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Title: High charge-discharge performance of Pb{sub 0.98}La{sub 0.02}(Zr{sub 0.35}Sn{sub 0.55}Ti{sub 0.10}){sub 0.995}O{sub 3} antiferroelectric ceramics

Abstract

The energy storage performance and charge-discharge properties of Pb{sub 0.98}La{sub 0.02}(Zr{sub 0.35}Sn{sub 0.55}Ti{sub 0.10}){sub 0.995}O{sub 3} (PLZST) antiferroelectric ceramics were investigated through directly measuring the hysteresis loops and pulse discharge current-time curves. The energy density only varies 0.2% per degree from 25 °C to 85 °C, and the energy efficiency maintains at about 90%. Furthermore, an approximate calculating model of maximum power density p{sub max} was established for the discharge process. Under a relatively high working electric field (8.2 kV/mm), this ceramics possess a greatly enhanced power density of 18 MW/cm{sup 3}. Moreover, the pulse power properties did not show degradation until 1500 times of charge-discharge cycling. The large released energy density, high energy efficiency, good temperature stability, greatly enhanced power density, and excellent fatigue endurance combined together make this PLZST ceramics an ideal candidate for pulse power applications.

Authors:
 [1];  [2]; ; ; ; ; ;  [1]
  1. Key Laboratory of Inorganic Functional Materials and Devices, Shanghai Institute of Ceramics, Chinese Academy of Sciences, 1295 Dingxi Road, Shanghai 200050 (China)
  2. (China)
Publication Date:
OSTI Identifier:
22598861
Resource Type:
Journal Article
Resource Relation:
Journal Name: Journal of Applied Physics; Journal Volume: 120; Journal Issue: 7; Other Information: (c) 2016 Author(s); Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS; 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; ANTIFERROELECTRIC MATERIALS; CERAMICS; DIAGRAMS; ELECTRIC FIELDS; ENERGY DENSITY; ENERGY EFFICIENCY; ENERGY STORAGE; FATIGUE; HYSTERESIS; LANTHANUM OXIDES; LEAD OXIDES; PERFORMANCE; POWER DENSITY; PULSES; TIN OXIDES; TITANIUM OXIDES; ZIRCONIUM OXIDES

Citation Formats

Xu, Chenhong, University of the Chinese Academy of Sciences, Beijing 100049, Liu, Zhen, Chen, Xuefeng, Yan, Shiguang, Cao, Fei, Dong, Xianlin, and Wang, Genshui, E-mail: genshuiwang@mail.sic.ac.cn. High charge-discharge performance of Pb{sub 0.98}La{sub 0.02}(Zr{sub 0.35}Sn{sub 0.55}Ti{sub 0.10}){sub 0.995}O{sub 3} antiferroelectric ceramics. United States: N. p., 2016. Web. doi:10.1063/1.4961329.
Xu, Chenhong, University of the Chinese Academy of Sciences, Beijing 100049, Liu, Zhen, Chen, Xuefeng, Yan, Shiguang, Cao, Fei, Dong, Xianlin, & Wang, Genshui, E-mail: genshuiwang@mail.sic.ac.cn. High charge-discharge performance of Pb{sub 0.98}La{sub 0.02}(Zr{sub 0.35}Sn{sub 0.55}Ti{sub 0.10}){sub 0.995}O{sub 3} antiferroelectric ceramics. United States. doi:10.1063/1.4961329.
Xu, Chenhong, University of the Chinese Academy of Sciences, Beijing 100049, Liu, Zhen, Chen, Xuefeng, Yan, Shiguang, Cao, Fei, Dong, Xianlin, and Wang, Genshui, E-mail: genshuiwang@mail.sic.ac.cn. Sun . "High charge-discharge performance of Pb{sub 0.98}La{sub 0.02}(Zr{sub 0.35}Sn{sub 0.55}Ti{sub 0.10}){sub 0.995}O{sub 3} antiferroelectric ceramics". United States. doi:10.1063/1.4961329.
@article{osti_22598861,
title = {High charge-discharge performance of Pb{sub 0.98}La{sub 0.02}(Zr{sub 0.35}Sn{sub 0.55}Ti{sub 0.10}){sub 0.995}O{sub 3} antiferroelectric ceramics},
author = {Xu, Chenhong and University of the Chinese Academy of Sciences, Beijing 100049 and Liu, Zhen and Chen, Xuefeng and Yan, Shiguang and Cao, Fei and Dong, Xianlin and Wang, Genshui, E-mail: genshuiwang@mail.sic.ac.cn},
abstractNote = {The energy storage performance and charge-discharge properties of Pb{sub 0.98}La{sub 0.02}(Zr{sub 0.35}Sn{sub 0.55}Ti{sub 0.10}){sub 0.995}O{sub 3} (PLZST) antiferroelectric ceramics were investigated through directly measuring the hysteresis loops and pulse discharge current-time curves. The energy density only varies 0.2% per degree from 25 °C to 85 °C, and the energy efficiency maintains at about 90%. Furthermore, an approximate calculating model of maximum power density p{sub max} was established for the discharge process. Under a relatively high working electric field (8.2 kV/mm), this ceramics possess a greatly enhanced power density of 18 MW/cm{sup 3}. Moreover, the pulse power properties did not show degradation until 1500 times of charge-discharge cycling. The large released energy density, high energy efficiency, good temperature stability, greatly enhanced power density, and excellent fatigue endurance combined together make this PLZST ceramics an ideal candidate for pulse power applications.},
doi = {10.1063/1.4961329},
journal = {Journal of Applied Physics},
number = 7,
volume = 120,
place = {United States},
year = {Sun Aug 21 00:00:00 EDT 2016},
month = {Sun Aug 21 00:00:00 EDT 2016}
}