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Title: Imaging and characterization of γ′ and γ″ nanoparticles in Inconel 718 by EDX elemental mapping and FIB–SEM tomography

Abstract

Microstructural characterization of Inconel 718 superalloy after three different heat treatment variants was performed by electron microscopy and electron tomography techniques, taking advantage of recent development in quantitative electron microscopy. Distribution maps of the chemical elements, collected by ChemiSTEM™ EDX system, offer a clear contrast between γ′, γ″, and the γ matrix. It was found that the γ′ phase contains mainly Ni, Al, and Ti, while the γ″ phase contains Ni, Nb, and Ti. Thus application of the Al and Nb STEM–EDX elemental maps enables identification and size measurements of γ′ and γ″ nanoparticles. 3D morphology of γ′ and γ″ precipitates was examined by electron microscopy and FIB–SEM tomography. Employed methods revealed that in all three heat treatment variants the γ′ particles are almost spheroidal while the γ″ precipitates are mainly elongated-disc shaped. However, the precipitate sizes differed for each variant contributing to differences in the yield strength. Tomographic images were used for estimation of the volume fraction of the both strengthening phases. - Highlights: • ChemiSTEM™ EDX elemental maps bring a fast mean to differentiate γ′ and γ″ particles. • Such maps enable for the explicit size measurements of γ′ and γ″ nanoparticles. • Explicit γ′ and γ″ phasesmore » total volume fraction was measured employing FIB–SEM. • γ′/γ″ co-precipitates and sandwich-like γ′/γ″/γ′ particles were present. • HRSTEM-HAADF imaging revealed atomic columns of the γ′/γ″ co-precipitates.« less

Authors:
 [1];  [1];  [2];  [1];  [3];  [1]
  1. AGH University of Science and Technology, International Centre of Electron Microscopy for Materials Science, Faculty of Metals Engineering and Industrial Computer Science, Al. A. Mickiewicza 30, 30-059 Kraków (Poland)
  2. (Switzerland)
  3. Pratt & Whitney, 400 Main Street, East Hartford, CT 06108 (United States)
Publication Date:
OSTI Identifier:
22476033
Resource Type:
Journal Article
Resource Relation:
Journal Name: Materials Characterization; Journal Volume: 100; Other Information: Copyright (c) 2014 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
77 NANOSCIENCE AND NANOTECHNOLOGY; DISTRIBUTION; HEAT TREATMENTS; INCONEL 718; MICROSTRUCTURE; NANOPARTICLES; PRECIPITATION; SCANNING ELECTRON MICROSCOPY; TOMOGRAPHY; YIELD STRENGTH

Citation Formats

Kulawik, K., E-mail: kulawik@agh.edu.pl, Buffat, P.A., E-mail: philippe.buffat@epfl.ch, Ecole Polytechnique Fédérale de Lausanne, CIME, Station 12, CH-1015 Lausanne Switzerland, Kruk, A., E-mail: kruczek@uci.agh.edu.pl, Wusatowska-Sarnek, A.M., E-mail: agnieszka.wusatowska-sarnek@pw.utc.com, and Czyrska-Filemonowicz, A., E-mail: czyrska@agh.edu.pl. Imaging and characterization of γ′ and γ″ nanoparticles in Inconel 718 by EDX elemental mapping and FIB–SEM tomography. United States: N. p., 2015. Web. doi:10.1016/J.MATCHAR.2014.12.012.
Kulawik, K., E-mail: kulawik@agh.edu.pl, Buffat, P.A., E-mail: philippe.buffat@epfl.ch, Ecole Polytechnique Fédérale de Lausanne, CIME, Station 12, CH-1015 Lausanne Switzerland, Kruk, A., E-mail: kruczek@uci.agh.edu.pl, Wusatowska-Sarnek, A.M., E-mail: agnieszka.wusatowska-sarnek@pw.utc.com, & Czyrska-Filemonowicz, A., E-mail: czyrska@agh.edu.pl. Imaging and characterization of γ′ and γ″ nanoparticles in Inconel 718 by EDX elemental mapping and FIB–SEM tomography. United States. doi:10.1016/J.MATCHAR.2014.12.012.
Kulawik, K., E-mail: kulawik@agh.edu.pl, Buffat, P.A., E-mail: philippe.buffat@epfl.ch, Ecole Polytechnique Fédérale de Lausanne, CIME, Station 12, CH-1015 Lausanne Switzerland, Kruk, A., E-mail: kruczek@uci.agh.edu.pl, Wusatowska-Sarnek, A.M., E-mail: agnieszka.wusatowska-sarnek@pw.utc.com, and Czyrska-Filemonowicz, A., E-mail: czyrska@agh.edu.pl. Sun . "Imaging and characterization of γ′ and γ″ nanoparticles in Inconel 718 by EDX elemental mapping and FIB–SEM tomography". United States. doi:10.1016/J.MATCHAR.2014.12.012.
@article{osti_22476033,
title = {Imaging and characterization of γ′ and γ″ nanoparticles in Inconel 718 by EDX elemental mapping and FIB–SEM tomography},
author = {Kulawik, K., E-mail: kulawik@agh.edu.pl and Buffat, P.A., E-mail: philippe.buffat@epfl.ch and Ecole Polytechnique Fédérale de Lausanne, CIME, Station 12, CH-1015 Lausanne Switzerland and Kruk, A., E-mail: kruczek@uci.agh.edu.pl and Wusatowska-Sarnek, A.M., E-mail: agnieszka.wusatowska-sarnek@pw.utc.com and Czyrska-Filemonowicz, A., E-mail: czyrska@agh.edu.pl},
abstractNote = {Microstructural characterization of Inconel 718 superalloy after three different heat treatment variants was performed by electron microscopy and electron tomography techniques, taking advantage of recent development in quantitative electron microscopy. Distribution maps of the chemical elements, collected by ChemiSTEM™ EDX system, offer a clear contrast between γ′, γ″, and the γ matrix. It was found that the γ′ phase contains mainly Ni, Al, and Ti, while the γ″ phase contains Ni, Nb, and Ti. Thus application of the Al and Nb STEM–EDX elemental maps enables identification and size measurements of γ′ and γ″ nanoparticles. 3D morphology of γ′ and γ″ precipitates was examined by electron microscopy and FIB–SEM tomography. Employed methods revealed that in all three heat treatment variants the γ′ particles are almost spheroidal while the γ″ precipitates are mainly elongated-disc shaped. However, the precipitate sizes differed for each variant contributing to differences in the yield strength. Tomographic images were used for estimation of the volume fraction of the both strengthening phases. - Highlights: • ChemiSTEM™ EDX elemental maps bring a fast mean to differentiate γ′ and γ″ particles. • Such maps enable for the explicit size measurements of γ′ and γ″ nanoparticles. • Explicit γ′ and γ″ phases total volume fraction was measured employing FIB–SEM. • γ′/γ″ co-precipitates and sandwich-like γ′/γ″/γ′ particles were present. • HRSTEM-HAADF imaging revealed atomic columns of the γ′/γ″ co-precipitates.},
doi = {10.1016/J.MATCHAR.2014.12.012},
journal = {Materials Characterization},
number = ,
volume = 100,
place = {United States},
year = {Sun Feb 15 00:00:00 EST 2015},
month = {Sun Feb 15 00:00:00 EST 2015}
}