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Title: Carbon dioxide adsorption on micro-mesoporous composite materials of ZSM-12/MCM-48 type: The role of the contents of zeolite and functionalized amine

Abstract

Highlights: • Synthesis of the micro-mesoporous composite materials of ZSM-12/MCM-48 type. • Application of these adsorbents in the carbon dioxide adsorption. • Effects of the contents of zeolite and amino group in the material surface on the CO{sub 2} capture efficiency. - Abstract: In this study ZSM-12/MCM-48 adsorbents have been synthesized at three ZSM-12 content, and also were functionalizated with amine groups by grafting. All the adsorbents synthesized were evaluated for CO{sub 2} capture. The X-ray diffraction analysis of the ZSM-12/MCM-48 composite showed the main characteristic peaks of ZSM-12 and MCM-48, and after the functionalization, the structure of MCM-48 on the composite impregnated was affected due amine presence. For the composites without amine, the ZSM-12 content was the factor determining in the adsorption capacity of CO{sub 2} and for the composites with amine the amount of amine was that influenced in the adsorption capacity.

Authors:
 [1];  [2]; ;  [3]
  1. Federal University of Sergipe, Materials Science and Engineering Postgraduate Program P"2CEM, São Cristovão/SE (Brazil)
  2. Federal University of Sergipe, Department of Chemical Engineering (DEQ), Av. Marechal Rondon S/N, 49100-000, São Cristovão/SE (Brazil)
  3. University of Málaga, Department of Inorganic Chemistry, Crystallography and Mineralogy, Faculty of Sciences, 29071, Málaga (Spain)
Publication Date:
OSTI Identifier:
22475953
Resource Type:
Journal Article
Journal Name:
Materials Research Bulletin
Additional Journal Information:
Journal Volume: 70; Other Information: Copyright (c) 2015 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA); Journal ID: ISSN 0025-5408
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; ADSORBENTS; ADSORPTION; AMINES; CAPACITY; CARBON DIOXIDE; COMPOSITE MATERIALS; CRYSTAL GROWTH; EFFICIENCY; NANOSTRUCTURES; POROUS MATERIALS; SURFACE PROPERTIES; SURFACES; SYNTHESIS; X-RAY DIFFRACTION; ZEOLITES

Citation Formats

Santos, S. C.G., Pedrosa, A.M.Garrido, Souza, M. J.B.,, Cecilia, J. A., and Rodríguez-Castellón, E. Carbon dioxide adsorption on micro-mesoporous composite materials of ZSM-12/MCM-48 type: The role of the contents of zeolite and functionalized amine. United States: N. p., 2015. Web. doi:10.1016/J.MATERRESBULL.2015.05.037.
Santos, S. C.G., Pedrosa, A.M.Garrido, Souza, M. J.B.,, Cecilia, J. A., & Rodríguez-Castellón, E. Carbon dioxide adsorption on micro-mesoporous composite materials of ZSM-12/MCM-48 type: The role of the contents of zeolite and functionalized amine. United States. doi:10.1016/J.MATERRESBULL.2015.05.037.
Santos, S. C.G., Pedrosa, A.M.Garrido, Souza, M. J.B.,, Cecilia, J. A., and Rodríguez-Castellón, E. Thu . "Carbon dioxide adsorption on micro-mesoporous composite materials of ZSM-12/MCM-48 type: The role of the contents of zeolite and functionalized amine". United States. doi:10.1016/J.MATERRESBULL.2015.05.037.
@article{osti_22475953,
title = {Carbon dioxide adsorption on micro-mesoporous composite materials of ZSM-12/MCM-48 type: The role of the contents of zeolite and functionalized amine},
author = {Santos, S. C.G. and Pedrosa, A.M.Garrido and Souza, M. J.B., and Cecilia, J. A. and Rodríguez-Castellón, E.},
abstractNote = {Highlights: • Synthesis of the micro-mesoporous composite materials of ZSM-12/MCM-48 type. • Application of these adsorbents in the carbon dioxide adsorption. • Effects of the contents of zeolite and amino group in the material surface on the CO{sub 2} capture efficiency. - Abstract: In this study ZSM-12/MCM-48 adsorbents have been synthesized at three ZSM-12 content, and also were functionalizated with amine groups by grafting. All the adsorbents synthesized were evaluated for CO{sub 2} capture. The X-ray diffraction analysis of the ZSM-12/MCM-48 composite showed the main characteristic peaks of ZSM-12 and MCM-48, and after the functionalization, the structure of MCM-48 on the composite impregnated was affected due amine presence. For the composites without amine, the ZSM-12 content was the factor determining in the adsorption capacity of CO{sub 2} and for the composites with amine the amount of amine was that influenced in the adsorption capacity.},
doi = {10.1016/J.MATERRESBULL.2015.05.037},
journal = {Materials Research Bulletin},
issn = {0025-5408},
number = ,
volume = 70,
place = {United States},
year = {2015},
month = {10}
}