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Title: A pair of novel Cd(II) enantiomers based on lactate derivatives: Synthesis, crystal structures and properties

Abstract

A pair of novel 3D homochiral metal−organic frameworks (HMOFs), namely [Cd{sub 2.5}((R)-CIA){sub 6}(1,4-DIB)(H{sub 2}O){sub 2}]·((CH{sub 3}){sub 2}NH{sub 2})·H{sub 2}O (1-D), [Cd{sub 2.5}((S)-CIA){sub 6}(1,4-DIB)(H{sub 2}O){sub 2}]·((CH{sub 3}){sub 2}NH{sub 2})·H{sub 2}O (1-L), have been synthesized using lactic acid derivative ligands ((R)-H{sub 3}CIA and (S)-H{sub 3}CIA) and 1,4-DIB. Crystallographic analyses indicate that the complexes 1-D and 1-L are packed by cage substructures. Some physical characteristics, such as solid-state circular dichroism (CD), thermal stabilities and photoluminescent properties are also investigated. Our results highlight the effective method to apply lactic acid derivative ligands to form interesting HMOFs. - Graphical abstract: Using lactic acid derivative ligands ((R)-H{sub 3}CIA and (S)-H{sub 3}CIA) and 1,4-DIB to assemble with Cd{sup 2+} ions, a pair of novel 3D homochiral metal-organic frameworks (HMOFs) with cage substructures have been synthesized. Display Omitted - Highlights: • Lactic acid derivative ligands • Cage substructure • Enantiomers.

Authors:
 [1];  [2];  [1];  [3]
  1. Department of Chemistry, Zunyi Normal College, Zunyi, Guizhou 563002 (China)
  2. (China)
  3. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, the Chinese Academy of Sciences, Fuzhou, Fujian 350002 (China)
Publication Date:
OSTI Identifier:
22584199
Resource Type:
Journal Article
Journal Name:
Journal of Solid State Chemistry
Additional Journal Information:
Journal Volume: 241; Other Information: Copyright (c) 2016 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA); Journal ID: ISSN 0022-4596
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; CADMIUM IONS; CRYSTAL STRUCTURE; CRYSTALLOGRAPHY; CRYSTALS; DICHROISM; LACTATES; LACTIC ACID; LIGANDS; METALS; ORGANOMETALLIC COMPOUNDS; PHOTOLUMINESCENCE; SOLIDS; STABILITY; SYNTHESIS; WATER

Citation Formats

Xu, Zhong-Xuan, E-mail: xuzhongxuan1974@163.com, State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, the Chinese Academy of Sciences, Fuzhou, Fujian 350002, Ao, Ke-Hou, and Zhang, Jian. A pair of novel Cd(II) enantiomers based on lactate derivatives: Synthesis, crystal structures and properties. United States: N. p., 2016. Web. doi:10.1016/J.JSSC.2016.06.001.
Xu, Zhong-Xuan, E-mail: xuzhongxuan1974@163.com, State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, the Chinese Academy of Sciences, Fuzhou, Fujian 350002, Ao, Ke-Hou, & Zhang, Jian. A pair of novel Cd(II) enantiomers based on lactate derivatives: Synthesis, crystal structures and properties. United States. doi:10.1016/J.JSSC.2016.06.001.
Xu, Zhong-Xuan, E-mail: xuzhongxuan1974@163.com, State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, the Chinese Academy of Sciences, Fuzhou, Fujian 350002, Ao, Ke-Hou, and Zhang, Jian. Thu . "A pair of novel Cd(II) enantiomers based on lactate derivatives: Synthesis, crystal structures and properties". United States. doi:10.1016/J.JSSC.2016.06.001.
@article{osti_22584199,
title = {A pair of novel Cd(II) enantiomers based on lactate derivatives: Synthesis, crystal structures and properties},
author = {Xu, Zhong-Xuan, E-mail: xuzhongxuan1974@163.com and State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, the Chinese Academy of Sciences, Fuzhou, Fujian 350002 and Ao, Ke-Hou and Zhang, Jian},
abstractNote = {A pair of novel 3D homochiral metal−organic frameworks (HMOFs), namely [Cd{sub 2.5}((R)-CIA){sub 6}(1,4-DIB)(H{sub 2}O){sub 2}]·((CH{sub 3}){sub 2}NH{sub 2})·H{sub 2}O (1-D), [Cd{sub 2.5}((S)-CIA){sub 6}(1,4-DIB)(H{sub 2}O){sub 2}]·((CH{sub 3}){sub 2}NH{sub 2})·H{sub 2}O (1-L), have been synthesized using lactic acid derivative ligands ((R)-H{sub 3}CIA and (S)-H{sub 3}CIA) and 1,4-DIB. Crystallographic analyses indicate that the complexes 1-D and 1-L are packed by cage substructures. Some physical characteristics, such as solid-state circular dichroism (CD), thermal stabilities and photoluminescent properties are also investigated. Our results highlight the effective method to apply lactic acid derivative ligands to form interesting HMOFs. - Graphical abstract: Using lactic acid derivative ligands ((R)-H{sub 3}CIA and (S)-H{sub 3}CIA) and 1,4-DIB to assemble with Cd{sup 2+} ions, a pair of novel 3D homochiral metal-organic frameworks (HMOFs) with cage substructures have been synthesized. Display Omitted - Highlights: • Lactic acid derivative ligands • Cage substructure • Enantiomers.},
doi = {10.1016/J.JSSC.2016.06.001},
journal = {Journal of Solid State Chemistry},
issn = {0022-4596},
number = ,
volume = 241,
place = {United States},
year = {2016},
month = {9}
}