Neutron powder diffraction refinement of the nuclear and magnetic structures of HoNi{sub 2}B{sub 2}C at R.T., 10, 5.1, and 2.2 K
- National Inst. of Standards and Technology, Gaithersburg, MD (United States). Reactor Radiation Div.
- AT and T Bell Labs., Murray Hill, NJ (United States)
The nuclear and magnetic structures of HoNi{sub 2}B{sub 2}C have been investigated by neutron powder diffraction at room temperature and at 10, 5.1 and 2.2K. The compound crystallizes with the symmetry of space group 14/mmm and has room temperature lattice parameters a = 3.5170(1) and c = 10.5217(3) {angstrom}. No phase transitions of the nuclear structure have been observed in the range of temperatures examined. Magnetic peaks begin to appear at about 8K. The magnetic structure is the superposition of two configurations, one in which ferromagnetic sheets of holmium spins parallel to the a-b plane are coupled antiferromagnetically along the c-axis, and another in which the ferromagnetic planes are rotated away from the antiparallel configuration to give an incommensurate helicoidal structure with a period approximately equal to twelve times the length of the c-axis. The helicoidal structure competes with superconductivity while the antiferromagnetism coexists with it.
- OSTI ID:
- 225303
- Report Number(s):
- CONF-941144-; ISBN 1-55899-278-2; TRN: IM9621%%233
- Resource Relation:
- Conference: Fall meeting of the Materials Research Society (MRS), Boston, MA (United States), 28 Nov - 9 Dec 1994; Other Information: PBD: 1995; Related Information: Is Part Of Neutron scattering in materials science 2; Neumann, D.A. [ed.] [National Inst. of Standards and Technology, Gaithersburg, MD (United States)]; Russell, T.P. [ed.] [IBM Almaden Research Center, San Jose, CA (United States)]; Wuensch, B.J. [ed.] [Massachusetts Inst. of Tech., Cambridge, MA (United States)]; PB: 813 p.; Materials Research Society symposium proceedings, Volume 376
- Country of Publication:
- United States
- Language:
- English
Similar Records
Magnetic order and crystal structure in the superconducting RNi{sub 2}B{sub 2}C materials
Incommensurate antiferromagnetism in the intermetallic superconductor HoNi{sub 2}B{sub 2}C