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Title: Facile approach to prepare Pt decorated SWNT/graphene hybrid catalytic ink

Abstract

Highlights: • Pt NPs were in situ synthesized onto CNT–graphene support in aqueous solution. • The as-prepared material was used directly as a catalyst ink without further treatment. • Catalyst ink is active toward methanol oxidation. • This approach realizes both scalable and greener production of hybrid catalysts. - Abstract: Platinum nanoparticles were in situ synthesized onto hybrid support involving graphene and single walled carbon nanotube in aqueous solution. We investigate the reduction of graphene oxide, and platinum nanoparticle functionalization on hybrid support by X-ray photoelectron spectroscopy, Raman spectroscopy, X-ray diffraction, scanning electron microscopy and transmission electron microscopy. The as-prepared platinum on hybrid support was used directly as a catalyst ink without further treatment and is active toward methanol oxidation. This work realizes both scalable and greener production of highly efficient hybrid catalysts, and would be valuable for practical applications of graphene based fuel cell catalysts.

Authors:
 [1]; ;  [1];  [2];  [2]
  1. Centre for Innovation in Energy Research, CSIR–Central Electrochemical Research Institute, Karaikudi 630006, Tamil Nadu (India)
  2. Department of Nuclear and Quantum Engineering, Korea Advanced Institute of Science and Technology, Daejeon, 305-701 (Korea, Republic of)
Publication Date:
OSTI Identifier:
22475825
Resource Type:
Journal Article
Journal Name:
Materials Research Bulletin
Additional Journal Information:
Journal Volume: 67; Other Information: Copyright (c) 2015 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA); Journal ID: ISSN 0025-5408
Country of Publication:
United States
Language:
English
Subject:
77 NANOSCIENCE AND NANOTECHNOLOGY; AQUEOUS SOLUTIONS; CARBON NANOTUBES; ELECTROCATALYSTS; GRAPHENE; NANOPARTICLES; OXIDATION; OXIDES; PLATINUM; RAMAN SPECTROSCOPY; SCANNING ELECTRON MICROSCOPY; TRANSMISSION ELECTRON MICROSCOPY; X-RAY DIFFRACTION; X-RAY PHOTOELECTRON SPECTROSCOPY

Citation Formats

Mayavan, Sundar, Department of Nuclear and Quantum Engineering, Korea Advanced Institute of Science and Technology, Daejeon, 305-701, Mandalam, Aditya, Balasubramanian, M., Sim, Jun-Bo, and Choi, Sung-Min. Facile approach to prepare Pt decorated SWNT/graphene hybrid catalytic ink. United States: N. p., 2015. Web. doi:10.1016/J.MATERRESBULL.2015.03.001.
Mayavan, Sundar, Department of Nuclear and Quantum Engineering, Korea Advanced Institute of Science and Technology, Daejeon, 305-701, Mandalam, Aditya, Balasubramanian, M., Sim, Jun-Bo, & Choi, Sung-Min. Facile approach to prepare Pt decorated SWNT/graphene hybrid catalytic ink. United States. doi:10.1016/J.MATERRESBULL.2015.03.001.
Mayavan, Sundar, Department of Nuclear and Quantum Engineering, Korea Advanced Institute of Science and Technology, Daejeon, 305-701, Mandalam, Aditya, Balasubramanian, M., Sim, Jun-Bo, and Choi, Sung-Min. Wed . "Facile approach to prepare Pt decorated SWNT/graphene hybrid catalytic ink". United States. doi:10.1016/J.MATERRESBULL.2015.03.001.
@article{osti_22475825,
title = {Facile approach to prepare Pt decorated SWNT/graphene hybrid catalytic ink},
author = {Mayavan, Sundar and Department of Nuclear and Quantum Engineering, Korea Advanced Institute of Science and Technology, Daejeon, 305-701 and Mandalam, Aditya and Balasubramanian, M. and Sim, Jun-Bo and Choi, Sung-Min},
abstractNote = {Highlights: • Pt NPs were in situ synthesized onto CNT–graphene support in aqueous solution. • The as-prepared material was used directly as a catalyst ink without further treatment. • Catalyst ink is active toward methanol oxidation. • This approach realizes both scalable and greener production of hybrid catalysts. - Abstract: Platinum nanoparticles were in situ synthesized onto hybrid support involving graphene and single walled carbon nanotube in aqueous solution. We investigate the reduction of graphene oxide, and platinum nanoparticle functionalization on hybrid support by X-ray photoelectron spectroscopy, Raman spectroscopy, X-ray diffraction, scanning electron microscopy and transmission electron microscopy. The as-prepared platinum on hybrid support was used directly as a catalyst ink without further treatment and is active toward methanol oxidation. This work realizes both scalable and greener production of highly efficient hybrid catalysts, and would be valuable for practical applications of graphene based fuel cell catalysts.},
doi = {10.1016/J.MATERRESBULL.2015.03.001},
journal = {Materials Research Bulletin},
issn = {0025-5408},
number = ,
volume = 67,
place = {United States},
year = {2015},
month = {7}
}