(4.8{sup 5}){sub 2} topology. 2 possesses a 3D (4,4)-connected net with the (4{sup 3}.6{sup 2}.8) topology. In addition, the thermogravimetric analyses (TGA) results for polymers are discussed.},
doi = {10.1134/S1063774516050072},
journal = {Crystallography Reports},
number = 5,
volume = 61,
place = {United States},
year = {Thu Sep 15 00:00:00 EDT 2016},
month = {Thu Sep 15 00:00:00 EDT 2016}
}