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Title: Characterization and optical properties of Fe{sub 2}O{sub 3}-PbO-B{sub 2}O{sub 3} glasses

Journal Article · · AIP Conference Proceedings
DOI:https://doi.org/10.1063/1.4946600· OSTI ID:22606589
 [1];  [2]; ; ; ;  [3];  [4]
  1. Rawal Institute of Engineering and Technology, Faridabad (Haryana)-121004 (India)
  2. Central University of Haryana, Mahendergarh-123029 (India)
  3. Guru Jambheshwar University of Science and Technology, Hisar (Haryana) - 125001 (India)
  4. Maharishi Dayanand University, Rohtak (Haryana)-124001 (India)

Heavy metal-based oxide glasses of compositions xFe{sub 2}O{sub 3}.(40-x)PbO.60B{sub 2}O{sub 3} have been synthesized by the standard melt-quenching technique. The amorphous nature of these samples is ascertained by XRD patterns. Scanning Electron Microscope is used to study the microstructure of the samples. The absorption edge (λ{sub cut-off}) shifts toward longer wavelengths with an increase in Fe{sub 2}O{sub 3} content in the glass matrix. Study of absorption edge signifies the glassy nature of the samples. The values of optical band gap energy for indirect allowed and forbidden transitions have been determined and it is found that it decreases with increasing Fe{sub 2}O{sub 3} content. The Urbach’s energy is used to characterize the degree of disorder in the studied samples.

OSTI ID:
22606589
Journal Information:
AIP Conference Proceedings, Vol. 1728, Issue 1; Conference: ICC 2015: International conference on condensed matter and applied physics, Bikaner (India), 30-31 Oct 2015; Other Information: (c) 2016 Author(s); Country of input: International Atomic Energy Agency (IAEA); ISSN 0094-243X
Country of Publication:
United States
Language:
English