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Title: Electrochemical characterization of aminated acrylic conducting polymer

Abstract

New attempt has been made to synthesize aminated acrylic conducting polymer (AACP) using precursor of phenylvinylsulfoxide (PVS). The process was conducted via the integration of microemulsion and photopolymerization techniques. It has been utilized for covalent immobilization of amino groups by the adding of N-achryiloxisuccinimide (NAS). Thermal eliminating of benzene sulfenic acids from PVS has been done at 250 °C to form electroactive polyacetylene (PA) segment. Characterization of AACP has been conducted using fourier transform infrared (FTIR), scanning electron microscopy (SEM) and linear sweep cyclic voltammetry (CV). A range of 0.3-1.25μm particle size obtained from SEM characterization. A quasi-reversible system performed as shown in electrochemical study.

Authors:
 [1];  [1];  [2];  [3]
  1. School of Chemical Sciences and Food Technology, Faculty of Science and Technology, Lestari Universiti Kebangsaan Malaysia (UKM), 43600 Bangi, Selangor Darul Ehsan (Malaysia)
  2. (UKM), 43600 Bangi, Selangor Darul Ehsan (Malaysia)
  3. Southeast Asia Disaster Prevention Research Initiative, Lestari Universiti Kebangsaan Malaysia (UKM), 43600 Bangi, Selangor Darul Ehsan (Malaysia)
Publication Date:
OSTI Identifier:
22488992
Resource Type:
Journal Article
Resource Relation:
Journal Name: AIP Conference Proceedings; Journal Volume: 1678; Journal Issue: 1; Conference: Universiti Kebangsaan Malaysia, Faculty of Science and Technology 2015 Postgraduate Colloquium, Selangor (Malaysia), 15-16 Apr 2015; Other Information: (c) 2015 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; ACRYLATES; BENZENE; COVALENCE; ELECTRIC CONDUCTIVITY; ELECTROCHEMISTRY; FOURIER TRANSFORMATION; INFRARED SPECTRA; MICROEMULSIONS; ORGANIC POLYMERS; PARTICLE SIZE; POLYMERIZATION; PRECURSOR; SCANNING ELECTRON MICROSCOPY; SULFOXIDES; VOLTAMETRY

Citation Formats

Rashid, Norma Mohammad, Heng, Lee Yook, Southeast Asia Disaster Prevention Research Initiative, Lestari Universiti Kebangsaan Malaysia, and Ling, Tan Ling. Electrochemical characterization of aminated acrylic conducting polymer. United States: N. p., 2015. Web. doi:10.1063/1.4931292.
Rashid, Norma Mohammad, Heng, Lee Yook, Southeast Asia Disaster Prevention Research Initiative, Lestari Universiti Kebangsaan Malaysia, & Ling, Tan Ling. Electrochemical characterization of aminated acrylic conducting polymer. United States. doi:10.1063/1.4931292.
Rashid, Norma Mohammad, Heng, Lee Yook, Southeast Asia Disaster Prevention Research Initiative, Lestari Universiti Kebangsaan Malaysia, and Ling, Tan Ling. 2015. "Electrochemical characterization of aminated acrylic conducting polymer". United States. doi:10.1063/1.4931292.
@article{osti_22488992,
title = {Electrochemical characterization of aminated acrylic conducting polymer},
author = {Rashid, Norma Mohammad and Heng, Lee Yook and Southeast Asia Disaster Prevention Research Initiative, Lestari Universiti Kebangsaan Malaysia and Ling, Tan Ling},
abstractNote = {New attempt has been made to synthesize aminated acrylic conducting polymer (AACP) using precursor of phenylvinylsulfoxide (PVS). The process was conducted via the integration of microemulsion and photopolymerization techniques. It has been utilized for covalent immobilization of amino groups by the adding of N-achryiloxisuccinimide (NAS). Thermal eliminating of benzene sulfenic acids from PVS has been done at 250 °C to form electroactive polyacetylene (PA) segment. Characterization of AACP has been conducted using fourier transform infrared (FTIR), scanning electron microscopy (SEM) and linear sweep cyclic voltammetry (CV). A range of 0.3-1.25μm particle size obtained from SEM characterization. A quasi-reversible system performed as shown in electrochemical study.},
doi = {10.1063/1.4931292},
journal = {AIP Conference Proceedings},
number = 1,
volume = 1678,
place = {United States},
year = 2015,
month = 9
}
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