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Title: Double-shelled plasmonic Ag-TiO{sub 2} hollow spheres toward visible light-active photocatalytic conversion of CO{sub 2} into solar fuel

Abstract

Double-shelled hollow hybrid spheres consisting of plasmonic Ag and TiO{sub 2} nanoparticles were successfully synthesized through a simple reaction process. The analysis reveals that Ag nanoparticles were dispersed uniformly in the TiO{sub 2} nanoparticle shell. The plasmonic Ag-TiO{sub 2} hollow sphere proves to greatly enhance the photocatalytic activity toward reduction of CO{sub 2} into renewable hydrocarbon fuel (CH{sub 4}) in the presence of water vapor under visible-light irradiation. The possible formation mechanism of the hollow sphere and related plasmon-enhanced photocatalytic performance were also briefly discussed.

Authors:
; ; ;  [1];  [2];  [1];  [2];  [3];  [4];  [1];  [2];  [4]
  1. National Laboratory of Solid State Microstructures, Collaborative Innovation Center of Advanced Microstructures, School of Physics, Nanjing University, Nanjing 210093 (China)
  2. (ERERC), Nanjing University, Nanjing 210093 (China)
  3. (MOE), Institute of Acoustics, Department of Physics, Nanjing University, Nanjing 210093 (China)
  4. (China)
Publication Date:
OSTI Identifier:
22499211
Resource Type:
Journal Article
Journal Name:
APL Materials
Additional Journal Information:
Journal Volume: 3; Journal Issue: 10; Other Information: (c) 2015 Author(s); Country of input: International Atomic Energy Agency (IAEA); Journal ID: ISSN 2166-532X
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 77 NANOSCIENCE AND NANOTECHNOLOGY; CARBON DIOXIDE; HYBRIDIZATION; IRRADIATION; METHANE; NANOPARTICLES; PHOTOCATALYSIS; TITANIUM OXIDES

Citation Formats

Feng, Shichao, Wang, Meng, Li, Ping, Tu, Wenguang, Eco-Materials and Renewable Energy Research Center, Zhou, Yong, Eco-Materials and Renewable Energy Research Center, Key Laboratory of Modern Acoustics, Jiangsu Key Laboratory for Nano Technology, Nanjing University, Nanjing 210093, Zou, Zhigang, Eco-Materials and Renewable Energy Research Center, and Jiangsu Key Laboratory for Nano Technology, Nanjing University, Nanjing 210093. Double-shelled plasmonic Ag-TiO{sub 2} hollow spheres toward visible light-active photocatalytic conversion of CO{sub 2} into solar fuel. United States: N. p., 2015. Web. doi:10.1063/1.4930043.
Feng, Shichao, Wang, Meng, Li, Ping, Tu, Wenguang, Eco-Materials and Renewable Energy Research Center, Zhou, Yong, Eco-Materials and Renewable Energy Research Center, Key Laboratory of Modern Acoustics, Jiangsu Key Laboratory for Nano Technology, Nanjing University, Nanjing 210093, Zou, Zhigang, Eco-Materials and Renewable Energy Research Center, & Jiangsu Key Laboratory for Nano Technology, Nanjing University, Nanjing 210093. Double-shelled plasmonic Ag-TiO{sub 2} hollow spheres toward visible light-active photocatalytic conversion of CO{sub 2} into solar fuel. United States. doi:10.1063/1.4930043.
Feng, Shichao, Wang, Meng, Li, Ping, Tu, Wenguang, Eco-Materials and Renewable Energy Research Center, Zhou, Yong, Eco-Materials and Renewable Energy Research Center, Key Laboratory of Modern Acoustics, Jiangsu Key Laboratory for Nano Technology, Nanjing University, Nanjing 210093, Zou, Zhigang, Eco-Materials and Renewable Energy Research Center, and Jiangsu Key Laboratory for Nano Technology, Nanjing University, Nanjing 210093. Thu . "Double-shelled plasmonic Ag-TiO{sub 2} hollow spheres toward visible light-active photocatalytic conversion of CO{sub 2} into solar fuel". United States. doi:10.1063/1.4930043.
@article{osti_22499211,
title = {Double-shelled plasmonic Ag-TiO{sub 2} hollow spheres toward visible light-active photocatalytic conversion of CO{sub 2} into solar fuel},
author = {Feng, Shichao and Wang, Meng and Li, Ping and Tu, Wenguang and Eco-Materials and Renewable Energy Research Center and Zhou, Yong and Eco-Materials and Renewable Energy Research Center and Key Laboratory of Modern Acoustics and Jiangsu Key Laboratory for Nano Technology, Nanjing University, Nanjing 210093 and Zou, Zhigang and Eco-Materials and Renewable Energy Research Center and Jiangsu Key Laboratory for Nano Technology, Nanjing University, Nanjing 210093},
abstractNote = {Double-shelled hollow hybrid spheres consisting of plasmonic Ag and TiO{sub 2} nanoparticles were successfully synthesized through a simple reaction process. The analysis reveals that Ag nanoparticles were dispersed uniformly in the TiO{sub 2} nanoparticle shell. The plasmonic Ag-TiO{sub 2} hollow sphere proves to greatly enhance the photocatalytic activity toward reduction of CO{sub 2} into renewable hydrocarbon fuel (CH{sub 4}) in the presence of water vapor under visible-light irradiation. The possible formation mechanism of the hollow sphere and related plasmon-enhanced photocatalytic performance were also briefly discussed.},
doi = {10.1063/1.4930043},
journal = {APL Materials},
issn = {2166-532X},
number = 10,
volume = 3,
place = {United States},
year = {2015},
month = {10}
}