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Title: Syntheses, structures and photoluminescent properties of Zn(Ⅱ)/Co(Ⅱ) coordination polymers based on flexible tetracarboxylate ligand of 5,5′-(butane-1,4-diyl)-bis(oxy)-di isophthalic acid

Abstract

Three new mixed-ligand metal-organic frameworks based on 5,5′-(butane-1,4- diyl)-bis(oxy)-diisophthalic acid and transitional metal cations with the help of two ancillary bridging N-donor pyridyl and imidazole linkers, [Zn(L){sub 0.5}(4,4′-bpy)]·2(H{sub 2}O) (1), [M(L){sub 0.5}(bib)]·4(H{sub 2}O) (M = Zn (2), Co (3)), (4,4′-bpy=4,4′–bipyridine, bib=1,4-bis (1H-imidazol-1-yl)-butane), have been synthesized under solvothermal conditions. Their structures and properties were determined by single-crystal and powder X-ray diffraction analyses, IR spectra, elemental analyses and thermogravimetric analyses (TGA). Compounds 1–3 display a 3D 3-fold interpenetrated frameworks linked by the L{sup 4−} ligands, ancillary N-donor linkers and the free water molecules in the crystal lattice. Topological analysis reveals that 1–3 are a (4,4)-connected bbf topology net with the (6{sup 4}·8{sup 2})(6{sup 6}) topology. The effects of the L{sup 4−} anions, the N-donor ligands, and the metal ions on the structures of the coordination polymers have been discussed. Furthermore, luminescence properties and thermogravimetric properties of these compounds were investigated. - Graphical abstract: Three new compounds of MOFs have been prepared and characterized. The luminescence properties and thermogravimetric properties of compounds were investigated. Display Omitted.

Authors:
 [1];  [2];  [2];  [3];  [2]; ; ; ;  [1];  [1]
  1. Inner Mongolia Key Lab Chem & Phys Rare Earth Mat, College of Chemistry and Chemical Engineering, Inner Mongolia University, Hohhot 010021 (China)
  2. (China)
  3. Department of Chemistry and Chemical Engineering, Ordos College of Inner Mongolia University, Ordos 017000 (China)
Publication Date:
OSTI Identifier:
22584182
Resource Type:
Journal Article
Resource Relation:
Journal Name: Journal of Solid State Chemistry; Journal Volume: 240; Other Information: Copyright (c) 2016 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; ANIONS; BIPYRIDINES; BUTANE; CATIONS; CRYSTAL LATTICES; FLUORESCENCE; IMIDAZOLES; INFRARED SPECTRA; LIGANDS; METALS; MOLECULES; MONOCRYSTALS; PHOTOLUMINESCENCE; POLYMERS; POWDERS; SYNTHESIS; THERMAL GRAVIMETRIC ANALYSIS; WATER; X RADIATION; X-RAY DIFFRACTION

Citation Formats

Gao, Yan-Peng, Department of Chemistry and Chemical Engineering, Ordos College of Inner Mongolia University, Ordos 017000, Department of Chemistry and Chemical Engineering, Ordos Applied Technology College, Ordos 017000, Guo, Le, Department of Chemistry and Chemical Engineering, Ordos Applied Technology College, Ordos 017000, Dong, Wei, Jia, Min, Zhang, Jing-Xue, Sun, Zhong, and Chang, Fei, E-mail: ndchfei@imu.edu.cn. Syntheses, structures and photoluminescent properties of Zn(Ⅱ)/Co(Ⅱ) coordination polymers based on flexible tetracarboxylate ligand of 5,5′-(butane-1,4-diyl)-bis(oxy)-di isophthalic acid. United States: N. p., 2016. Web. doi:10.1016/J.JSSC.2016.05.023.
Gao, Yan-Peng, Department of Chemistry and Chemical Engineering, Ordos College of Inner Mongolia University, Ordos 017000, Department of Chemistry and Chemical Engineering, Ordos Applied Technology College, Ordos 017000, Guo, Le, Department of Chemistry and Chemical Engineering, Ordos Applied Technology College, Ordos 017000, Dong, Wei, Jia, Min, Zhang, Jing-Xue, Sun, Zhong, & Chang, Fei, E-mail: ndchfei@imu.edu.cn. Syntheses, structures and photoluminescent properties of Zn(Ⅱ)/Co(Ⅱ) coordination polymers based on flexible tetracarboxylate ligand of 5,5′-(butane-1,4-diyl)-bis(oxy)-di isophthalic acid. United States. doi:10.1016/J.JSSC.2016.05.023.
Gao, Yan-Peng, Department of Chemistry and Chemical Engineering, Ordos College of Inner Mongolia University, Ordos 017000, Department of Chemistry and Chemical Engineering, Ordos Applied Technology College, Ordos 017000, Guo, Le, Department of Chemistry and Chemical Engineering, Ordos Applied Technology College, Ordos 017000, Dong, Wei, Jia, Min, Zhang, Jing-Xue, Sun, Zhong, and Chang, Fei, E-mail: ndchfei@imu.edu.cn. Mon . "Syntheses, structures and photoluminescent properties of Zn(Ⅱ)/Co(Ⅱ) coordination polymers based on flexible tetracarboxylate ligand of 5,5′-(butane-1,4-diyl)-bis(oxy)-di isophthalic acid". United States. doi:10.1016/J.JSSC.2016.05.023.
@article{osti_22584182,
title = {Syntheses, structures and photoluminescent properties of Zn(Ⅱ)/Co(Ⅱ) coordination polymers based on flexible tetracarboxylate ligand of 5,5′-(butane-1,4-diyl)-bis(oxy)-di isophthalic acid},
author = {Gao, Yan-Peng and Department of Chemistry and Chemical Engineering, Ordos College of Inner Mongolia University, Ordos 017000 and Department of Chemistry and Chemical Engineering, Ordos Applied Technology College, Ordos 017000 and Guo, Le and Department of Chemistry and Chemical Engineering, Ordos Applied Technology College, Ordos 017000 and Dong, Wei and Jia, Min and Zhang, Jing-Xue and Sun, Zhong and Chang, Fei, E-mail: ndchfei@imu.edu.cn},
abstractNote = {Three new mixed-ligand metal-organic frameworks based on 5,5′-(butane-1,4- diyl)-bis(oxy)-diisophthalic acid and transitional metal cations with the help of two ancillary bridging N-donor pyridyl and imidazole linkers, [Zn(L){sub 0.5}(4,4′-bpy)]·2(H{sub 2}O) (1), [M(L){sub 0.5}(bib)]·4(H{sub 2}O) (M = Zn (2), Co (3)), (4,4′-bpy=4,4′–bipyridine, bib=1,4-bis (1H-imidazol-1-yl)-butane), have been synthesized under solvothermal conditions. Their structures and properties were determined by single-crystal and powder X-ray diffraction analyses, IR spectra, elemental analyses and thermogravimetric analyses (TGA). Compounds 1–3 display a 3D 3-fold interpenetrated frameworks linked by the L{sup 4−} ligands, ancillary N-donor linkers and the free water molecules in the crystal lattice. Topological analysis reveals that 1–3 are a (4,4)-connected bbf topology net with the (6{sup 4}·8{sup 2})(6{sup 6}) topology. The effects of the L{sup 4−} anions, the N-donor ligands, and the metal ions on the structures of the coordination polymers have been discussed. Furthermore, luminescence properties and thermogravimetric properties of these compounds were investigated. - Graphical abstract: Three new compounds of MOFs have been prepared and characterized. The luminescence properties and thermogravimetric properties of compounds were investigated. Display Omitted.},
doi = {10.1016/J.JSSC.2016.05.023},
journal = {Journal of Solid State Chemistry},
number = ,
volume = 240,
place = {United States},
year = {Mon Aug 15 00:00:00 EDT 2016},
month = {Mon Aug 15 00:00:00 EDT 2016}
}