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Title: Synthesis, structural and optical characterization of APbX{sub 3} (A=methylammonium, dimethylammonium, trimethylammonium; X=I, Br, Cl) hybrid organic-inorganic materials

Abstract

In this paper we report the synthesis, the crystal structure and the optical response of APbX{sub 3} (A=MA, DMA, and TMA; X=I, Br) hybrid organic-inorganic materials including some new phases. We observe that as the cation group increases in size, the optical absorption edge shifts to higher energies with energy steps which are systematic and independent on the anion. A linear correlation between the optical bad gap and the tolerance factor has been shown for the series of samples investigated. - Graphical abstract: The crystal structure and the optical response of the two series of hybrid organic-inorganic materials APbX{sub 3} (A=MA, DMA, and TMA; X=I, Br), which include some new phases, are reported. A dependence of crystal structure and band-gap with tolerance factor is shown. Display Omitted - Highlights: • DMAPbI{sub 3}, TMAPbI{sub 3} and TMAPbBr{sub 3} are reported as new hybrid organic-inorganic compounds. • Crystal structure and optical properties as a function of the number of methyl groups are provided. • Correlation between structure and optical properties are given as a function of tolerance factor.

Authors:
; ; ;  [1];  [2];  [3]; ;  [4];  [1]
  1. Department of Chemistry and INSTM, University of Pavia, Pavia 27100 (Italy)
  2. University of Pavia, Centro Grandi Strumenti, 27100 Pavia (Italy)
  3. University of Milano and INSTM, Via Golgi 19, 20133 Milano (Italy)
  4. University of Pavia and CNISM, Via Bassi 6, 27100 Pavia (Italy)
Publication Date:
OSTI Identifier:
22584178
Resource Type:
Journal Article
Resource Relation:
Journal Name: Journal of Solid State Chemistry; Journal Volume: 240; Other Information: Copyright (c) 2016 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; ABSORPTION; ANIONS; CATIONS; CRYSTAL STRUCTURE; CRYSTALS; HYBRIDIZATION; INORGANIC COMPOUNDS; OPTICAL PROPERTIES; PEROVSKITES; PHOTOVOLTAIC EFFECT; SYNTHESIS; TOLERANCE; X RADIATION; X-RAY DIFFRACTION

Citation Formats

Mancini, Alessandro, Quadrelli, Paolo, Amoroso, Giuseppe, Milanese, Chiara, Boiocchi, Massimo, Sironi, Angelo, Patrini, Maddalena, Guizzetti, Giorgio, and Malavasi, Lorenzo, E-mail: lorenzo.malavasi@unipv.it. Synthesis, structural and optical characterization of APbX{sub 3} (A=methylammonium, dimethylammonium, trimethylammonium; X=I, Br, Cl) hybrid organic-inorganic materials. United States: N. p., 2016. Web. doi:10.1016/J.JSSC.2016.05.015.
Mancini, Alessandro, Quadrelli, Paolo, Amoroso, Giuseppe, Milanese, Chiara, Boiocchi, Massimo, Sironi, Angelo, Patrini, Maddalena, Guizzetti, Giorgio, & Malavasi, Lorenzo, E-mail: lorenzo.malavasi@unipv.it. Synthesis, structural and optical characterization of APbX{sub 3} (A=methylammonium, dimethylammonium, trimethylammonium; X=I, Br, Cl) hybrid organic-inorganic materials. United States. doi:10.1016/J.JSSC.2016.05.015.
Mancini, Alessandro, Quadrelli, Paolo, Amoroso, Giuseppe, Milanese, Chiara, Boiocchi, Massimo, Sironi, Angelo, Patrini, Maddalena, Guizzetti, Giorgio, and Malavasi, Lorenzo, E-mail: lorenzo.malavasi@unipv.it. Mon . "Synthesis, structural and optical characterization of APbX{sub 3} (A=methylammonium, dimethylammonium, trimethylammonium; X=I, Br, Cl) hybrid organic-inorganic materials". United States. doi:10.1016/J.JSSC.2016.05.015.
@article{osti_22584178,
title = {Synthesis, structural and optical characterization of APbX{sub 3} (A=methylammonium, dimethylammonium, trimethylammonium; X=I, Br, Cl) hybrid organic-inorganic materials},
author = {Mancini, Alessandro and Quadrelli, Paolo and Amoroso, Giuseppe and Milanese, Chiara and Boiocchi, Massimo and Sironi, Angelo and Patrini, Maddalena and Guizzetti, Giorgio and Malavasi, Lorenzo, E-mail: lorenzo.malavasi@unipv.it},
abstractNote = {In this paper we report the synthesis, the crystal structure and the optical response of APbX{sub 3} (A=MA, DMA, and TMA; X=I, Br) hybrid organic-inorganic materials including some new phases. We observe that as the cation group increases in size, the optical absorption edge shifts to higher energies with energy steps which are systematic and independent on the anion. A linear correlation between the optical bad gap and the tolerance factor has been shown for the series of samples investigated. - Graphical abstract: The crystal structure and the optical response of the two series of hybrid organic-inorganic materials APbX{sub 3} (A=MA, DMA, and TMA; X=I, Br), which include some new phases, are reported. A dependence of crystal structure and band-gap with tolerance factor is shown. Display Omitted - Highlights: • DMAPbI{sub 3}, TMAPbI{sub 3} and TMAPbBr{sub 3} are reported as new hybrid organic-inorganic compounds. • Crystal structure and optical properties as a function of the number of methyl groups are provided. • Correlation between structure and optical properties are given as a function of tolerance factor.},
doi = {10.1016/J.JSSC.2016.05.015},
journal = {Journal of Solid State Chemistry},
number = ,
volume = 240,
place = {United States},
year = {Mon Aug 15 00:00:00 EDT 2016},
month = {Mon Aug 15 00:00:00 EDT 2016}
}