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Title: Electrodynamical forbiddance of a strong quadrupole interaction in surface enhanced optical processes. Experimental confirmation of the existence in fullerene C{sub 60}

Abstract

It is demonstrated that in the SERS and SEIRA spectra of the fullerene C{sub 60}, the lines, which are forbidden in usual Raman and IR spectra and allowed in SERS and SEIRA, are absent. In addition the enhancement SERS coefficient in a single molecule detection regime is ~10{sup 8} instead of the value 10{sup 14}–10{sup 15}, characteristic for this phenomenon. These results are explained by the existence of so-called electrodynamical forbiddance of a strong quadrupole light-molecule interaction, which arises because of belonging of C{sup 60} to the icosahedral symmetry group and due to the electrodynamical law divE = 0.

Authors:
 [1];  [2]
  1. Russian Academy of Sciences, Ioffe Physical Technical Institute (Russian Federation)
  2. State University of Information Technologies, Mechanics and Optics (Russian Federation)
Publication Date:
OSTI Identifier:
22617070
Resource Type:
Journal Article
Resource Relation:
Journal Name: Journal of Experimental and Theoretical Physics; Journal Volume: 124; Journal Issue: 2; Other Information: Copyright (c) 2017 Pleiades Publishing, Inc.; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; DETECTION; FORBIDDEN TRANSITIONS; FULLERENES; INFRARED SPECTRA; INTERACTIONS; MOLECULES; QUADRUPOLES; RAMAN SPECTRA; SURFACES; SYMMETRY GROUPS; VISIBLE RADIATION

Citation Formats

Polubotko, A. M., E-mail: alex.marina@mail.ioffe.ru, and Chelibanov, V. P., E-mail: Chelibanov@gmail.com. Electrodynamical forbiddance of a strong quadrupole interaction in surface enhanced optical processes. Experimental confirmation of the existence in fullerene C{sub 60}. United States: N. p., 2017. Web. doi:10.1134/S1063776117010058.
Polubotko, A. M., E-mail: alex.marina@mail.ioffe.ru, & Chelibanov, V. P., E-mail: Chelibanov@gmail.com. Electrodynamical forbiddance of a strong quadrupole interaction in surface enhanced optical processes. Experimental confirmation of the existence in fullerene C{sub 60}. United States. doi:10.1134/S1063776117010058.
Polubotko, A. M., E-mail: alex.marina@mail.ioffe.ru, and Chelibanov, V. P., E-mail: Chelibanov@gmail.com. Wed . "Electrodynamical forbiddance of a strong quadrupole interaction in surface enhanced optical processes. Experimental confirmation of the existence in fullerene C{sub 60}". United States. doi:10.1134/S1063776117010058.
@article{osti_22617070,
title = {Electrodynamical forbiddance of a strong quadrupole interaction in surface enhanced optical processes. Experimental confirmation of the existence in fullerene C{sub 60}},
author = {Polubotko, A. M., E-mail: alex.marina@mail.ioffe.ru and Chelibanov, V. P., E-mail: Chelibanov@gmail.com},
abstractNote = {It is demonstrated that in the SERS and SEIRA spectra of the fullerene C{sub 60}, the lines, which are forbidden in usual Raman and IR spectra and allowed in SERS and SEIRA, are absent. In addition the enhancement SERS coefficient in a single molecule detection regime is ~10{sup 8} instead of the value 10{sup 14}–10{sup 15}, characteristic for this phenomenon. These results are explained by the existence of so-called electrodynamical forbiddance of a strong quadrupole light-molecule interaction, which arises because of belonging of C{sup 60} to the icosahedral symmetry group and due to the electrodynamical law divE = 0.},
doi = {10.1134/S1063776117010058},
journal = {Journal of Experimental and Theoretical Physics},
number = 2,
volume = 124,
place = {United States},
year = {Wed Feb 15 00:00:00 EST 2017},
month = {Wed Feb 15 00:00:00 EST 2017}
}