Quantum control of isomerization by robust navigation in the energy spectrum

doi:10.1063/1.4936424

Title: Quantum control of isomerization by robust navigation in the energy spectrum

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Abstract

In this paper, we present a detailed study on the application of the quantum control technique of navigation in the energy spectrum to chemical isomerization processes, namely, CN–Li⇆ Li–CN. This technique is based on the controlled time variation of a Hamiltonian parameter, an external uniform electric field in our case. The main result of our work establishes that the navigation involved in the method is robust, in the sense that quite sizable deviations from a pre-established control parameter time profile can be introduced and still get good final results. This is specially relevant thinking of a experimental implementation of the method.

Authors:

Murgida, G. E., E-mail: murgida@tandar.cnea.gov.ar ^[1]; Arranz, F. J., E-mail: fj.arranz@upm.es ^[2]; Borondo, F., E-mail: f.borondo@uam.es ^[3]; Instituto de Ciencias Matemáticas ^[4]

Centro Atómico Constituyentes, GIyA, CNEA, San Martín, and Consejo Nacional de Investigaciones Científicas y Técnicas, C1033AAJ Buenos Aires (Argentina)
Grupo de Sistemas Complejos, Universidad Politécnica de Madrid, 28040 Madrid (Spain)
Departamento de Química, Universidad Autónoma de Madrid, Cantoblanco, 28049 Madrid (Spain)
(ICMAT), Cantoblanco, 28049 Madrid (Spain)

Publication Date:: Mon Dec 07 00:00:00 EST 2015

OSTI Identifier:: 22493294

Resource Type:: Journal Article

Journal Name:: Journal of Chemical Physics

Additional Journal Information:: Journal Volume: 143; Journal Issue: 21; Other Information: (c) 2015 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA); Journal ID: ISSN 0021-9606

Country of Publication:: United States

Language:: English

Subject:: 71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS; 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; CARBON NITRIDES; CYANIDES; ELECTRIC FIELDS; ENERGY SPECTRA; HAMILTONIANS; ISOMERIZATION; LITHIUM; LITHIUM COMPOUNDS; VARIATIONS

Citation Formats


                    Murgida, G. E., E-mail: murgida@tandar.cnea.gov.ar, Arranz, F. J., E-mail: fj.arranz@upm.es, Borondo, F., E-mail: f.borondo@uam.es, and Instituto de Ciencias Matemáticas. Quantum control of isomerization by robust navigation in the energy spectrum.  United States: N. p., 2015. 
        Web.  doi:10.1063/1.4936424.

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                    Murgida, G. E., E-mail: murgida@tandar.cnea.gov.ar, Arranz, F. J., E-mail: fj.arranz@upm.es, Borondo, F., E-mail: f.borondo@uam.es, & Instituto de Ciencias Matemáticas. Quantum control of isomerization by robust navigation in the energy spectrum.  United States.  https://doi.org/10.1063/1.4936424

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                    Murgida, G. E., E-mail: murgida@tandar.cnea.gov.ar, Arranz, F. J., E-mail: fj.arranz@upm.es, Borondo, F., E-mail: f.borondo@uam.es, and Instituto de Ciencias Matemáticas. 2015.  
        "Quantum control of isomerization by robust navigation in the energy spectrum".  United States.  https://doi.org/10.1063/1.4936424.

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@article{osti_22493294,

  title        = {Quantum control of isomerization by robust navigation in the energy spectrum},

  author       = {Murgida, G. E., E-mail: murgida@tandar.cnea.gov.ar and Arranz, F. J., E-mail: fj.arranz@upm.es and Borondo, F., E-mail: f.borondo@uam.es and Instituto de Ciencias Matemáticas},

  abstractNote = {In this paper, we present a detailed study on the application of the quantum control technique of navigation in the energy spectrum to chemical isomerization processes, namely, CN–Li⇆ Li–CN. This technique is based on the controlled time variation of a Hamiltonian parameter, an external uniform electric field in our case. The main result of our work establishes that the navigation involved in the method is robust, in the sense that quite sizable deviations from a pre-established control parameter time profile can be introduced and still get good final results. This is specially relevant thinking of a experimental implementation of the method.},

  doi          = {10.1063/1.4936424},

  url          = {https://www.osti.gov/biblio/22493294},
  journal      = {Journal of Chemical Physics},

  issn         = {0021-9606},

  number       = 21,

  volume       = 143,

  place        = {United States},

  year         = {Mon Dec 07 00:00:00 EST 2015},

  month        = {Mon Dec 07 00:00:00 EST 2015}

}

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