Radial direct bandgap p-i-n GaNP microwire solar cells with enhanced short circuit current
- Graduate Program of Materials Science and Engineering, University of California, San Diego, La Jolla, California 92037 (United States)
- Department of Electrical and Computer Engineering, University of California, San Diego, La Jolla, California 92037 (United States)
- Department of Nanoengineering, University of California, San Diego, La Jolla, California 92037 (United States)
- Center for Integrated Nanotechnologies, Sandia National Laboratories, Albuquerque, New Mexico 87185 (United States)
We report the demonstration of dilute nitride heterostructure core/shell microwire solar cells utilizing the combination of top-down reactive-ion etching to create the cores (GaP) and molecular beam epitaxy to create the shells (GaNP). Systematic studies of cell performance over a series of microwire lengths, array periods, and microwire sidewall morphologies examined by transmission electron microscopy were conducted to shed light on performance-limiting factors and to optimize the cell efficiency. We show by microscopy and correlated external quantum efficiency characterization that the open circuit voltage is degraded primarily due to the presence of defects at the GaP/GaNP interface and in the GaNP shells, and is not limited by surface recombination. Compared to thin film solar cells in the same growth run, the microwire solar cells exhibit greater short circuit current but poorer open circuit voltage due to greater light absorption and number of defects in the microwire structure, respectively. The comprehensive understanding presented in this work suggests that performance benefits of dilute nitride microwire solar cells can be achieved by further tuning of the epitaxial quality of the underlying materials.
- OSTI ID:
- 22597743
- Journal Information:
- Journal of Applied Physics, Vol. 120, Issue 5; Other Information: (c) 2016 Author(s); Country of input: International Atomic Energy Agency (IAEA); ISSN 0021-8979
- Country of Publication:
- United States
- Language:
- English
Similar Records
Enhanced conversion efficiency in wide-bandgap GaNP solar cells
Surface Passivation and Carrier Collection in {110}, {100} and Circular Si Microwire Solar Cells
Related Subjects
GENERAL PHYSICS
COMPARATIVE EVALUATIONS
ELECTRIC POTENTIAL
ELECTRICAL FAULTS
ELECTRONS
ETCHING
GALLIUM PHOSPHIDES
IONS
MOLECULAR BEAM EPITAXY
MOLECULAR BEAMS
MORPHOLOGY
PERFORMANCE
P-N JUNCTIONS
QUANTUM EFFICIENCY
SHELLS
SOLAR CELLS
SURFACES
THIN FILMS
TRANSMISSION ELECTRON MICROSCOPY