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Title: Morphological evolution of prussian yellow Fe[Fe(CN){sub 6}] colloidal nanospheres

Abstract

A simple hydrothermal system was developed for controllable morphologies of the Prussian yellow Fe[Fe(CN){sub 6}] nanostructures in the presence of organic additives. Hollow and solid nanospheres of the Prussian yellow materials were successfully synthesized with suitable experimental conditions. It is found that the amounts of organic additives CTAB could result in the formation of the spherical nanocrystals and the hydrolysis of phosphate in the solution could play a role in the final morphology of the products. A possible formation mechanism of the Prussian yellow nanostructures is proposed. - Graphical abstract: A hydrothermal process was developed for controllable fabrication of the Prussian yellow hollow and solid nanospheres with the employment of different phosphate. The hydrolysis of phosphate in the solution could play a role in the morphology of the Prussian yellow nanomaterials. The acid phosphate (NaH{sub 2}PO{sub 4}) could result in the formation of the solid nanoparticles. The alkalescent phosphate (Na{sub 2}HPO{sub 4}) could result in the formation of the hollow nanoparticles. Display Omitted.

Authors:
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Publication Date:
OSTI Identifier:
22584146
Resource Type:
Journal Article
Resource Relation:
Journal Name: Journal of Solid State Chemistry; Journal Volume: 239; Other Information: Copyright (c) 2016 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; 77 NANOSCIENCE AND NANOTECHNOLOGY; ADDITIVES; CYANIDES; HYDROLYSIS; HYDROTHERMAL SYSTEMS; NANOMATERIALS; NANOPARTICLES; NANOSTRUCTURES; PHOSPHATES; SOLIDS; SOLUTIONS

Citation Formats

Gu, Jianmin, E-mail: jmgu@ysu.edu.cn, Fu, Shaoyan, Jin, Cuihong, Liu, Xin, Gao, Yahui, Wu, Jingxiao, Bian, Zhenpan, Tian, Hua, Wang, Lin, and Gao, Faming. Morphological evolution of prussian yellow Fe[Fe(CN){sub 6}] colloidal nanospheres. United States: N. p., 2016. Web. doi:10.1016/J.JSSC.2016.03.047.
Gu, Jianmin, E-mail: jmgu@ysu.edu.cn, Fu, Shaoyan, Jin, Cuihong, Liu, Xin, Gao, Yahui, Wu, Jingxiao, Bian, Zhenpan, Tian, Hua, Wang, Lin, & Gao, Faming. Morphological evolution of prussian yellow Fe[Fe(CN){sub 6}] colloidal nanospheres. United States. doi:10.1016/J.JSSC.2016.03.047.
Gu, Jianmin, E-mail: jmgu@ysu.edu.cn, Fu, Shaoyan, Jin, Cuihong, Liu, Xin, Gao, Yahui, Wu, Jingxiao, Bian, Zhenpan, Tian, Hua, Wang, Lin, and Gao, Faming. 2016. "Morphological evolution of prussian yellow Fe[Fe(CN){sub 6}] colloidal nanospheres". United States. doi:10.1016/J.JSSC.2016.03.047.
@article{osti_22584146,
title = {Morphological evolution of prussian yellow Fe[Fe(CN){sub 6}] colloidal nanospheres},
author = {Gu, Jianmin, E-mail: jmgu@ysu.edu.cn and Fu, Shaoyan and Jin, Cuihong and Liu, Xin and Gao, Yahui and Wu, Jingxiao and Bian, Zhenpan and Tian, Hua and Wang, Lin and Gao, Faming},
abstractNote = {A simple hydrothermal system was developed for controllable morphologies of the Prussian yellow Fe[Fe(CN){sub 6}] nanostructures in the presence of organic additives. Hollow and solid nanospheres of the Prussian yellow materials were successfully synthesized with suitable experimental conditions. It is found that the amounts of organic additives CTAB could result in the formation of the spherical nanocrystals and the hydrolysis of phosphate in the solution could play a role in the final morphology of the products. A possible formation mechanism of the Prussian yellow nanostructures is proposed. - Graphical abstract: A hydrothermal process was developed for controllable fabrication of the Prussian yellow hollow and solid nanospheres with the employment of different phosphate. The hydrolysis of phosphate in the solution could play a role in the morphology of the Prussian yellow nanomaterials. The acid phosphate (NaH{sub 2}PO{sub 4}) could result in the formation of the solid nanoparticles. The alkalescent phosphate (Na{sub 2}HPO{sub 4}) could result in the formation of the hollow nanoparticles. Display Omitted.},
doi = {10.1016/J.JSSC.2016.03.047},
journal = {Journal of Solid State Chemistry},
number = ,
volume = 239,
place = {United States},
year = 2016,
month = 7
}