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Title: Synthesis of metal-adeninate frameworks with high separation capacity on C{sub 2}/C{sub 1} hydrocarbons

Abstract

By introducing isophthalic acid or 2,5-thiophenedicarboxylic acid to assemble with adenine and cadmium salt, two isostructural and anionic porous metal-organic frameworks (1 and 2) possessing the novel (4,8)-connected sqc topology are presented here. 1 shows permanent porosity with Langmuir surface area of 770.1 m{sup 2}/g and exhibits high separation capacity on C{sub 2}/C{sub 1} hydrocarbons. - Graphical abstract: The assembly between isophthalic acid, adenine ligands and Cd{sup 2+} ions leads to an anionic porous metal-organic frameworks, which shows permanent porosity and exhibits high C{sub 2}/C{sub 1} hydrocarbons separation capacity. Display Omitted.

Authors:
 [1];  [1];  [2]; ; ;  [1]
  1. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002 (China)
  2. (China)
Publication Date:
OSTI Identifier:
22584125
Resource Type:
Journal Article
Resource Relation:
Journal Name: Journal of Solid State Chemistry; Journal Volume: 238; Other Information: Copyright (c) 2016 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; ADENINES; CADMIUM; HYDROCARBONS; LIGANDS; ORGANOMETALLIC COMPOUNDS; POROSITY; POROUS MATERIALS; SORPTION; SURFACE AREA; SURFACES; SYNTHESIS

Citation Formats

He, Yan-Ping, E-mail: hyp041@163.com, Zhou, Nan, Hunan GuangYi Experimental Middle School, Changsha, Hunan 410014, Tan, Yan-Xi, Wang, Fei, and Zhang, Jian. Synthesis of metal-adeninate frameworks with high separation capacity on C{sub 2}/C{sub 1} hydrocarbons. United States: N. p., 2016. Web. doi:10.1016/J.JSSC.2016.03.043.
He, Yan-Ping, E-mail: hyp041@163.com, Zhou, Nan, Hunan GuangYi Experimental Middle School, Changsha, Hunan 410014, Tan, Yan-Xi, Wang, Fei, & Zhang, Jian. Synthesis of metal-adeninate frameworks with high separation capacity on C{sub 2}/C{sub 1} hydrocarbons. United States. doi:10.1016/J.JSSC.2016.03.043.
He, Yan-Ping, E-mail: hyp041@163.com, Zhou, Nan, Hunan GuangYi Experimental Middle School, Changsha, Hunan 410014, Tan, Yan-Xi, Wang, Fei, and Zhang, Jian. Wed . "Synthesis of metal-adeninate frameworks with high separation capacity on C{sub 2}/C{sub 1} hydrocarbons". United States. doi:10.1016/J.JSSC.2016.03.043.
@article{osti_22584125,
title = {Synthesis of metal-adeninate frameworks with high separation capacity on C{sub 2}/C{sub 1} hydrocarbons},
author = {He, Yan-Ping, E-mail: hyp041@163.com and Zhou, Nan and Hunan GuangYi Experimental Middle School, Changsha, Hunan 410014 and Tan, Yan-Xi and Wang, Fei and Zhang, Jian},
abstractNote = {By introducing isophthalic acid or 2,5-thiophenedicarboxylic acid to assemble with adenine and cadmium salt, two isostructural and anionic porous metal-organic frameworks (1 and 2) possessing the novel (4,8)-connected sqc topology are presented here. 1 shows permanent porosity with Langmuir surface area of 770.1 m{sup 2}/g and exhibits high separation capacity on C{sub 2}/C{sub 1} hydrocarbons. - Graphical abstract: The assembly between isophthalic acid, adenine ligands and Cd{sup 2+} ions leads to an anionic porous metal-organic frameworks, which shows permanent porosity and exhibits high C{sub 2}/C{sub 1} hydrocarbons separation capacity. Display Omitted.},
doi = {10.1016/J.JSSC.2016.03.043},
journal = {Journal of Solid State Chemistry},
number = ,
volume = 238,
place = {United States},
year = {Wed Jun 15 00:00:00 EDT 2016},
month = {Wed Jun 15 00:00:00 EDT 2016}
}