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Title: Facile synthesis of Ca{sub 0.68}Si{sub 9}Al{sub 3}(ON){sub 16}:Eu{sup 2+} microbelts mat with the enhanced fluorescence and mechanical performance

Abstract

Yellow-emitting phosphor mat consisting of Ca{sub 0.68}Si{sub 9}Al{sub 3}(ON){sub 16}:Eu{sup 2+} microbelts was prepared by electrospinning and subsequent nitridation. The as-prepared fiber precursor is smooth and uniform with diameter of 800 to 900 nm. After removing organic templates and nitridation, the morphology of the fiber is well retained and thus a smooth microbelts phosphor mat was obtained. X-ray diffraction and the photoluminescence (PL) spectra reveals that a relatively pure Ca{sub 0.68}Si{sub 9}Al{sub 3}(ON){sub 16} phase and the highest spectral intensity could be obtained at a relatively low temperature of 1500 °C and Eu{sup 2+} doping molar concentration of 0.1. The excitation spectra exhibits a broad band, ranging from 300 to 550 nm, which could be excited by blue LED chip at room temperature. The emission spectra of all exhibits a single broad band in the 400 to 700 nm region, with the maximum intensity always being at 580 nm. The Ca{sub 0.68}Si{sub 9}Al{sub 3}(ON){sub 16}:Eu{sup 2+} microbelts phosphor mat has the bending strength about 4.5 MPa with a photoluminescence quantum yield as high as 65%. By employing it as yellow phosphor, a high-performance warm white LED could be fabricated with low correlated color temperature (2985 K), high-color-rendering index (Ra=86) andmore » luminous efficacy of 129.5 lm W{sup −1}. Different color temperatures also could be tuned by employing microbelts phosphor mats with different thicknesses. - Graphical abstract: Yellow-emitting phosphor mat consisting of Ca{sub 0.68}Si{sub 9}Al{sub 3}(ON){sub 16}:Eu{sup 2+} microbelts fibers were prepared by electrospinning the fiber precursor and subsequent nitridation. Because the good mechanical strength it could be utilized to realize LEDs remote packaging. By employing it as yellow phosphor, a high-performance warm white LED could be fabricated. Different color temperatures also could be tuned by employing microbelts phosphor mats with different thicknesses. - Highlights: • Ca{sub 0.68}Si{sub 9}Al{sub 3}(ON){sub 16}:Eu{sup 2+} microbelts mats were synthesized by electrospinning method. • The optimum doping concentration of Eu{sup 2+} ion is 0.1 mole. • The microbelts mats show strong yellow emission at 580 nm. • The Ca{sub 0.68}Si{sub 9}Al{sub 3}(ON){sub 16}:Eu{sup 2+} mat had the bending strength about 4.5 Mp. • Different color temperatures could be turned with different thicknesses of the mats.« less

Authors:
;  [1];  [1];  [2];  [2]
  1. State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, Shanghai 201620 (China)
  2. Engineering Research Center of Advanced Glasses Manufacturing Technology, MOE, College of Materials Science and Engineering, Donghua University, Shanghai 201620 (China)
Publication Date:
OSTI Identifier:
22577753
Resource Type:
Journal Article
Journal Name:
Journal of Solid State Chemistry
Additional Journal Information:
Journal Volume: 233; Other Information: Copyright (c) 2015 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA); Journal ID: ISSN 0022-4596
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; CONCENTRATION RATIO; EMISSION SPECTRA; EUROPIUM IONS; EXCITATION; FIBERS; FLEXURAL STRENGTH; FLUORESCENCE; NITRIDATION; PERFORMANCE; PHOSPHORS; PHOTOLUMINESCENCE; SYNTHESIS; THICKNESS; X RADIATION; X-RAY DIFFRACTION

Citation Formats

Zhao, Hailei, Cui, Bo, Wang, Hongzhi, Zhang, Qinghong, and Li, Yaogang. Facile synthesis of Ca{sub 0.68}Si{sub 9}Al{sub 3}(ON){sub 16}:Eu{sup 2+} microbelts mat with the enhanced fluorescence and mechanical performance. United States: N. p., 2016. Web. doi:10.1016/J.JSSC.2015.10.044.
Zhao, Hailei, Cui, Bo, Wang, Hongzhi, Zhang, Qinghong, & Li, Yaogang. Facile synthesis of Ca{sub 0.68}Si{sub 9}Al{sub 3}(ON){sub 16}:Eu{sup 2+} microbelts mat with the enhanced fluorescence and mechanical performance. United States. doi:10.1016/J.JSSC.2015.10.044.
Zhao, Hailei, Cui, Bo, Wang, Hongzhi, Zhang, Qinghong, and Li, Yaogang. Fri . "Facile synthesis of Ca{sub 0.68}Si{sub 9}Al{sub 3}(ON){sub 16}:Eu{sup 2+} microbelts mat with the enhanced fluorescence and mechanical performance". United States. doi:10.1016/J.JSSC.2015.10.044.
@article{osti_22577753,
title = {Facile synthesis of Ca{sub 0.68}Si{sub 9}Al{sub 3}(ON){sub 16}:Eu{sup 2+} microbelts mat with the enhanced fluorescence and mechanical performance},
author = {Zhao, Hailei and Cui, Bo and Wang, Hongzhi and Zhang, Qinghong and Li, Yaogang},
abstractNote = {Yellow-emitting phosphor mat consisting of Ca{sub 0.68}Si{sub 9}Al{sub 3}(ON){sub 16}:Eu{sup 2+} microbelts was prepared by electrospinning and subsequent nitridation. The as-prepared fiber precursor is smooth and uniform with diameter of 800 to 900 nm. After removing organic templates and nitridation, the morphology of the fiber is well retained and thus a smooth microbelts phosphor mat was obtained. X-ray diffraction and the photoluminescence (PL) spectra reveals that a relatively pure Ca{sub 0.68}Si{sub 9}Al{sub 3}(ON){sub 16} phase and the highest spectral intensity could be obtained at a relatively low temperature of 1500 °C and Eu{sup 2+} doping molar concentration of 0.1. The excitation spectra exhibits a broad band, ranging from 300 to 550 nm, which could be excited by blue LED chip at room temperature. The emission spectra of all exhibits a single broad band in the 400 to 700 nm region, with the maximum intensity always being at 580 nm. The Ca{sub 0.68}Si{sub 9}Al{sub 3}(ON){sub 16}:Eu{sup 2+} microbelts phosphor mat has the bending strength about 4.5 MPa with a photoluminescence quantum yield as high as 65%. By employing it as yellow phosphor, a high-performance warm white LED could be fabricated with low correlated color temperature (2985 K), high-color-rendering index (Ra=86) and luminous efficacy of 129.5 lm W{sup −1}. Different color temperatures also could be tuned by employing microbelts phosphor mats with different thicknesses. - Graphical abstract: Yellow-emitting phosphor mat consisting of Ca{sub 0.68}Si{sub 9}Al{sub 3}(ON){sub 16}:Eu{sup 2+} microbelts fibers were prepared by electrospinning the fiber precursor and subsequent nitridation. Because the good mechanical strength it could be utilized to realize LEDs remote packaging. By employing it as yellow phosphor, a high-performance warm white LED could be fabricated. Different color temperatures also could be tuned by employing microbelts phosphor mats with different thicknesses. - Highlights: • Ca{sub 0.68}Si{sub 9}Al{sub 3}(ON){sub 16}:Eu{sup 2+} microbelts mats were synthesized by electrospinning method. • The optimum doping concentration of Eu{sup 2+} ion is 0.1 mole. • The microbelts mats show strong yellow emission at 580 nm. • The Ca{sub 0.68}Si{sub 9}Al{sub 3}(ON){sub 16}:Eu{sup 2+} mat had the bending strength about 4.5 Mp. • Different color temperatures could be turned with different thicknesses of the mats.},
doi = {10.1016/J.JSSC.2015.10.044},
journal = {Journal of Solid State Chemistry},
issn = {0022-4596},
number = ,
volume = 233,
place = {United States},
year = {2016},
month = {1}
}